Origin of the northern Indus Fan and Murray Ridge, Northern Arabian Sea: interpretation from seismic and magnetic imaging

The nature and origin of the sediments and crust of the Murray Ridge System and northern Indus Fan are discussed. The uppermost unit consists of Middle Miocene to recent channel–levee complexes typical of submarine fans. This unit is underlain by a second unit composed of hemipelagic to pelagic sediments deposited during the drift phase after the break-up of India–Seychelles–Africa. A predrift sequence of assumed Mesozoic age occurring only as observed above basement ridges is composed of highly consolidated rocks. Different types of the acoustic basement were detected, which reflection seismic pattern, magnetic anomalies and gravity field modeling indicate to be of continental character. The continental crust is extremely thinned in the northern Indus Fan, lacking a typical block-faulted structure. The Indian continent–ocean transition is marked on single MCS profiles by sequences of seaward-dipping reflectors (SDR). In the northwestern Arabian Sea, the Indian plate margin is characterized by several phases of volcanism and deformation revealed from interpretation of multichannel seismic profiles and magnetic anomalies. From this study, thinned continental crust spreads between the northern Murray Ridge System and India underneath the northern Indus Fan.     

Anaerobic digestion of residual liquid effluent (brown juice) from a green biorefinery

This work studied the anaerobic digestion of brown juice, a liquid residual stream generated from biomass fractionation in a green biorefinery. Biomethane potential batch tests and inhibition studies of brown juice were performed during continuous processing in an upflow anaerobic sludge blanket reactor. Prolongation of the lag phase in the batch tests with increasing substrate/inoculum ratio suggested initial inhibition, which was, however, overcome by adaptation. This was indicated by high final methane yields, which were close to the theoretical maximum of up to 500 L-CH₄ kg-VS^?1, achieved after 15 days for most of the set-ups. Reactor operation at the organic loading rate of 13.9 g-COD L^?1 day^?1 and hydraulic retention time of 3 days revealed methane yields of 202 L-CH₄ kg-COD^?1 (307 L-CH₄ kg-VS^?1). Particle size analysis of the granules used in the reactor showed disintegration of the larger granules.     

Effect of suction on the mechanical behaviour of iron ore rock

The effect of suction on the behaviour of iron ore has been studied from both physical and mechanical points of view. The porosity and the suction phenomena have been analysed using different experimental techniques. Uniaxial compressive tests on partially saturated samples have shown that the suction is responsible for strength and cohesion improvement. Considering the theory of partially saturated porous soils of Coussy and Dangla (Mécanique des sols non saturés (2002 edn). Hermès Science: 2002; 390), we have proposed a constitutive law for partially saturated iron ore. The real increase in the apparent cohesion due to the capillary attraction forces is overestimated if the yield function is written in terms of effective stresses. The effect of the capillary cohesion has been modelled with a function in the expression of the apparent cohesion of the yield function. The effect of suction on the mechanical behaviour has been represented in the effective stresses space and in the total stresses space like the Alonso model (Géotechnique 1990; 40 :405–430). Copyright © 2005 John Wiley & Sons, Ltd.     

Paleobotany of Wisconsinan interstadials, eastern Great Lakes region, North America

This study concerns the pollen and plant macrofossils from Mid-Wisconsinan Interstadial sites within the Wisconsinan ice margin in eastern North America. The time period covered is from about 55,000 years BP to 22,500 years BP, an interval much longer than the postglacial. Sediments examined are principally those of large lakes deposited in the Erie and Ontario basins during intervals of ice retreat.The Port Talbot I Interval (from about 55,000 to 50,000 years BP) in the Erie basin is characterized by pollen assemblages alternating from Pinus-dominated zones to ones with abundant Pinus, Quercus, and nonarboreal pollen. These assemblages are interpreted as indicating relatively warm and dry conditions. Mean July temperatures fluctuated between 15 and 21°C.During the succeeding Port Talbot II Interval and Plum Point Interstadial, in both the Erie and Ontario basins, pollen assemblages are characterized by dominant Pinus and Picea. Characteristic macrofossils include needles of the boreal Picea and Larix and leaves of species with a more northerly distribution, such as Dryas integrifolia, Betula glandulosa var. glandulosa, Vaccinium uliginosum var. alpinum, and Salix herbacea. These fossil assemblages are interpreted as indicating cooler and moister conditions in a forest-tundra environment. Mean July temperatures fluctuated between 10 and 15°C during the Port Talbot II Interval and Plum Point Interstadial.     

