The star-forming content of the W3 giant molecular cloud

We have surveyed a ∼0.9 square degree area of the W3 giant molecular cloud (GMC) and star-forming region in the 850-μm continuum, using the Submillimetre Common-User Bolometer Array on the James Clerk Maxwell Telescope. A complete sample of 316 dense clumps were detected with a mass range from around 13 to  2500 M_⊙  . Part of the W3 GMC is subject to an interaction with the H  ii region and fast stellar winds generated by the nearby W4 OB association. We find that the fraction of total gas mass in dense, 850-μm traced structures is significantly altered by this interaction, being around 5–13 per cent in the undisturbed cloud but ∼25–37 per cent in the feedback-affected region. The mass distribution in the detected clump sample depends somewhat on assumptions of dust temperature and is not a simple, single power law but contains significant structure at intermediate masses. This structure is likely to be due to crowding of sources near or below the spatial resolution of the observations. There is little evidence of any difference between the index of the high-mass end of the clump mass function in the compressed region and in the unaffected cloud. The consequences of these results are discussed in terms of current models of triggered star formation.     

Role of hypsometry and planform in basin hydrologic response

The effects of variations of drainage basin morphometry and relief characteristics on flood peak magnitude and time-to-peak are investigated using simulated stream networks. The networks are produced by three models: headward growth, systematic capture, and minimum power relaxation. Translational and kinematic wave flood routing were used to generate synthetic hydrographs. Peak discharge and time-to-peak are predictable to a high degree by five different sets of morphometric-relief parameters. In order of decreasing order of importance in predictive ability the parameters characterize basin size, relative relief, basin concavity, and basin shape. Both simulated and natural stream networks exhibit strong dependence of planimetric morphometry upon basin concavity. The effect of this dependency is to increase the effect of basin concavity upon flood hydrographs.     

The relationship between dissolved hydrogen and nitrogen fixation in ocean waters

Fixed nitrogen is a key nutrient involved in regulating global marine productivity and hence the global oceanic carbon cycle. Oceanic nitrogen (N₂) fixation is estimated to supply 8×10¹² moles N y^?1 to the ocean, approximately equal to current riverine and the atmospheric inputs of fixed N, and between 50 and 100% of current estimates of oceanic denitrification. However, the spatial and temporal variability of N₂ fixation remains uncertain, mostly because of the normal low resolution sampling for diazotroph distribution and fixation rates. It is well established that N₂ fixation, mediated by the enzyme nitrogenase, is a source of hydrogen (H₂), but the extent to which it leads to supersaturation of H₂ in oceanic waters is unresolved. Here, we present simultaneous measurements of upper ocean dissolved H₂ concentration (nmol L^?1), and rates of N₂ fixation (μmol N m^?3 d^?1), determined using ¹⁵N₂ tracer techniques (at 7 or 15 m), on a transect from Fiji to Hawaii. We find a significant correlation (r=0.98) between dissolved H₂ and rates of N₂ fixation, with the greatest supersaturation of H₂ and highest rates of N₂ fixation being observed in the subtropical gyres at the southern (～18°S) and northern (18°N) reaches of the transect. The lowest H₂ saturation and N₂ fixation were observed in the equatorial region between 8°S and 14°N. We propose that an empirical relationship between H₂ supersaturations and N₂ fixation measurements could be used to guide sampling for ¹⁵N fixation measurements or to aid the spatial interpolation of such measurements.     

Ammonia-water ice laboratory studies relevant to outer Solar System surfaces

Although water- and ammonia-ices have been observed or postulated as important components of the icy surfaces of planetary satellites in the outer Solar System, significant gaps exist in our knowledge of the spectra and behavior of such mixtures under astrophysical conditions. To that end, we have completed low-temperature spectroscopic studies (1-20 μm) of water-ammonia mixtures, with an emphasis on features in the near-IR, a region which is accessible to ground-based observations. The influences of composition, formation temperature, thermal- and radiation-processing, and phase (crystalline or amorphous) of the components were examined. Spectra of both pure NH₃ and H₂O-NH₃ icy mixtures with ratios from 0.7 to 57 were measured at temperatures from 10 to 120 K. Conditions for the formation and thermal stability of the ammonia hemihydrate (2NH₃⋅H₂O) and the ammonia monohydrate (NH₃⋅H₂O) have been examined. Band positions of NH₃ in different H₂O-ices and major band positions of the hydrates were measured. We report spectral shifts that depend on concentration and temperature. The radiation-induced amorphization of the hemihydrate was observed and the radiation destruction of NH₃ in H₂O-ices was measured. Implications of these results for the formation, stability, and detection of ammonia on outer satellite surfaces are discussed.     

