Spatio‐temporal distribution of near‐surface and root zone soil moisture at the catchment scale

Soil moisture is highly variable both spatially and temporally. It is widely recognized that improving the knowledge and understanding of soil moisture and the processes underpinning its spatial and temporal distribution is critical. This paper addresses the relationship between near‐surface and root zone soil moisture, the way in which they vary spatially and temporally, and the effect of sampling design for determining catchment scale soil moisture dynamics. In this study, catchment scale near‐surface (0–50 mm) and root zone (0–300 mm) soil moisture were monitored over a four‐week period. Measurements of near‐surface soil moisture were recorded at various resolutions, and near‐surface and root zone soil moisture data were also monitored continuously within a network of recording sensors. Catchment average near‐surface soil moisture derived from detailed spatial measurements and continuous observations at fixed points were found to be significantly correlated (r² = 0·96; P = 0·0063; n = 4). Root zone soil moisture was also found to be highly correlated with catchment average near‐surface, continuously monitored (r² = 0·81; P < 0·0001; n = 26) and with detailed spatial measurements of near‐surface soil moisture (r² = 0·84). The weaker relationship observed between near‐surface and root zone soil moisture is considered to be caused by the different responses to rainfall and the different factors controlling soil moisture for the soil depths of 0–50 mm and 0–300 mm. Aspect is considered to be the main factor influencing the spatial and temporal distribution of near‐surface soil moisture, while topography and soil type are considered important for root zone soil moisture. The ability of a limited number of monitoring stations to provide accurate estimates of catchment scale average soil moisture for both near‐surface and root zone is thus demonstrated, as opposed to high resolution spatial measurements. Similarly, the use of near‐surface soil moisture measurements to obtain a reliable estimate of deeper soil moisture levels at the small catchment scale was demonstrated. Copyright © 2007 John Wiley & Sons, Ltd.     

Water quality monitoring: a combined approach to investigate gradients of change in the Great Barrier Reef, Australia

For the managers of a region as large as the Great Barrier Reef, it is a challenge to develop a cost effective monitoring program, with appropriate temporal and spatial resolution to detect changes in water quality. The current study compares water quality data (phytoplankton abundance and water clarity) from remote sensing with field sampling (continuous underway profiles of water quality and fixed site sampling) at different spatial scales in the Great Barrier Reef north of Mackay (20 degrees S). Five transects (20-30 km long) were conducted from clean oceanic water to the turbid waters adjacent to the mainland. The different data sources demonstrated high correlations when compared on a similar spatial scale (18 fixed sites). However, each data source also contributed unique information that could not be obtained by the other techniques. A combination of remote sensing, underway sampling and fixed stations will deliver the best spatial and temporal monitoring of water quality in the Great Barrier Reef.     

Depthimeter-Precise Vessel Depth for Bathymetry

This article describes the design, operation, and field testing of the depthimeter. The depthimeter merges heave and acoustically derived vessel depth to form estimates of instantaneous vessel depth and instantaneous sea surface height, both relative to mean sea level. Results from sea trials held in December 1997 demonstrate successful operation of the system.     

New observations on high‐pressure phases in a shock melt vein in the Villalbeto de la Peña meteorite: Insights into the shock behavior of diopside

The petrology and mineralogy of shock melt veins in the L6 ordinary chondrite host of Villalbeto de la Peña, a highly shocked, L chondrite polymict breccia, have been investigated in detail using scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, and electron probe microanalysis. Entrained olivine, enstatite, diopside, and plagioclase are transformed into ringwoodite, low‐Ca majorite, high‐Ca majorite, and an assemblage of jadeite‐lingunite, respectively, in several shock melt veins and pockets. We have focused on the shock behavior of diopside in a particularly large shock melt vein (10 mm long and up to 4 mm wide) in order to provide additional insights into its high‐pressure polymorphic phase transformation mechanisms. We report the first evidence of diopside undergoing shock‐induced melting, and the occurrence of natural Ca‐majorite formed by solid‐state transformation from diopside. Magnesiowüstite has also been found as veins injected into diopside in the form of nanocrystalline grains that crystallized from a melt and also occurs interstitially between majorite‐pyrope grains in the melt‐vein matrix. In addition, we have observed compositional zoning in majorite‐pyrope grains in the matrix of the shock‐melt vein, which has not been described previously in any shocked meteorite. Collectively, all these different lines of evidence are suggestive of a major shock event with high cooling rates. The minimum peak shock conditions are difficult to constrain, because of the uncertainties in applying experimentally determined high‐pressure phase equilibria to complex natural systems. However, our results suggest that conditions between 16 and 28 GPa and 2000–2200 °C were reached.     

柴达木盆地西部第四纪气候变化和流域风化

长期以来关于构造隆升、气候变化和大陆化学风化的相互关系存在诸多争议。在气候和构造相互作用典型区域建立高精度大陆化学风化序列是解决上述科学问题的有效途径之一。位于青藏高原东北缘长期封闭的柴达木盆地,其独特的位置和连续的沉积使其成为研究构造隆升、气候变化和大陆化学风化的理想场所。本文以柴达木盆地西部千米深钻SG-1钻孔高质量的连续细粒湖相岩芯为研究对象,使用盐类矿物的硫酸根和钾离子含量、碳酸盐锰含量和硅酸盐化学蚀变指数（CIA）和Nd同位素分析,重建该区第四纪以来湖泊流域气候变化过程和硅酸盐化学风化及可能的物源变化。结果表明柴达木盆地西部第四纪以来流域物源相对稳定,流域整体呈现出气候干旱化、流域硅酸盐风化强度减弱、湖水盐度增加和湖面降低的长期一致性演化过程;上述演化进程在2.2 Ma到2.0 Ma期间短暂加强,在约1.2 Ma和约0.6~0.5 Ma出现逐步加强趋势。过去60万年,柴达木盆地西部在冰期存在的相对高湖面时期与黄土高原粒度指标反映的冬季风减弱阶段可以很好对比。北大西洋海表温度反映的高纬过程是长时间尺度（>105年）驱动柴达木盆地西部气候变化和流域硅酸盐风化强度变化的主要因素;西伯利亚高压系统和西风系统的"跷跷板关系"可能是冰期-间冰期或者更短尺度影响柴达木盆地西部气候变化的主要因素。     