On steep isogradic surfaces in the Simplon area

The Simplon tunnel (19.7 km long) in the Central Alps crosses, at an altitude of 640–700 m, a mountain chain that culminates in Monte Leone (3 553 m). Along the tunnel axis the metamorphic grade of Mesozoic sediments, recrystallized during the Lepontine phase of the Alpine orogenesis, increases from NW to SE. Investigations on rock samples from the tunnel and from surface exposures give information in three dimensions on conditions during the culmination of Alpine regional metamorphism in the Simplon group. The succession of isograds from km 3 from the NW entrance of the tunnel in SE direction is: First occurrence of biotite, of garnet, last occurrence of albite in paragenesis with calcite, entry of feldspars of the peristerite gap and of oligoclase alone in calc-schists, marbles and amphibolites, coming in of plagioclase An > 30 associated with calcite, first occurrence of staurolite and kyanite, entry of tremolite and calcite, occurrence of plagioclase An >50 in calcschists. Correlation of the data from tunnel and surface samples shows that, in the northwestern and central part of the section, the isogradic surfaces are steeply inclined to the NW, the average dip is 60–75°, with uncertainty between 55 and 90°. In the southeastern part of the section the isogradic surfaces are overturned and dip to the E. No observations indicate gently inclined isogradic surfaces. Geological evidence excludes postmetamorphic tilting of originally subhorizontal isogradic surfaces in such a scale. It is assumed that, during the Lepontine phase, the isobaric surfaces have been subhorizontal, but that the isotherms (which roughly correspond to isograds) have formed angles greater than 45° with isobars. During the culmination of metamorphism vertical and lateral temperature gradients differed considerably from place to place in the Simplon area, and gradually changed also in one and the same direction. The Simplon area is situated near the western edge of the high-grade metamorphic zones of the Ticino complex. The metamorphic conditions described are believed to have been strongly influenced by the eastern adjacent vast thermal bulge of the Central Alps. Thus, not only in Val Bregaglia, with its quite different geological environment, at the E end of the highgrade zone and of the same thermal antiform, but also in the Simplon area in the W, isogradic surfaces are steeply inclined.     

Advances in modelling of snowpack processes utilizing remote sensing technology

Application of models over large areas requires enormous amounts of point data which are seldom available. As a result, the use of remote sensing to acquire data for these models becomes a practical alternative because from space areal measurements can be made over entire regions. Remote sensing data sets of snow are being studied and refined for input into energy balance, hydrological, and general circulation models. Snow influences the amount of solar energy retained and returned to space, the utilization of radiant energy in the hydrological cycle, and the atmospheric circulation by interacting with and modifying air masses. The continually evolving remote sensing technology will be used to provide a better understanding of how snow cover influences global climate and a better fundamental understanding of snow accumulation and ablation processes.     

Sédimentation récifale rythmique dans le Jurassique superieur du Grand-Saleve (Haute-Savoie,France)

Résumé L'étude statistique des composants minéraux et organiques, selon les méthodes de l'auteur, a été effectuée sur plus de 600 coupes minces régulièrement distribuées dans une série récifale de 225 m d'épaisseur. Elle a révélé des soulèvements et des subsidences encadrant des récifs et se traduisant par une succession de microfaciès clastiques dont les assemblages faunistiques sont très bien délimités au point de vue bathymétrique. Une comparaison avec les formations récifales actuelles est tentée sur la base des faunes périrécifales.     

Crustal attenuation in the Southern Andean retroarc (38°–39°30′ S) determined from tectonic and gravimetric studies: The Lonco-Luán asthenospheric anomaly