Methods for medium-term prediction of the net sediment transport by waves and currents in complex coastal regions

Medium-term prediction of sediment transport and morphological behaviour in the coastal zone is becoming increasingly important as a result of human interference and changing environmental conditions. The interaction of waves and tides is shown to play a pivotal role in the net (annual) sediment transport and morphodynamics of the coastal zone. The Telemac Modelling System has been applied to the Dyfi Estuary and neighbouring coastline, mid Wales, to recreate the annual wave–current conditions and the resulting sediment fluxes. ‘Input reduction’ methods have been required to produce realistic schematisations of events in practical computation times. A field campaign carried out in 2006 provided data for validation of the flow module (Telemac-2D) and also observations to verify the patterns predicted by the wave module (Tomawac). To improve model accuracy refinements were implemented with regard to the sand transport formulation used in the sand transport module (Sisyphe). Here, a parameterisation of the results from the UWB 1DV sand transport ‘research’ model, for the conditions in the Dyfi Estuary, has been introduced, allowing Sisyphe to provide greater realism in the morphological predictions. The model predictions are presented along with a discussion of the success/failure and limitations of the modelling methods applied.     

A Late‐glacial chironomid record from Hawes Water,northwest England

This paper presents the results of a high‐resolution Late‐glacial chironomid stratigraphy from Hawes Water, a small carbonate lake in northern Lancashire. The samples were from a core taken from the terrestrialised margin of the present lake, which represents an intermediate depth between the true littoral and the profundal. The chironomid assemblage showed a high degree of sensitivity to both broad‐scale and short‐term temperature changes. Comparison with an existing proxy temperature record (δ¹⁸O) for the site confirmed the presence of four temperature inversions within the Late‐glacial Interstadial. A mean July air temperature inference model, derived from acid, soft‐water lakes in Norway and Svalbard, was applied to the data. Despite the absence of carbonate lakes within the Norwegian training set, there was a close similarity between trends in estimated July air temperature and the δ¹⁸O trace, with a particularly strong correspondence in the periods of clay deposition. This suggests that this model is highly robust. The inferred maximum Interstadial temperature was 13.4°C, dropping initially to 7.5°C in the Loch Lomond Stadial. Temperatures reach a maximum of nearly 10°C in this period, cool for a short period before rising rapidly to 13.2°C at the start of the Holocene. These temperatures are similar to but slightly higher than those estimated for Whitrig Bog, southeast Scotland, and lower than those inferred from coleopteran‐based models for sites in South Wales. Copyright © 2004 John Wiley & Sons, Ltd.     

Shock and annealing in aubrites: Implications for parent‐body history

Several aubrites (e.g., LAP 03719, Bishopville, Khor Temiki, ALH 83015) contain orthopyroxene grains that exhibit more‐pronounced shock effects than associated olivine grains. The orthopyroxene grains in these samples have clinoenstatite lamellae on (100) and exhibit weak mosaic extinction, characteristic of shock stage S4; the olivine grains exhibit either sharp optical extinction, characteristic of shock stage S1 (as in LAP 03719), or undulose extinction (shock stage S2), as in Bishopville and ALH 83015. The Khor Temiki regolith breccia contains S1 and S2 olivine grains. Because literature data show that diffusion is much slower in orthopyroxene than in olivine, it seems likely that aubrites experienced postshock, impact‐induced annealing. After differentiation, the aubrite parent asteroid suffered major collisions that caused extensive brecciation of near‐surface materials and damaged orthopyroxene and olivine crystal lattices. As a result of these impact events, some aubrites were shocked and buried within warm ejecta blankets or beneath fallback debris under the crater floor. Entombed olivine crystal lattices healed (and became unstrained, reaching shock stage S1), but orthopyroxene lattices retained their S4‐level shock‐damaged features. Aubrites with S4 orthopyroxene and S2 olivine were probably very weakly shocked again after olivine was annealed to S1.     

