Application of entropy analysis of in situ droplet-size spectra in evaluation of oil chemical dispersion efficacy

In situ droplet-size distributions were measured using a laser in situ scattering and transmissiometry (LISST-100X) particle size analyzer during the evaluation of natural and chemical dispersion efficiency of crude oils under different wave and current conditions. An entropy grouping of the in situ dispersed oil droplet-size spectra has classified the multi-modal droplet-size distributions into different groups based on similar droplet-size spectra characteristics within groups and distinction between groups. A generalized linear logistic regression model was fitted to analyze the effects of a number of factors and their interactions on the grouping of oil droplet-size spectra. The grouped results corresponded to the oil dispersion efficiency at different levels. This new method for droplet-size distribution data analysis can have significant implication in field evaluation of natural and chemical dispersion efficiency of oil.     

Osteichthyans from the Fairpoint Member of the Fox Hills Formation (Maastrichtian), Meade County, South Dakota, USA

The Fairpoint Member of the Fox Hills Formation (upper Maastrichtian) in Meade County, South Dakota, USA, contains an osteichthyan assemblage indicative of transitional to marine shoreface deposits. The fauna consists of: Lepisosteus sp., Paralbula casei, Cylindracanthus cf. C. ornatus, Enchodus gladiolus, Hadrodus sp., and indeterminate osteichthyans with probable affinities to the Siluriformes and Beryciformes. The Fairpoint fauna is of limited species diversity and in this character mirrors many other Upper Cretaceous North American osteichthyan assemblages. Comparison to Upper Cretaceous chondrichthyan diversity and consideration of the structure of Cretaceous marine food webs suggest that osteichthyans are strongly under-represented in the Upper Cretaceous of North America. The small size and poor preservation potential of many Upper Cretaceous North American osteichthyans probably account for much of this observed paucity. Fairpoint osteichthyans are members of families that survive the Cretaceous–Paleocene boundary extinction event. Some of these genera and families are still extant and occur in a wide array of modern fresh, brackish, and shallow marine environments.     

The Use of Spatial Cognitive Abilities in Geographical Information Systems: The Map Overlay Operation

Spatial cognitive abilities play an important role in the use of GIS, although they have yet to be examined in a controlled experimental setting. This study aimed to develop an experimental design which measures spatial cognitive abilities in the use of GIS, specifically the map overlay operation. Subjects ( n = 134) received three map overlay tests in which they were given two of the following: input map layers, logical operator(s), or output map layer(s). Subjects were required to select the correct logical operator for Test 1, to select the correct output map layer for Test 2, and to select the correct input map layers for Test 3. Each test contained a total of 16 questions, based on a 4 ('and', 'or', 'xor', 'not' operators) × 2 (one or two polygons per map layer) × 2 (three or five polygon edges) factorial design. Results indicated a significant main effect of logical operators and number of polygons on performance; however, there was no effect of the number of polygon edges on performance. Significant two-way interactions revealed an effect of the number of polygon edges and the number of polygons using various logical operators on performance. In addition, performance was not significantly different between males and females or between GIS users and non-users. Overall, results show that map overlays in which a visual correspondence can be made between the same polygons in the input and output map layers are cognitively less demanding than map overlays in which the shape of the polygons have been radically transformed between the input and output map layers. This study helps further develop our understanding of the spatial cognitive abilities which are required in the use of GIS, and whether certain sub-populations differ in these cognitive abilities. These results may contribute to more effective and efficient GIS teaching and interface design by taking into account individual spatial cognitive abilities.     

Sensitivity analysis of pounding between adjacent structures

This article deals with sensitivity of the response of pounding buildings with respect to structural and earthquake excitation parameters. A comprehensive sensitivity analysis is carried out by means of Monte Carlo simulations of adjacent single degree of freedom impacting oscillators. This sensitivity analysis, based on Sobol's method, computes sensitivity indexes which provide a consistent measure of the relative importance of parameters such as the dimensionless main excitation frequency, the mass and frequency ratios of the structures, and the coefficient of restitution. Moreover, the influence of nonlinear behavior of the impacting structures is also considered. The consequences of pounding on the structures themselves are analyzed in terms of maximum force and nonlinear demand amplification compared with the case without pounding. As for the influence of pounding on the floor response spectra, the quantity of interest is the maximum impact impulse. The overall conclusions of this analysis are that the frequency ratio is the most important parameter as far as the maximum force and nonlinear demand are concerned. Regarding the maximum impact impulse, the mass and frequency ratios are, in general, the most influential parameters, the mass ratio being predominant for low frequencies of the oscillator of interest.     

