Changing grading of soil: effect on critical states

Examples of situations are presented where the grading of a soil changes during its lifetime either by crushing of particles leading to an increase of fine material or by slow transport of fine particles with seepage leading to a decrease of fine material. Such grading changes influence the basic constitutive properties of the soil, in particular properties such as critical states which are dependent on the available range of densities of packing. Discrete element modelling is used to show the dependence of critical state conditions on grading and the way in which the particle assembly seeks out new critical state conditions as the grading changes.     

Solubility of Pt and Pd sulfides and Au metal in aqueous bisulfide solutions

An experimental study of the solubility of Pt and Pd sulfides and Au metal in aqueous bisulfide solutions was conducted at temperatures from 200° to 350 °C and at saturated vapor pressure. A 500-mL Bridgemantype pressure vessel constructed of titanium, and equipped with a motor-driven magnetic stirrer was employed. The pH and the oxidation state were buffered by the coexistence of H₂S/HS^–/SO _inf4 ^sup2– . The pH at temperature was calculated to be in the range 5.91–9.43, and S was 0.3–2.2 m. Under the experimental conditions, the measured solubility of gold is about two to three orders of magnitude greater than that of either platinum and palladium, and the measured solubility of platinum is, in general, approximately equal to that of palladium, in molal units. The solubilities are found to be in the range: platinum 4–800 ppb, palladium 1–400 ppb, and gold 2–300 ppm. The solubility data can be modeled adequately using the following reactions: Au+H₂S+HH^–=Au(HS) ₂ ^– +1/2H₂ (K₁₄); PtS+HS^–+H⁺=Pt (HS) ₂ ⁰ (K₁₅); PdS+HS^–+H⁺=Pd (HS) ₂ ⁰ (K₁₆); PtS₂+H₂=Pt (HS) ₂ ⁰ (K₂₁).With equilibrium constants determined as follows (errors represent two standard deviations): Preliminary measurements of the solubilities of metallic Pt, Pd and Au as hydroxide complexes were also conducted using a second titanium pressure vessel, at temperatures of 200° to 350 °C and vapor saturation pressure, with pH and the oxidation state controlled or buffered by adding known amounts of NaOH and H₂ gas. The concentration of NaOH was in the range 0.01–1.3 m, and the partial pressure of H₂ at 200 °C was 62–275 bars, initially. Under the temperature and pressure conditions of these experiments, the solubility of platinum in 1 m NaOH solution is less than 100 ppb, that of palladium is less than 10 ppb and that of gold is less than 0.2 ppm; and in 0.01 m NaOH solutions, both Pt and Pd solubilities are less than 1 ppb. These data indicate that the contributions of hydroxide complexes to the total solubilities in the bisulfide runs, where the pH was in the range of 5.9–9.4, are negligible. The concentrations of both Pt and Pd as bisulfide complexes in the Salton Sea geothermal system predicted using the stability constants determined in this work agree very well with those values measured by McKibben et al. (1990). This calculation strongly suggests that the PGE are transported in moderately reducing, near neutral hydrothermal fluids as bisulfide complexes, as is gold. However, the much lower maximum solubility of the PGE relative to gold severely constrains models of re genesis, and may explain the relative rarity of hydrothermal PGE deposits compared to the relative abundance of hydrothermal Au deposits.     

High spatial and spectral resolution 10-μm observations of jupiter

Ten-micrometer spectra of the North Tropical Zone, North Equatorial Belt, and Great Red Spot at a spectral resolution of 1.1 cm^?1 are compared to synthetic spectra. These ground-based spectra were obtained simultaneously with the Voyager 1 encounter with Jupiter in March, 1979. The NH₃ vertical distribution is found to decrease with altitude significantly faster than the saturated vapor pressure curve and is different for the three observed regions. Spatial variability in the NH₃ mixing ratio could be caused by changes in the amount of NH₃ condensation or in the degree of the NH₃ photolysis. The C₂H₆ emission at 12 μm has approximately the same strength at the North Tropical Zone and North Equatorial Belt, but it is 30% weaker at the Great Red Spot. A cooler temperature inversion or a smaller abundance of C₂H₆ could explain the lower C₂H₆ emission over the Great Red Spot.     

Measurements of magnetic fluxes and field strengths in the photospheric network

We present digital pictures of an active region network cell in five quantities, measured simultaneously: continuum intensity, line-center intensity, equivalent width, magnetogram signal, and magnetic field strength. These maps are derived from computer analysis of circularly polarized line profiles of FeI 5250.2; spectral and spatial resolution are 1/40 Å and 1.5, respectively. Measured Zeeman splittings show the existence of strong magnetic fields (1000–1800 G) at nearly all points with a magnetogram signal exceeding 125 G. The mean and rms deviation of the field strengths change by less than 20% over a factor-of-four range of fluxes. From the significant disparity between measured fluxes and field strengths, we conclude that large flux patches (up to 4 across) consist of closely-packed unresolved filaments. The smallest filaments must be less than 0.7 in diameter. We also observe the dark component of the photospheric network, which appears to contain sizable transverse fields.     

