Os and Os enrichments and high-He/He sources in the Earth’s mantle: Evidence from Icelandic picrites

Picrites from the neovolcanic zones in Iceland display a range in ¹⁸⁷Os/¹⁸⁸Os from 0.1297 to 0.1381 (γ_Os = + 2.1 to +8.7) and uniform ¹⁸⁶Os/¹⁸⁸Os of 0.1198375 ± 32 (2σ). The value for ¹⁸⁶Os/¹⁸⁸Os is within uncertainty of the present-day value for the primitive upper mantle of 0.1198398 ± 16. These Os isotope systematics are best explained by ancient recycled crust or melt enrichment in the mantle source region. If so, then the coupled enrichments displayed in ¹⁸⁶Os/¹⁸⁸Os and ¹⁸⁷Os/¹⁸⁸Os from lavas of other plume systems must result from an independent process, the most viable candidate at present remains core-mantle interaction. While some plumes with high ³He/⁴He, such as Hawaii, appear to have been subjected to detectable addition of Os (and possibly He) from the outer core, others such as Iceland do not.A positive correlation between ¹⁸⁷Os/¹⁸⁸Os and ³He/⁴He from 9.6 to 19 Ra in Iceland picrites is best modeled as mixtures of 1 Ga or older ancient recycled crust mixed with primitive mantle or incompletely degassed depleted mantle isolated since 1-1.5 Ga, which preserves the high ³He/⁴He of the depleted mantle at the time. These mixtures create a hybrid source region that subsequently mixes with the present-day convecting MORB mantle during ascent and melting. This multistage mixing scenario requires convective isolation in the deep mantle for hundreds of million years or more to maintain these compositionally distinct hybrid sources. The ³He/⁴He of lavas derived from the Iceland plume changed over time, from a maximum of 50 Ra at 60 Ma, to approximately 25-27 Ra at present. The changes are coupled with distinct compositional gaps between the different aged lavas when ³He/⁴He is plotted versus various geochemical parameters such as ¹⁴³Nd/¹⁴⁴Nd and La/Sm. These relationships can be interpreted as an increase in the proportion of ancient recycled crust in the upwelling plume over this time period.The positive correlation between ¹⁸⁷Os/¹⁸⁸Os and ³He/⁴He demonstrates that the Iceland lava He isotopic compositions do not result from simple melt depletion histories and consequent removal of U and Th in their mantle sources. Instead their He isotopic compositions reflect mixtures of heterogeneous materials formed at different times with different U and Th concentrations. This hybridization is likely prevalent in all ocean island lavas derived from deep mantle sources.     

Influence of non-linear effects upon surge elevations along the west coast of Britain

A two-dimensional vertically integrated hydrodynamic finite-element model of the west coast of Britain is used to examine the response of the region to extreme meteorological forcing. The extent to which tide–surge interaction modifies the computed surge elevation and current distributions is examined in detail. The nature of the finite-element model with its ability to refine the mesh in nearshore regions is ideal for examining the influence of non-linear effects upon surges in these regions. Calculations using spatially uniform orthogonal wind stresses show that the surge elevation and current in shallow water are particularly sensitive to the method used to remove the tide as a result of the highly non-linear nature of the tide–surge interaction in these regions. The most accurate means of de-tiding the solution is by subtracting a tide derived by harmonic analysis of the tide and surge time series at the time of the surge. Subtracting a tide-only solution (the usual approach) leads to tidal energy leaking into the surge solution. Calculations show that this arises because the surge modifies the tidal amplitude and phase in shallow-water regions to such an extent that they are appreciably different to those found in the tide-only calculation. Results suggest that this problem becomes more important, as nearshore meshes are refined in an attempt to improve surge prediction. This suggests that in the future, highly accurate fine-mesh models will be required to compute total water levels without the present linear separation into tidal and surge signal used in operational surge prediction.     

On the sensitivity of computed higher tidal harmonics to mesh size in a finite element model

A finite element model of the Irish and Celtic Sea regions with a range of grid resolutions is used to examine the influence of resolution upon the higher harmonics of the tide in the region. Comparisons are also made with published results from finite difference models of the area, and observations. Calculations using fine near-shore elements with non-zero water depths in coastal regions were found to be more accurate and less time consuming than those using a zero coastal water depth. A detailed examination of the spatial variability of the higher harmonics in near-shore regions of the eastern Irish Sea particularly the Solway and Morecambe Bay showed significant small-scale variability. This together with the variation in higher harmonics in the eastern Irish Sea and adjacent estuaries, clearly shows the need for an unstructured grid model of the region that can include the estuaries. To match the high resolution of the model in near-shore regions accurate high-resolution topography is required.     

Climate and Rural Income

This paper tests whether climate has an impact on per capita rural income. The study finds that total (agricultural and nonagricultural) income in rural counties and municipios in the US and Brazil are affected by climate. The study demonstrates that this income effect is due to changes in the net value of agriculture. Regions with better climates for agriculture support higher rural incomes and regions with poor climates have more rural poverty. The results also suggest that global warming will likely increase rural poverty.     