Simulated perturbation in the sea-to-air flux of dimethylsulfi de and the impact on polar climate

Marine biogenic emission of dimethylsulfi de(DMS)has been well recognized as the main natural source of reduced sulfur to the remote marine atmosphere and has the potential to aff ect climate,especially in the polar regions.We used a global climate model(GCM)to investigate the impact on atmospheric chemistry from a change to the contemporary DMS fl ux to that which has been projected for the late 21 st century.The perturbed simulation corresponded to conditions that pertained to a tripling of equivalent CO 2,which was estimated to occur by year 2090 based on current worst-case greenhouse gas emission scenarios.The changes in zonal mean DMS fl ux were applied to 50°S–70°S Antarctic(ANT)and 65°N–80°N Arctic(ARC)regions.The results indicate that there are clearly diff erent impacts after perturbation in the southern and northern polar regions.Most quantities related to the sulfur cycle show a higher increase in ANT.However,most sulfur compounds have higher peaks in ARC.The perturbation in DMS fl ux leads to an increase of atmospheric DMS of about 45%in ANT and 33.6%in ARC.The sulfur dioxide(SO 2)vertical integral increases around 43%in ANT and 7.5%in ARC.Sulfate(SO 4)vertical integral increases by 17%in ANT and increases around 6%in ARC.Sulfur emissions increases by 21%in ANT and increases by 9.7%in ARC.However,oxidation of DMS by OH increases by 38.2%in ARC and by 15.17%in ANT.Aerosol optical depth(AOD)increases by 4%in the ARC and by 17.5%in the ANT,and increases by 22.8%in austral summer.The importance of the perturbation of the biogenic source to future aerosol burden in polar regions leads to a cooling in surface temperature of 1 K in the ANT and 0.8 K in the ARC.Generally,polar regions in the Antarctic Ocean will have a higher off setting eff ect on warming after DMS fl ux perturbation.     

Zircon U–Pb geochronology and Hf isotope geochemistry of magmatic and metamorphic rocks from the Hida Belt,southwest Japan

Zircon U–Pb and Hf isotope data integrated in this study for magmatic and metamorphic rocks from the Hida Belt,southwest Japan,lead to a new understanding of the evolution of the Cordilleran arc system along the ancestral margins of present-day Northeast Asia.Ion microprobe data for magmatic zircon domains from eight mafic to intermediate orthogneisses in the Tateyama and Tsunogawa areas yielded weighted mean ~(206)Pb/~(238)U ages spanning the entire Permian period(302–254 Ma).Under cathodoluminescence,primary magmatic growth zones in the zircon crystals were observed to be partially or completely replaced by inward-penetrating,irregularly curved featureless or weakly zoned secondary domains that mostly yielded U–Pb ages of 250–240 Ma and relatively high Th/U ratios( 0.2).These secondary domains are considered to have been formed by solid-state recrystallization during thermal overprints associated with intrusions of Hida granitoids.Available whole-rock geochemical and Sr–Nd isotope data as well as zircon age spectra corroborate that the Hida Belt comprises the Paleozoic–Mesozoic Cordilleran arc system built upon the margin of the North China Craton,together with the Yeongnam Massif in southern Korea.The arc magmatism along this system was commenced in the Carboniferous and culminated in the Permian–Triassic transition period.Highly positive εHf(t) values( +12) of late Carboniferous to early Permian detrital zircons in the Hida paragneisses indicate that there was significant input from the depleted asthenospheric mantle and/or its crustal derivatives in the early stage of arc magmatism.On the other hand,near-chondritic εHf(t) values(+5 to-2) of magmatic zircons from late Permian Hida orthogneisses suggest a lithospheric mantle origin.Hf isotopic differences between magmatic zircon cores and the secondary rims observed in some orthogneiss samples clearly indicate that the zircons were chemically open to fluids or melts during thermal overprints.Resumed highly positive zircon εHf(t) values(+9) shared by Early Jurassic granitoids in the Hida Belt and Yeongnam Massif may reflect reworking of the Paleozoic arc crust.     

Projection of future climate change conditions using IPCC simulations, neural networks and Bayesian statistics. Part 1: Temperature mean state and seasonal cycle in South America