Airborne total eclipse observation of the extreme solar limb at 400 μm

The total solar eclipse of February 26, 1979 was monitored at far infrared wavelengths from the NASA Lear Jet Observatory flying at 12.9 km in the eclipse shadow. The resultant eclipse curve for radiation within a bandwidth of 20 cm^–1 centered upon 25 cm^–1 (400 m) was measured and analysed at an equivalent angular resolution of 1 arc sec over a 100 arc sec region adjacent to the limb to provide information on the intensity distribution of continuum radiation close to this limb. The curve has been compared to predictions derived from models of the solar atmosphere for the specific geometry of this eclipse, and is shown to match most closely that derived from a uniform distribution of radiation across the disk. This is in distinct contrast to the result obtained in the only other comparable experiment, carried out over Africa in 1973 from a supersonic Concorde aircraft, in which an intense but narrow spike of far infrared radiation at the extreme solar limb was inferred from the data. The absence also in the present observations of the significant limb brightening predicted by the HSRA model (in which homogeneity within the source region is assumed) is in substantial agreement with lower resolution results from mountain altitudes. This result is interpreted as further evidence for the presence in the Sun's lower chromosphere of significant inhomogeneity with a scale size of at least 1000 km at this depth.     

Solar radio bursts of spectral type II,coronal shocks,and optical coronal transients

The association of solar radio bursts of spectral type II and coronal shocks with solar flare ejecta observed in H, the green coronal line, and white-light coronagraphs is examined. Rather than identifying fast-moving optical coronal transients with outward-travelling shock waves that generate type II radio bursts, as has been suggested in some earlier papers, we suggest that, for the most part, such transients should probably be identified with piston-type phenomena well behind the shock. We then discuss a general model, consisting of three main velocity regimes, in which we relate type II radio bursts and coronal shocks to optically-observed ejecta.     

On the petrology and structure of a gravitionally differentiated moon of fission origin

In a previous paper, it was shown that the basic properties and the developmental history of a gravitationally differentiated Moon of fission origin match those known for the Moon. In the first part of this report, the models of a differentiated Moon are critically reviewed based on second order considerations of some of the chemical systems used to develope the earlier models and based on new lunar data. As a result, slightly updated models are developed and the results indicate that a Moon of fission origin has a feldspar rich crust (≈70% Or_0.8Ab_5.3An_93.9 with ≈30% pyroxene and olivine) reaching an average depth of ≈65 km. A KREEP rich layer is located at the interface of the crust and the upper mantle. The upper mantle consists of peridotite (≈80% Wo₁₀En₇₀Fs₂₀ and ≈20% Fo_75–80 with ≈3% Al₂O₃ and ≈ 2% TiO₂) and reaches a depth of 300–400 km. Below 300–400 km lies a dunite (≈Fo₉₅) lower mantle. A simple model for the distribution of K, U and Th (and by inference, KREEP) in the differentiated Moon model is developed using a distribution coefficient of 0.1 for the three elements. This coefficient is derived from published data on the distribution of U in Apollo 11 basalts. The simple model successfully accounts for the observed K, U and Th contents of the various mare basalts and upland rocks and yields a heat flow of 21 erg cm^?2s^?1 for the Moon. A model for the fine structure of the peridotite upper mantle of the model Moon is developed based on the TiO₂ and trace element variations observed in the various mare basalts. It is proposed that the upper mantle is rhythmically banded on the scale of 10's of km and that this banding leads to local variations of a factor of ±3 in the K, U and Th content, _-10 ⁺⁵ in the TiO₂ content and _-∞ ⁺² in the olivine content of the peridotite. It is also proposed that this banding leads to large scale horizontal inhomogenuities in the composition of the upper mantle. It is also shown that the formation of the primitive suite of upland rocks is easily explained by the cumulation of plagioclase, which carried varying amounts of pyroxene, olivine and melt with it, during the peritectic crystallization of the last 20% of the differentiating Moon. It is found that the 100 Mg/(Mg+Fe) ratios of the mafics and the An contents of the plagioclases of the rocks are controlled by several factors, the most important of which is the ratio of melt to crystals which together formed the various upland rocks. The inverse relationship between the An contents and the Mg contents of the upland rocks is a direct consequence of the differentiation sequence proposed. The results and models presented in this paper further support the hypothesis that the Moon formed as a result of fission from the proto-Earth.     

Boulder 1, Station 2, Apollo 17: Petrology and petrogenesis

Boulder 1, Station 2, Apollo 17 is a stratified boulder containing dark clasts and dark-rimmed light clasts set in a light-gray friable matrix. The gray to black clasts (GCBx and BCBx) are multigenerational, competent, high-grade metamorphic, and partially melted breccias. They contain a diverse suite of lithic clasts which are mainly ANT varieties, but include granites, basaltic-textured olivine basalts, troctolitic and spinel troctolitic basalts, and unusual lithologies such as KREEP norite, ilmenite (KREEP) microgabbro, and the Civet Cat norite, which is believed to be a plutonic differentiate. The GCBxs and BCBxs are variable in composition, averaging a moderately KREEPy olivine norite. The matrix consists of mineral fragments derived from the observed lithologies plus variable amounts of a component, unobserved as a clast-type, that approximates a KREEP basalt in composition, as well as mineral fragments of unknown derivation. The high-temperature GCBxs cooled substantially before their incorporation into the friable matrix of Boulder 1. The light friable matrix (LFBx) is texturally distinct from the competent breccia clasts and, apart from the abundant ANT clasts, contains clasts of a KREEPy basalt that is not observed in the competent breccias. The LFBx lacks such lithologies as the granites and the Civet Cat norite observed in the competent breccias and in detail is a distinct chemical as well as textural entity. We interpret the LFBx matrix as Serenitatis ejecta deposited in the South Massif, and the GCBx clasts as remnants of an ejecta blanket produced by an earlier impact. The source terrain for the Serenitatis impact consisted of the competent breccias, crustal ANT lithologies, and the KREEPy basalts, attesting to substantial lunar activity prior to the impact. The age of the older breccias suggests that the Serenitatis event is younger than 4.01±0.03 b.y.