Spectral gamma‐ray logs and palaeoclimate change? Permian–Triassic,Persian Gulf

Spectral gamma ray (SGR) logs are used as stratigraphic tools in correlation, sequence stratigraphy and most recently, in clastic successions as a proxy for changes in hinterland palaeoweathering. In this study we analyse the spectral gamma ray signal recorded in two boreholes that penetrated the carbonate and evaporate‐dominated Permian–Triassic boundary (PTB) in the South Pars Gasfield (offshore Iran, Persian Gulf) in an attempt to analyse palaeoenvironmental changes from the upper Permian (Upper Dalan Formation) and lower Triassic (Lower Kangan Formation). The results are compared to lithological changes, total organic carbon (TOC) contents and published stable isotope ( δ ¹⁸O, δ ¹³C) results. This work is the first to consider palaeoclimatic effects on SGR logs from a carbonate/evaporate succession. While Th/U ratios compare well to isotope data (and thus a change to less arid hinterland climates from the Late Permian to the Early Triassic), Th/K ratios do not, suggesting a control not related to hinterland weathering. Furthermore, elevated Th/U ratios in the Early Triassic could reflect a global drawdown in U, rather than a more humid episode in the sediment hinterlands, with coincident changes in TOC. Previous work that used spectral gamma ray data in siliciclastic successions as a palaeoclimate proxy may not apply in carbonate/evaporate sedimentary rocks. Copyright © 2014 John Wiley & Sons, Ltd.     

Cutting with both arms of the scissors: the economic and political case for restrictive supply-side climate policies

Proponents of climate change mitigation face difficult choices about which types of policy instrument(s) to pursue. The literature on the comparative evaluation of climate policy instruments has focused overwhelmingly on economic analyses of instruments aimed at restricting demand for greenhouse gas emissions (especially carbon taxes and cap-and-trade schemes) and, to some extent, on instruments that support the supply of or demand for substitutes for emissions-intensive goods, such as renewable energy. Evaluation of instruments aimed at restricting the upstream supply of commodities or products whose downstream consumption causes greenhouse gas emissions—such as fossil fuels—has largely been neglected in this literature. Moreover, analyses that compare policy instruments using both economic and political (e.g. political “feasibility” and “feedback”) criteria are rare. This article aims to help bridge both of these gaps. Specifically, the article demonstrates that restrictive supply-side policy instruments (targeting fossil fuels) have numerous characteristic economic and political advantages over otherwise similar restrictive demand-side instruments (targeting greenhouse gases). Economic advantages include low administrative and transaction costs, higher abatement certainty (due to the relative ease of monitoring, reporting and verification), comprehensive within-sector coverage, some advantageous price/efficiency effects, the mitigation of infrastructure “lock-in” risks, and mitigation of the “green paradox”. Political advantages include the superior potential to mobilise public support for supply-side policies, the conduciveness of supply-side policies to international policy cooperation, and the potential to bring different segments of the fossil fuel industry into a coalition supportive of such policies. In light of these attributes, restrictive supply-side policies squarely belong in the climate policy “toolkit”.     

Coastal sedimentation associated with the December 12th, 1992 tsunami in Flores,Indonesia

This paper presents the result of a detailed granulometric investigation of sediments deposited by a modern tsunami, the 1992 tsunami in Flores, Indonesia. Eyewitness accounts indicate that sediments were deposited upon coastal lowlands over wide areas as a result of the tsunami inundation. Distinctive vertical and lateral variations in particle size composition are characteristic features of the tsunami deposits and these are intimately related to sedimentary processes associated with flood inundation. The geomorphological and sedimentary evidence is used here to establish a preliminary model of tsunami sedimentation. This information is believed to be of great value in understanding sedimentary processes associated with tsunami flooding and in the interpretation of palaeo-tsunami deposits.     

Selection of integration time intervals for quartz OSL decay curves

In quartz optically stimulated luminescence (OSL) dating protocols, an initial integral of the OSL decay curve is used in the calculation of equivalent dose, once a background integral has been subtracted. Because the OSL signal commonly contains a number of exponentially decaying components, the exact choice of time intervals used for the initial-signal and background integrals determines the composition of the net signal. Here we investigate which combination of time intervals will produce the net signal most dominated by the fast OSL component, while keeping an acceptable level of precision. Using a three-component model of OSL decay, we show that for a specified level of precision, the net signal most dominated by the fast component can be obtained when the background integral immediately follows the initial signal and is approximately 2.5 times its length. With this ‘early-background’ approach, the contribution of slow components to the net signal is virtually zero. We apply our methods to four samples from relatively young deposits. Compared to the widely used ‘late-background’ approach, in which the background integral is taken from the last few seconds of OSL, we find less thermal transfer, less recuperation and a higher proportion of aliquots yielding an equivalent dose in agreement with expectations. We find the use of an early background to be a simple and effective way of improving the accuracy of OSL dating, and suggest is should be used in standard protocols.     