Flattened chondrules in the LAP 04581 LL5 chondrite: Evidence for an oblique impact into LL3 material and subsequent collisional heating

Abstract– LaPaz Icefield (LAP) 04581 is a shock‐stage S2 LL5 chondrite that initially consisted of unrecrystallized LL3 material with a moderately abundant fine‐grained porous matrix (on the order of 15 vol%). A rare oblique impact created shearing stresses that produced a petrofabric in the rock, induced frictional melting of troilite (thereby forming a large troilite vein), and caused chondrule flattening. The latter process was facilitated by impact‐induced collapse of matrix pores. Chondrule flattening could not have occurred if the rock had been impacted after it had been metamorphosed to type 5 levels because the fine‐grained matrix would have previously recrystallized and developed low porosity. Ar‐Ar dating of LAP 04581 yields an age of 4175 Ma. This date is long after ²⁶Al had decayed away and most likely reflects the timing of a second impact event that shocked the rock to S4–S5 levels. The troilite vein became polycrystalline at this time and the whole rock was annealed to petrologic type 5, perhaps by being buried beneath hot ejecta of low thermal diffusivity. After annealing, the rock was weakly shocked to S2 levels. LAP 04581 serves as an example of impact‐induced heating being a viable mechanism for chondrite metamorphism.     

Compositions and taxonomy of 15 unusual carbonaceous chondrites

Abstract– We used instrumental neutron activation analysis and petrography to determine bulk and phase compositions and textural characteristics of 15 carbonaceous chondrites of uncertain classification: Acfer 094 (type 3.0, ungrouped CM‐related); Belgica‐7904 (mildly metamorphosed, anomalous, CM‐like chondrite, possibly a member of a new grouplet that includes Wisconsin Range (WIS) 91600, Dhofar 225, and Yamato‐86720); Dar al Gani (DaG) 055 and its paired specimen DaG 056 (anomalous, reduced CV3‐like); DaG 978 (type 3 ungrouped); Dominion Range 03238 (anomalous, magnetite‐rich CO3.1); Elephant Moraine 90043 (anomalous, magnetite‐bearing CO3); Graves Nunataks 98025 (type 2 or type 3 ungrouped); Grosvenor Mountains (GRO) 95566 (anomalous CM2 with a low degree of aqueous alteration); Hammadah al Hamra (HaH) 073 (type 4 ungrouped, possibly related to the Coolidge‐Loongana [C‐L] 001 grouplet); Lewis Cliff (LEW) 85311 (anomalous CM2 with a low degree of aqueous alteration); Northwest Africa 1152 (anomalous CV3); Pecora Escarpment (PCA) 91008 (anomalous, metamorphosed CM); Queen Alexandra Range 99038 (type 2 ungrouped); Sahara 00182 (type 3 ungrouped, possibly related to HaH 073 and/or to C‐L 001); and WIS 91600 (mildly metamorphosed, anomalous, CM‐like chondrite, possibly a member of a new grouplet that includes Belgica‐7904, Dhofar 225, and Y‐86720). Many of these meteorites show fractionated abundance patterns, especially among the volatile elements. Impact volatilization and dehydration as well as elemental transport caused by terrestrial weathering are probably responsible for most of these compositional anomalies. The metamorphosed CM chondrites comprise two distinct clusters on the basis of their Δ¹⁷O values: approximately ?4‰ for PCA 91008, GRO 95566, DaG 978, and LEW 85311, and approximately 0‰ for Belgica‐7904 and WIS 91600. These six meteorites must have been derived from different asteroidal regions.     

Impact melting in the Cumberland Falls and Mayo Belwa aubrites

Abstract– Six chondritic clasts in the Cumberland Falls polymict breccia were examined: four texturally resemble ordinary chondrites (OCs) and two are impact melt breccias containing shocked OC clasts adjacent to a melt matrix. The six chondritic clasts are probably remnants of a single OC projectile that was heterogeneously shocked when it collided with the Cumberland Falls host. Mayo Belwa is the first known aubrite impact melt breccia. It contains coarse enstatite grains exhibiting mosaic extinction; the enstatite grains are surrounded by a melt matrix composed of 3–16 μm‐size euhedral and subhedral enstatite grains embedded in sodic plagioclase. Numerous vugs, ranging from a few micrometers to a few millimeters in size, constitute ～5 vol% of the meteorite. They occur nearly exclusively within the Mayo Belwa matrix; literature data show that some vugs are lined with bundles of acicular grains of the amphibole fluor‐richterite. This phase has been reported previously in only two other enstatite meteorites (Abee and St. Sauveur), both of which are EH‐chondrite impact melt breccias. It seems likely that in Mayo Belwa, volatiles were vaporized during an impact event and formed bubbles in the melt. As the melt solidified, the bubbles became cavities; plagioclase and fluor‐richterite crystallized at the margins of these cavities via reaction of the melt with the vapor.