An incentive mechanism for reducing emissions from conversion of intact and non-intact forests

This paper presents a new accounting mechanism in the context of the UNFCCC issue on reducing emissions from deforestation in developing countries, including technical options for determining baselines of forest conversions. This proposal builds on the recent scientific achievements related to the estimation of tropical deforestation rates and to the assessment of ‘intact’ forest areas. The distinction between ‘intact’ and ‘non intact’ forests used here arises from experience with satellite-based deforestation measurements and allows accounting for carbon losses from forest degradation. The proposed accounting system would use forest area conversion rates as input data. An optimal technical solution to set baselines would be to use historical average figures during the time period from 1990 to 2005. The system introduces two different schemes to account for preserved carbon: one for countries with high forest conversion rates where the desired outcome would be a reduction in their rates, and another for countries with low rates. A ‘global’ baseline rate would be used to discriminate between these two country categories (high and low rates). For the hypothetical accounting period 2013–2017 and considering 72% of the total tropical forest domain for which data are available, the scenario of a 10% reduction of the high rates and of the preservation of low rates would result in approximately 1.6 billion tCO₂ of avoided emissions. The resulting benefits of this reduction would be shared between those high-rate countries which reduced deforestation and those low-rate countries which did not increase their deforestation over an agreed threshold (e.g., half of “global” baseline rate).     

Looking inside stars and looking for planets

Asteroseismology and extrasolar planets are the main science goals of the Eddington mission, now approved by ESA for a 2007 launch. Alan Penny presents a summary of the January 2002 RAS meeting that discussed the sciences of this wide-field high-precision photometric space telescope. Since the date of this meeting, ESA has decided to implement the mission in the framework of a 2007–08 launch.     

The citric acid-MnO2(birnessite) reaction. Electron transfer, complex formation, and autocatalytic feedback

Citrate released by plants, bacteria, and fungi into soils is subject to abiotic oxidation by MnO₂(birnessite), yielding 3-ketoglutarate, acetoacetate, and Mn^II. Citrate loss and generation of products as a function of time all yield S-shaped curves, indicating autocatalysis. Increasing the citrate concentration decreases the induction period. The maximum rate (r_max) along the reaction coordinate follows a Langmuir-Hinshelwood dependence on citrate concentration. Increases in pH decrease r_max and increase the induction time. Adding Mn^II, Zn^II, orthophosphate, or pyrophosphate at the onset of reaction decreases r_max. Mn^II addition eliminates the induction period, while orthophosphate and pyrophosphate addition increase the induction period. These findings indicate that two parallel processes are responsible. The first, relatively slow process involves the oxidation of free citrate by surface-bound Mn^III,IV, yielding Mn^II and citrate oxidation products. The second process, which is subject to strong positive feedback, involves electron transfer from Mn^II-citrate complexes to surface-bound Mn^III,IV, generating Mn^III-citrate and Mn^II. Subsequent intramolecular electron transfer converts Mn^III-citrate into Mn^II and citrate oxidation products.     

Reaction of Mn (hydr)oxides with oxalic acid, glyoxylic acid, phosphonoformic acid, and structurally-related organic compounds

Phosphonoformic acid, oxalic acid, glyoxylic acid, and 10 additional organic compounds that are structurally related to them have been reacted with synthetic MnO₂ (birnessite), consisting of 22% Mn^III and 78% Mn^IV, and synthetic MnOOH (manganite), consisting solely of Mn^III. Significant concentrations of dissolved Mn^III were detected in reactions of phosphonoformic acid with MnOOH, indicating that ligand-assisted dissolution took place. Reaction of phosphonoformic acid with MnO₂, and reaction of all other organic reactants with either MnOOH or MnO₂, yielded only Mn^II, indicating that reductive dissolution was predominant. As far as reductive dissolution reactions are concerned, MnO₂ yields a range of reactivity that is nearly 20-times greater than that of MnOOH. Oxidation converts phosphonoformic acid into orthophosphate ion, glyoxylic acid into formic acid, pyruvic acid into acetic acid, and 2,3-butanedione into acetic acid. When differences in surface area loading are accounted for, oxalic acid, pyruvic acid, and 2,3-butanedione yield virtually the same dissolution rates for the two (hydr)oxides. At pH 5.0, glyoxylic acid reacts 14-times faster with MnO₂ than with MnOOH. MnO₂ reacts more slowly than MnOOH by a factor of 1/16th with oxamic acid, 1/20th with lactic acid, and 1/33rd with dimethyl oxalate. Adsorptive, complexant, and reductant properties of the 13 organic reactants are believed responsible for the observed reactivity differences.     

Evidence in CO3.0 chondrules for a drift in the O isotopic composition of the solar nebula

Abstract— Several recent studies have shown that materials such as magnetite that formed in asteroids tend to have higher Δ¹⁷O (=δ¹⁷O ? 0.52 × δ¹⁸O) values than those recorded in unaltered chondrules. Other recent studies have shown that, in sets of chondrules from carbonaceous chondrites, Δ¹⁷O tends to increase as the FeO contents of the silicates increase. We report a comparison of the O isotopic composition of olivine phenocrysts in low‐FeO (≤Fa₁) type I and high‐FeO (≥Fa₁₅) type II porphyritic chondrules in the highly primitive CO3.0 chondrite Yamato‐81020. In agreement with a similar study of chondrules in CO3.0 ALH A77307 by Jones et al. (2000), Δ¹⁷O tends to increase with increasing FeO. We find that Δ¹⁷O values are resolved (but only marginally) between the two sets of olivine phenocrysts. In two of the high‐FeO chondrules, the difference between Δ¹⁷O of the late‐formed, high‐FeO phenocryst olivine and those in the low‐FeO cores of relict grains is well‐resolved (although one of the relicts is interpreted to be a partly melted amoeboid olivine inclusion by Yurimoto and Wasson [2002]). It appears that, during much of the chondrule‐forming period, there was a small upward drift in the Δ¹⁷O of nebular solids and that relict cores preserve the record of a different (and earlier) nebular environment.