Paraglacial modification of slope form

The morphological consequences of paraglacial modification of valley-side drift slopes are investigated at six sites in Norway. Here, paraglacial slope adjustment operates primarily through the development of gully systems, whereby glacigenic sediment is stripped from the upper drift slope and redeposited in debris cones downslope. This results in an overall lowering of average gradient by up to 4·5° along gully axes. In general, slope profile adjustment appears to be characterized by a convergence of slope profiles towards an ‘equilibrium form’ with an upper rectilinear slope gradient at 29°± 4° and a range of concavities of approximately 0·0 to 0·4. After initial rapid incision, further gully deepening is limited, but gullies become progressively wider as sidewall gradients decline to c. 25°, after which parallel retreat appears to predominate. The final form of mature paraglacial gully systems consists of an upper bedrock-floored source area, a mid-slope area of broad gullies whose sidewalls rest at stable, moderate gradients, and a lower slope zone where gullies discharge onto the surfaces of debris cones and fans. Some gullies appear to have attained this final form and have stabilized following exhaustion of readily entrainable sediment within decades of gully initiation. At most sites, paraglacial activity has transformed steep drift-mantled valley sides into gullied slopes where an average of c. 2–3 m of surface lowering has taken place. At the most active sites, these average amounts imply minimum erosion rates averaging c. 90 mm a⁻¹ since gully initiation, which highlights the extreme rapidity of paraglacial erosion of deglaciated drift-mantled slopes. Copyright © 1999 John Wiley & Sons, Ltd.     

A GIS-based approach to site vegetated buffer strips for erosion control within an agricultural catchment in southern England

Agricultural soil erosion is largely attributed to arable intensification and increased mechanization. Runoff from arable land and intensively managed grassland transports sediment and contaminants across the landscape and into watercourses, causing crop loss, land degradation, and water quality issues. One low-cost and low-maintenance nature-based mitigation approach is the implementation of vegetated buffer strips (VBS): grassland sited along field margins to trap sediment and contaminants, reducing transportation and diffuse pollution rates. GIS modelling using remotely sensed landscape indices and land parcel data can provide an efficient means of identifying priority areas for intervention at sub-catchment or farm system scales. We develop and test a scalable runoff risk model in the lower Rother catchment, West Sussex. The model uses the Normalized Difference Vegetation Index (NDVI) applied to satellite images as an erodibility proxy and identifies locations along pathways that are conceivably at greatest risk of sediment accumulation and transfer, guided by field observations. We assess current and historical field boundaries near high-risk locations, evaluating the potential capacity of their margins to contribute to runoff risk reduction using an innovative ranking system. Recommendations are made for VBS implementation and the value of historical field boundary and margin restoration is discussed. Our method offers a rapid approach with minimal data requirements to identify high-risk sediment runoff locations and priority sites for intervention. The tool has the potential to guide decision-makers responsible for targeting and implementing soil erosion and runoff control measures such as VBS, while also maximizing agri-environmental and cultural benefits.     

Measurement and calculation of OH reactivity at a United Kingdom coastal site

Measurements of OH reactivity were made at the Weybourne Atmospheric Observatory on the North Norfolk coast, UK in May 2004. A wide range of supporting species was also measured concurrently as part of the TORCH-2 field campaign, allowing a detailed study of the OH oxidation chemistry to be carried out. Measurements were made in a variety of air masses, with the 3 most prevalent being air from the Atlantic that arrived at the site from over mainland UK in a South Westerly direction, and much cleaner Northerly air that originated over the far North Sea or Arctic, passed over the North Sea and arrived at the site from a North/North Easterly direction. Direct OH reactivity measurements were made on 6 days during the campaign and with influence of 2 of the 3 air masses prevalent during the study period. The average, minimum and maximum measured OH reactivity are: 4.9, 1.3 and 9.7 respectively. The measured OH reactivity was compared to key OH sinks such as NO₂ and CO and a general positive correlation was observed. OH reactivity (k′) was then calculated using the full range of OH sinks species that were measured (including >30 NMHCs) and their pseudo first order rate constants for reaction with OH. For much of the measurement period there is a significant difference between the measured and calculated k′, with an average value of k′_meas- k′_calc?=?1.9 s^-1, indicative of unmeasured OH sinks. A zero-dimensional box model containing a subset of the Master Chemical Mechanism was used to calculate the OH reactivity more accurately. The simultaneously measured trace species were used as inputs to the model and their oxidative degradation was described by a chemical mechanism containing ~5,000 species. The extra OH sinks species produced by the model, resulted in an improvement in the agreement between k′_meas and k′_calc, however the averaged missing OH reactivity across the entire measurement period remained at 1.4 s^-1. Speculation is made as to the source of this missing reactivity, including reference to studies showing that a potentially large number of high molecular weight aromatic species could be unmeasured by standard instrumentation.     

HgO at high pressures: the transition to the NaCl structure (HgO-III) and the equation of state of tetragonal HgO-II

The high-pressure behavior of HgO-montroydite was investigated up to 36.5 GPa using angle-dispersive X-ray diffraction. The tetragonal phase of this material (HgO-II), a distortion of the NaCl structure, transforms into the cubic NaCl structure (HgO-III) above ~31.5 GPa. The transformation of mercury oxide from the orthorhombic Pnma (HgO-I) structure to a tetragonal I4/mmm structure (HgO-II) is confirmed to occur at 13.5 ± 1.5 GPa. Neither of the high-pressure phases, HgO-II nor HgO-III, is quenchable in pressure. The derived isothermal bulk modulus of HgO-II and its pressure derivative strongly depend on the assumed zero-pressure volume of this phase, but our elasticity results on HgO-II nevertheless lie significantly closer to theoretical calculations than prior experimental results, and the measured pressure of the phase transformation to the NaCl structure is also in agreement with recent theoretical results. The general accord with theory supports the existence of significant relativistic effects on the high-pressure phase transitions of HgO.