Iron(III) accumulations in inland saline waterways,Hunter Valley,Australia: Mineralogy,micromorphology and pore-water geochemistry

Discharge of Fe(II)-rich groundwaters into surface-waters results in the accumulation of Fe(III)-minerals in salinized sand-bed waterways of the Hunter Valley, Australia. The objective of this study was to characterise the mineralogy, micromorphology and pore-water geochemistry of these Fe(III) accumulations. Pore-waters had a circumneutral pH (6.2–7.2), were sub-oxic to oxic (Eh 59–453 mV), and had dissolved Fe(II) concentrations up to 81.6 mg L⁻¹. X-ray diffraction (XRD) on natural and acid-ammonium-oxalate (AAO) extracted samples indicated a dominance of 2-line ferrihydrite in most samples, with lesser amounts of goethite, lepidocrocite, quartz, and alumino-silicate clays. The majority of Fe in the samples was bound in the AAO extractable fraction (Fe^Ox) relative to the Na-dithionite extractable fraction (Fe^Di), with generally high Fe^Ox:Fe^Di ratios (0.52–0.92). The presence of nano-crystalline 2-line ferrihydrite (Fe₅HO₃·4H₂O) with lesser amounts of goethite (α-FeOOH) was confirmed by scanning electron microscopy (SEM) coupled with energy dispersive X-ray analysis (EDX), and transmission electron microscopy (TEM) coupled with selected area electron diffraction (SAED). In addition, it was found that lepidocrocite (γ-FeOOH), which occurred as nanoparticles as little as ∼5 lattice spacings thick perpendicular to the (0 2 0) lattice plane, was also present in the studied Fe(III) deposits. Overall, the results highlight the complex variability in the crystallinity and particle-size of Fe(III)-minerals which form via oxidation of Fe(II)-rich groundwaters in sand-bed streams. This variability may be attributed to: (1) divergent precipitation conditions influencing the Fe(II) oxidation rate and the associated supply and hydrolysis of the Fe(III) ion, (2) the effect of interfering compounds, and (3) the influence of bacteria, especially Leptothrix ochracea.     

Seasonal and solar cycle association of zonal drifts of ionospheric plasma irregularities in the Indian equatorial region

Long series of simultaneous VHF scintillation observations at two stations situated in near magnetic east-west direction in the vicinity of the dip equator in the Indian region have been employed to investigate the night-time ionospheric plasma zonal drifts. The drifts are found to be predominantly easterly. On comparing the magnitudes of the drifts with those results derived earlier by HF fading technique, monitoring signals from two satellites at a station and spaced receiver experiment, their associations with the season and the degree of solar activity are discussed. On a broader scale, the annual mean sunspot number is shown to have a direct control on the derived drift, the positive relationship even on day to day basis with the solar flux is established. However, the relationship, as understood by the slope of the best fit line, in the Indian region (0.27) is found to be weaker when compared with the similar slope (0.45) in the American sector. There appears to be no geomagnetic activity control on the estimated drifts.     

A comparative study of the performance of various vertical discretization schemes

Summary Most finite-difference numerical weather prediction models employ vertical discretizations that are staggered, and are low-order (usually second-order) approximations for the important terms such as the derivation of the geopotential from the hydrostatic equation, and the calculation of the vertically integrated divergence. In a sigma-coordinate model the latter is used for computing both the surface pressure change and the vertical velocity. All of the above-mentioned variables can diminish the accuracy of the forecast if they are not calculated accurately, and can have an impact on related quantities such as precipitation.In this study various discretization schemes in the vertical are compared both in theory and in practice. Four different vertical grids are tested: one unstaggered and three staggered (including the widely-used Lorenz grid). The comparison is carried out by assessing the accuracy of the grids using vertical numerics that range from second-order up to sixth-order.The theoretical part of the study examines how faithfully each vertical grid reproduces the vertical modes of the governing equations linearized with a basic state atmosphere. The performance of the grids is evaluated for 2nd, 4th and 6th-order numerical schemes based on Lagrange polynomials, and for a 6th-ordercompact scheme.Our interpretation of the results of the theoretical study is as follows. The most important result is that the order of accuracy employed in the numerics seems to be more significant than the choice of vertical grid. There are differences between the grids at second-order, but these differences effectively vanish as the order of accuracy increases. The sixth-order schemes all produce very accurate results with the grids performing equally well, and with the compact scheme significantly outperforming the Lagrange scheme. A second major result is that for the number of levels typically used in current operational forecast models, second-order schemes (which are used almost universally) all appear to be relatively poor, for other than the lowest modes.The theoretical claims were confirmed in practice using a large number (100) of forecasts with the Australian Bureau of Meteorology Research Centre's operational model. By comparing test model forecasts using the four grids and the different orders of numerics with very high resolution control model forecasts, the results of the theoretical study seem to be corroborated.With 8 Figures     