The western retroarc of the Southern Andes between 38° and 40° S is formed by a NNW-elongated ridge not associated with stacked thrust sheets. On the contrary, during the last 4–3 Ma this ridge was affected by extensional deformation, regional uplift and related folding on a very broad scale. Receiver function analysis shows that the drainage divide area and adjacent retroarc lie over an attenuated crust. Expected crustal thickness at these latitudes is around 38 km, whereas in this part of the retroarc the thickness is less than 32 km. The causes for such attenuation have been linked to a moderate steepening of the subducted Nazca plate beneath the South American plate, which is suggested by a westward shift and narrowing of the magmatic arc during the last 4 to 5 Ma. Gravimetric studies show that the upper plate did not react homogeneously to slab steepening, but ancient sutures and lithospheric discontinuities deeply buried under Mesozoic to Cenozoic sequences in the retroarc were locally reactivated. These processes resulted in an asthenospheric anomaly that correlates at the surface with the area of Pliocene to Quaternary doming, widespread extension and three radial troughs. Two of the troughs have accommodated substantial amounts of extension, but the third was probably aborted at an early stage. Moreover, the presence of an anomalous concentration of calderas and large volcanic centers over the proposed asthenospheric anomaly, and their age distribution, may indicate minor migration of the asthenospheric anomaly between 4 and 2 Ma through the western South American plate.     

A Reflection on Mg, Cd, Ca, Li and Si Isotopic Measurements and Related Reference Materials

This contribution aims to report the reflections we had with the scientific community during two international workshops on reference materials for stable isotopes in Davos (2002) and Nice (2003). After evaluating the isotopic homogeneity of some existing reference materials, based on either certificates, literature data or specific inter-laboratory rounds, we confirm these as primary reference materials or propose new ones relative to which stable isotope compositions should be reported. We propose DSM-3 for Mg, NIST SRM 915a for Ca, L-SVEC for Li and NBS28 for Si. Cadmium does not yet have a well identified delta zero material, although three commercial mono-elemental Cd solutions have yielded the same isotopic composition relative to one another. In order to scale the linearity of any mass spectrometer, some secondary reference materials are also proposed: Cambridge-1 solution for Mg, the "Münster-Cd" and JEPPIM Cd solutions for Cd and the "Big Batch" silicate for Si. The team from Nancy propose to prepare a mixed spike solution for Li isotopes. Well-characterised natural samples such as ocean or continental waters, diatoms, sponges, rocks and minerals are needed to validate the entire analytical procedure, particularly to take into account the effect of sample mineralisation and of chemical manipulations for elemental separation prior to analysis.     

Mineralisation of amethyst-bearing geodes in Ametista do Sul (Brazil) from low-temperature sedimentary brines: evidence from monophase liquid inclusions and stable isotopes

Fluid inclusion studies in combination with hydrogen, oxygen and sulphur isotope data provide novel insights into the genesis of giant amethyst-bearing geodes in Early Cretaceous Paraná continental flood basalts at Amestita do Sul, Brazil. Monophase liquid inclusions in colourless quartz, amethyst, calcite, barite and gypsum were analysed by microthermometry after stimulating bubble nucleation using single femtosecond laser pulses. The salinity of the fluid inclusions was determined from ice-melting temperatures and a combination of prograde and retrograde homogenisation temperatures via the density maximum of the aqueous solutions. Four mineralisation stages are distinguished. In stage I, celadonite, chalcedony and pyrite formed under reducing conditions in a thermally stable environment. Low δ³⁴S_V-CDT values of pyrite (?25 to ?32?‰) suggest biogenic sulphate reduction by organotrophic bacteria. During the subsequent stages II (amethyst, goethite and anhydrite), III (early subhedral calcite) and IV (barite, late subhedral calcite and gypsum), the oxidation state of the fluid changed towards more oxidising conditions and microbial sulphate reduction ceased. Three distinct modes of fluid salinities around 5.3, 3.4 and 0.3 wt% NaCl-equivalent characterise the mineralisation stages II, III and IV, respectively. The salinity of the stage I fluid is unknown due to lack of fluid inclusions. Variation in homogenisation temperatures and in δ¹⁸O values of amethyst show evidence of repeated pulses of ascending hydrothermal fluids of up to 80–90 °C infiltrating a basaltic host rock of less than 45 °C. Colourless quartz and amethyst formed at temperatures between 40 and 80 °C, while the different calcite generations and late gypsum precipitated at temperatures below 45 °C. Calculated oxygen isotope composition of the amethyst-precipitating fluid in combination with δD values of amethyst-hosted fluid inclusions (?59 to ?51?‰) show a significant ¹⁸O-shift from the meteoric water line. This ¹⁸O-shift, high salinities of the fluid inclusions with chloride-sulphate composition, and high δ³⁴S values of anhydrite and barite (7.5 to 9.9?‰) suggest that sedimentary brines from deeper parts of the Guaraní aquifer system must have been responsible for the amethyst mineralisation.