A Simple Model of Soil-Gas Concentrations Sparged into an Unlined Unsaturated Zone

We derive an analytical model of soil-gas contamination sparged into an imlined unsaturated zone. A nonaqueous phase liquid (NAPL) source lies in the capillary fringe, with an exponential sparge constant within the radius of influence and a constant ambient evaporation rate beyond. Advection, diffusion, and dispersion govern the conservative soil-gas response, expressed as a quasi-steady series solution with radial Bessel and hyperbolic vertical dependence. Simulations suggest that sparged contamination initially spreads beyond the radius of influence down a negative gradient. This gradient eventually reverses, leading to a subsequent influx of ambient contamination. Soil-gas concentrations accordingly reflect slowly varying source conditions as well as slowly varying diffusive transport through the radius of influence. The two time scales are independent: One depends on NAPL, airflow, and capillary fringe characteristics, the other on soil moisture, gaseous diffusivity, and unsaturated zone thickness. The influx of ambient contamination generates an asymptotic soil-gas concentration much less than the initial source concentration. The simple model is applied to a pilot-scale sparging study at Plattsburgh Air Force Base in upstate New York, with physically plausible results.     

Tourist Carrying Capacity Measures: Crowding Syndrome in the Caribbean

International tourism is increasing at an unprecedented rate. Understanding the variety of national and local impacts of this increase is of importance to a growing number of governments. Butler's resort cycle model (1974, 1980, 1991) provides for several long‐term possibilities as to the relationship between crowding and growth. McElroy, de Albuquerque, and Dioguardi (1993) focus on one of those possibilities. Specifically, using their penetration ratio, they predict that as tourist crowding continues for a group of Caribbean islands, the appeal of these islands decreases in the eyes of potential tourists and that, as time increases, the growth rate of the affected islands, actually decreases. Our article indicates that such a simple, straight‐line relationship between increased crowding and a decrease in the rate of change may not be inevitable; indeed, diseconomies of scale may be avoided. The use of a curvilinear regression function reveals how both positive and negative scale economies existed in the Caribbean during the years 1992 through 1996.     

Partial molar volume of water in phonolitic glasses and liquids

The volumes and expansivities of four hydrous phonolite glasses and liquids have been measured by dilatometry from 300 K up to the glass transition and over a 50 K interval just above the glass transition. The partial molar volume of water is independent of the water content for the glass and liquid phases, with values of about 11.0ǂ.5 and 17.1ǂ.9 cm³/mol at 300 and 800 K, respectively. The partial molar thermal expansivity of water in phonolite glasses is about 8᎒^-5 K^-1, a result similar to recently published values for different silicate compositions, and about 36.5᎒^-5 K^-1 in phonolite liquids. The implications for melt density and water dissolution are discussed.     

Extending Participation in the Swaziland Sugar Industry to Small-Scale Growers: Patterns and Prospects

Since its inception in 1956, the Swazi sugar industry has been dominated by large-scale estates. In 1991, due to a combination of political and economic factors, steps were taken to allow the industry to become more accessible to small-scale Swazi farmers. The paper considers the scale and nature of this newly emerging group and discusses its likely impact on employment. Although these developments have been introduced to enable the benefits of the industry to trickle down more effectively to the rural poor, evidence suggests that better off or more organised groups or individuals are best placed to take advantage of the new opportunities. Further growth is now limited by a lack of water and it is likely that the recent rapid increase in this sector will now slow down. Some concern also exists over the impact of sugar cane monoculture on soils.