Intra-oceanic settings of the western Mexico Late Jurassic-Early Cretaceous arc sequences. Implications for the Pacific-Tethys geodynamic relationships during the Cretaceous

Abstract

The Guerrero suspect terrane composed of Late Jurassic-Early Cretaceous sequences, extends from Baja California up to Acapulco and is considered to be coeval with the Late Mesozoic igneous and sedimentary arc sequences of the Greater Antilles, Venezuela and Western Cordillera of Colombia. New geological, petrological and geochemical data from central and southern Mexico, led us to propose a new model for the building of the Alisitos-Teloloapan arc. This arc, partly built on the Pacific oceanic lithosphere and partly on continental fragments, could be related to the subduction of an oceanic basin - the Arperos basin - under the Paleo-Pacific plate. This subduction was dipping southwest.

At the beginning of the magmatic activity of the oceanic segment of this arc, depleted tholeiitic basalts were emitted in a submarine environnement below the CCD. While subduction was going on, the arc magmas evolved from LREE depleted tholeiites to slightly LREE enriched tholeiites and then, to calc-alkaline basalts and andesites enriched in LREE and HFSE. Concurrently, the arc sedimentary environment changed from deep oceanic to neritic with the deposition of Aptian-Albian reefal limestones, at the end of the arc building. In the continent-based segment, the arc magmas are exclusively differentiated calc-alkaline suites depleted in HREE and Y, formed of predominantly siliceous lavas and pyroclastic rocks, emitted in a sub-aerial or shallow marine environment.

Thus, taking into account this above mentioned model, the Cretaceous volcanic series, accreted to the margins of cratonal America, in Colombia, Venezuela, Greater Antilles and Mexico, could be related to the same west-south-west dipping subduction of oceanic basins, fringing the North and South American continental cratons and connected directly with the inter-American Tethys. While the subduction was proceeding, this magmatic arc drifted towards the North and South American cratons and finally, collided with the continental margins at different periods during the Cretaceous.     

Theory of Basin Scale Dynamics of a Stratified Rotating Fluid

The dynamics of a stratified fluid contained in a rotating rectangular box is described in terms of the evolution of the lowest moments of its density and momentum fields. The first moment of the density field also gives the position of the fluids centre-of-mass. The resulting low-order model allows for fast assessment both of adopted parameterisations, as well as of particular values of parameters. In the ideal fluid limit (neglect of viscous and diffusive effects), in the absence of wind, the equations have a Hamiltonian structure that is integrable (non-integrable) in the absence (presence) of differential heating. In a non-rotating convective regime, dynamically rich behaviour and strong dependence on the single (lumped) parameter are established. For small values of this parameter, in a self-similar regime, further reduction to an explicit map is discussed in an Appendix. Introducing rotation in a nearly geostrophic regime leads through a Hopf bifurcation to a limit cycle, and under the influence of wind and salt to multiple equilibria and chaos, respectively.     

Cyclic inelastic behavior and analytical modelling of pile–leg interaction in jacket type offshore platforms

Structures in locations susceptible to severe seismic disturbances should be designed properly in order to resist lateral forces induced by earthquake motions. Steel offshore platforms are some of those structures which are built to withstand environmental and accidental loads during oil exploitation operation. Particular attention is being paid to earthquake loads in seismic active areas because it directly influences the capacity of the offshore installations.