Projections for South America of future climate change conditions in mean state and seasonal cycle for temperature during the twenty-first century are discussed. Our analysis includes one simulation of seven Atmospheric-Ocean Global Circulation Models, which participated in the Intergovernmental Panel on Climate Change Project and provided at least one simulation for the twentieth century (20c3m) and one simulation for each of three Special Report on Emissions Scenarios (SRES) A2, A1B, and B1. We developed a statistical method based on neural networks and Bayesian statistics to evaluate the models’ skills in simulating late twentieth century temperature over continental areas. Some criteria [model weight indices (MWIs)] are computed allowing comparing over such large regions how each model captures the temperature large scale structures and contributes to the multi-model combination. As the study demonstrates, the use of neural networks, optimized by Bayesian statistics, leads to two major results. First, the MWIs can be interpreted as optimal weights for a linear combination of the climate models. Second, the comparison between the neural network projection of twenty-first century conditions and a linear combination of such conditions allows the identification of the regions, which will most probably change, according to model biases and model ensemble variance. Model simulations in the southern tip of South America and along the Chilean and Peruvian coasts or in the northern coasts of South America (Venezuela, Guiana) are particularly poor. Overall, our results present an upper bound of potential temperature warming for each scenario. Spatially, in SRES A2, our major findings are that Tropical South America could warm up by about 4°C, while southern South America (SSA) would also undergo a near 2–3°C average warming. Interestingly, this annual mean temperature trend is modulated by the seasonal cycle in a contrasted way according to the regions. In SSA, the amplitude of the seasonal cycle tends to increase, while in northern South America, the amplitude of the seasonal cycle would be reduced leading to much milder winters. We show that all the scenarios have similar patterns and only differ in amplitude. SRES A1B differ from SRES A2 mainly for the late twenty-first century, reaching more or less an 80–90% amplitude compared to SRES A2. SRES B1, however, diverges from the other scenarios as soon as 2025. For the late twenty-first century, SRES B1 displays amplitudes, which are about half those of SRES A2.     

Rythmes de sédimentation dans le crétacé helvétique

A new method of sedimentary rocks investigation is proposed. It illustrates by means of curves the variations in both time and space of the main mineral and organic features. By combining them together in a logical way, it is possible to decipher the relations between sedimentation and the different factors governing it: depth, distance to shoreline, direction and strength of marine currents, biological and chemical conditions, tectonics and so on. Finally a paleogeographic classification of lithological facies is obtained.Some examples taken in the Cretaceous of the Swiss High Calcareous Alps are presented. The bathymetrical interpretation of their facies is in close agreement with the results of modern oceanographic investigations which have described in some cases very similar conditions.

---

Zusammenfassung Eine Interpretationsmethode der Sedimentgesteine wird dargestellt. Mittels Kurven warden die zeitlichen und räumlichen Variationen der wichtigsten mineralogischen und organischen Charaktere ausgedrückt. Die durch diese Kurven gelieferten Angaben werden unter sich in logischer Weise kombiniert und erlauben eine paläogeographische Klassifikation der verschiedenen lithologischen Einheiten. Hiermit ist es möglich, die Verbindungen zwischen der Sedimentation und den verschiedenen Faktoren, welche die letztere beeinflussen, herzustellen: Tiefe, Entfernung von der Küste, Richtung und Stärke der Strömungen, physikalisch-chemische Bedingungen, Tektonik usw. Es werden verschiedene Beispiele aus der helvetischen Kreide dargelegt. Die bathymetrische Interpretation ihrer lithologischen Fazies entspricht den neuesten Arbeiten der Ozeanographie, worin ähnliche aktuelle Bedingungen beschrieben sind.

     

7000 years of paleostorm activity in the NW Mediterranean Sea in response to Holocene climate events

A high-resolution record of paleostorm events along the French Mediterranean coast over the past 7000 years was established from a lagoonal sediment core in the Gulf of Lions. Integrating grain size, faunal analysis, clay mineralogy and geochemistry data with a chronology derived from radiocarbon dating, we recorded seven periods of increased storm activity at 6300–6100, 5650–5400, 4400–4050, 3650–3200, 2800–2600, 1950–1400 and 400–50 cal yr BP (in the Little Ice Age). In contrast, our results show that the Medieval Climate Anomaly (1150–650 cal yr BP) was characterised by low storm activity.The evidence for high storm activity in the NW Mediterranean Sea is in agreement with the changes in coastal hydrodynamics observed over the Eastern North Atlantic and seems to correspond to Holocene cooling in the North Atlantic. Periods of low SSTs there may have led to a stronger meridional temperature gradient and a southward migration of the westerlies. We hypothesise that the increase in storm activity during Holocene cold events over the North Atlantic and Mediterranean regions was probably due to an increase in the thermal gradient that led to an enhanced lower tropospheric baroclinicity over a large Central Atlantic–European domain.     

XMM–Newton observations of the black hole X-ray transient XTE J1650–500 in quiescence

We report the result of an XMM–Newton observation of the black hole X-ray transient XTE J1650–500 in quiescence. The source was not detected, and we set upper limits on the 0.5–10 keV luminosity of  0.9–1.0 × 10³¹ erg s⁻¹  (for a newly derived distance of 2.6 kpc). These limits are in line with the quiescent luminosities of black hole X-ray binaries with similar orbital periods (∼7–8 h).