The dose-response relationship between No. 2 fuel oil and the growth of the salt marsh grass,Spartina alterniflora

The effect of No. 2 fuel oil on the biomass production of the salt marsh plant, Spartina alterniflora, was studied in a greenhouse dose-response experiment. S. alterniflora were transplanted into soil with 10 dosage levels of No. 2 fuel oil ranging from 0 to 456 mg g(-1) dry soil. Three months after transplantation, values for plant biomass, stem density, and shoot height decreased significantly with increasing fuel oil level in a dose-response fashion. Evapo-transpiration rates were correlated with the total biomass response. Relative to the control, a significant decrease in total (above- plus below-ground) plant biomass was observed at concentrations above 57 mg g(-1) dry soil. Within the 3-month experimental period, detrimental effects on below-ground biomass accumulation and bioluminescence of the marine bacterium Viberio fisheri in the Microtox Solid Phase Test were observed at oil concentrations >29 mg g(-1) dry soil, suggesting that biological effects of oil within the sediment matrix may be more pronounced than on above-ground biomass, requiring a dosage 228 mg g(-1) dry soil to elicit a significant detrimental effect. Hence, measurements of oil effects with biological end-points based solely on above-ground responses may underestimate the potential impacts of petroleum hydrocarbon spills, especially when the oil has penetrated the soil. While S. alterniflora was proved to be relatively tolerant to the No. 2 fuel oil spills, its effectiveness in phytoremediation operations may be limited at fuel oil levels 228 mg g(-1) dry soil, as both plant growth and microbial activity may be constrained.     

Geochemical characterization of surface waters and groundwater resources in the Managua area (Nicaragua,Central America)

This paper reports new geochemical data on dissolved major and minor constituents in surface waters and ground waters collected in the Managua region (Nicaragua), and provides a preliminary characterization of the hydrogeochemical processes governing the natural water evolution in this area. The peculiar geological features of the study site, an active tectonic region (Nicaragua Depression) characterized by active volcanism and thermalism, combined with significant anthropogenic pressure, contribute to a complex evolution of water chemistry, which results from the simultaneous action of several geochemical processes such as evaporation, rock leaching, mixing with saline brines of natural or anthropogenic origin. The effect of active thermalism on both surface waters (e.g., saline volcanic lakes) and groundwaters, as a result of mixing with variable proportions of hyper-saline geothermal Na–Cl brines (e.g., Momotombo geothermal plant), accounts for the high salinities and high concentrations of many environmentally-relevant trace elements (As, B, Fe and Mn) in the waters. At the same time the active extensional tectonics of the Managua area favour the interaction with acidic, reduced thermal fluids, followed by extensive leaching of the host rock and the groundwater release of toxic metals (e.g., Ni, Cu). The significant pollution in the area, deriving principally from urban and industrial waste-water, probably also contributes to the aquatic cycling of many trace elements, which attain concentrations above the WHO recommended limits for the elements Ni (∼40 μg/l) and Cu (∼10 μg/l) limiting the potential utilisation of Lake Xolotlan for nearby Managua.     

Geodetic observation crucial to sea level monitoring

The relative rate of rise of the sea levels measured by a tide gauge is made of a sea and a land component. The first is usually restricted to the global short-term effect of melting icecaps and expansion of water mass due to global temperature change. The second is often limited to the regional long-term effects of glacial isostatic adjustment (GIA). Sometimes, the regional subsidence, due to compaction and ground water withdrawal, is considered. Here we show as this assumption of regional subsidence fails to represent the relative sea level patterns of Sandy Hook, NJ, and The Battery, NY, as well as of Venezia Punta Della Salute, Venezia II, Trieste and Trieste II. The subsidence of the tide gauge instrument may only be addressed by the precise monitoring of the tide gauge vs. a Global Navigation Satellite System (GNSS) antenna, even if the GNSS tracking is only recent and not yet very accurate. The relative sea level records are much more complicated than what is thought.     

On melting of the subducted oceanic crust: Effects of subduction induced mantle flow

Based on petrological and geochemical arguments, it is possible that arc magma is derived from subducted oceanic crust. In this paper, regional thermal models have been constructed to study the feasibility of melting cold subducted oceanic crusts at shallow depth (i.e. at depths of about 100 km) by a dynamic mantle. Calculated results suggest that plate subduction will generate an induced flow in the wedge above the subducting slab. This current continuously feeds hot mantle material into the corner and onto the slab surface. A high temperature thermal environment can be maintained in the vicinity of the wedge corner, immediately beneath the over-riding plate. Our regional models further demonstrate quantitatively that production of local melting is possible just about 30 km down dip from the asthenosphere wedge corner. Additional geological processes such as reasonable amounts of shear heating and minor dehydration (which will lower the local melting temperature) will further increase the probability of melting a cold subducted oceanic crust at shallow depth.