In this paper, a small-scaled planar platform has been modelled analytically using nonlinear finite element program, based on an experimental test, conducted simultaneously in order to assess the local and global behavior of pile–leg interaction in Jacket Type Offshore Platforms (JTOPs). A combination of nonlinear beam column elements and fatigue affected elements are used to capture the inelastic cyclic behavior of planar frame as accurately as possible. Results of analytical tests are to be compared with experiments and it is concluded that an analytical approach can be best used for modelling JTOPs with reasonable accuracy regardless of the type and scale of the structure. Moreover, a special study on joints has been carried out and the best model has been selected to simulate brittle behavior of joints resulting from heat affected zone.     

Flood‐based analysis of high‐magnitude sediment transport using a non‐parametric method

Upland erosion and the resulting reservoir siltation is a serious issue in the Isábena catchment (445 km² Central Spanish Pyrenees). During a three‐month period, water and sediment fluxes have been monitored at the catchment outlet (Capella), two adjacent subcatchments (Villacarli, 41 km²; Cabecera, 145 km²) and the elementary badland catchment Torrelaribera (8 ha). This paper presents the results of the monitoring, a method for the calculation of a sedigraph from intermittent measurements and the derived sediment yields at the monitored locations. The observed suspended sediment concentrations (SSCs) demonstrate the role of badlands as sediment sources: SSCs of up to 280 g l^?1 were encountered for Villacarli, which includes large badland areas. SSCs at the Cabecera catchment, with great areas of woodland, barely exceeded 30 g l^?1. SSCs directly at the sediment source (Torrelaribera) were comparable to those at Villacarli, suggesting a close connection within this subcatchment. At Capella, SSCs of up to 99 g l^?1 were observed. For all sites, SSC displayed only a loose correlation with discharge, inhibiting the application of a simple sediment rating curve. Instead, ancillary variables acting as driving forces or proxies for the processes (rainfall energy, cumulative discharge, rising/falling limb data) were included in a quantile regression forest model to explain the variability in SSC. The variables with most predictive power vary between the sites, suggesting the predominance of different processes. The subsequent flood‐based calculation of sediment yields attests high specific sediment yields for Torrelaribera and Villacarli (6277 and 1971 t km^?2) and medium to high yields for Cabecera and Capella (139 and 410 t km^?2) during the observation period. In all catchments, most of the sediment was exported during intense storms of late summer. Later flood events yield successively less sediment. Relating upland sediment production to yield at the outlet suggests considerable effects of sediment storage within the river channel. Copyright © 2008 John Wiley & Sons, Ltd.     

Meteoric Be in soil profiles - A global meta-analysis

In order to assess current understanding of meteoric ¹⁰Be dynamics and distribution in terrestrial soils, we assembled a database of all published meteoric ¹⁰Be soil depth profiles, including 104 profiles from 27 studies in globally diverse locations, collectively containing 679 individual measurements. This allows for the systematic comparison of meteoric ¹⁰Be concentration to other soil characteristics and the comparison of profile depth distributions between geologic settings. Percent clay, ⁹Be, and dithionite-citrate extracted Al positively correlate to meteoric ¹⁰Be in more than half of the soils where they were measured, but the lack of significant correlation in other soils suggests that no one soil factor controls meteoric ¹⁰Be distribution with depth. Dithionite-citrate extracted Fe and cation exchange capacity are only weakly correlated to meteoric ¹⁰Be. Percent organic carbon and pH are not significantly related to meteoric ¹⁰Be concentration when all data are complied.The compilation shows that meteoric ¹⁰Be concentration is seldom uniform with depth in a soil profile. In young or rapidly eroding soils, maximum meteoric ¹⁰Be concentrations are typically found in the uppermost 20 cm. In older, more slowly eroding soils, the highest meteoric ¹⁰Be concentrations are found at depth, usually between 50 and 200 cm. We find that the highest measured meteoric ¹⁰Be concentration in a soil profile is an important metric, as both the value and the depth of the maximum meteoric ¹⁰Be concentration correlate with the total measured meteoric ¹⁰Be inventory of the soil profile.In order to refine the use of meteoric ¹⁰Be as an estimator of soil erosion rate, we compare near-surface meteoric ¹⁰Be concentrations to total meteoric ¹⁰Be soil inventories. These trends are used to calibrate models of meteoric ¹⁰Be loss by soil erosion. Erosion rates calculated using this method vary based on the assumed depth and timing of erosional events and on the reference data selected.