Origin and formation pathways of kerogen-like organic matter in recent sediments off the Danube delta (northwestern Black Sea)

The chemical structure, source(s), and formation pathway(s) of kerogen-like organic matter (KL) were investigated in recent sediments from the northwestern Black Sea, off the Danube delta. Three sections from a sediment core collected at the mouth of the Sulina branch of the delta, under an oxic water column, were examined: S₀ (0–0.5 cm bsf), S₁₀ (10–13 cm bsf), and S₂₀ (20–25 cm bsf). The bulk geochemical features of these sediments (total organic carbon, organic C/N atomic ratio, δ¹³C_org) were determined. Thereafter, KL was isolated from the samples, as the insoluble residue obtained after HF/HCl treatment. KL chemical composition was investigated via spectroscopic (FTIR, solid state ¹³C and ¹⁵N NMR) and pyrolytic (Curie point pyrolysis–gas chromatography–mass spectrometry) methods, and the morphological features were examined by scanning and transmission electron microscopy. Similar morphological features and chemical composition were observed for the three KLs and they suggested that the selective preservation of land-plant derived material as well as of resistant aliphatic biomacromolecules (probably derived from cell walls of freshwater microalgae) was the main process involved in KL formation. Besides, some melanoidin-type macromolecules (formed via the degradation-recondensation of products mainly derived from proteinaceous material) and/or some encapsulated proteins also contributed to the KL chemical structure.     

1D complete calculation for electrostatic soundings interpretation

Soundings achieved with the electrostatic method cannot be interpreted correctly with 1D electrical programs if the extension of the array or the conductivity of the ground are too large. A complete calculation taking into account the induction effect due to the frequency must be performed. This paper presents the solutions for overcoming the difficulties encountered in this calculation: the iterative processes which make it possible to determine the kernel functions of the Hankel transforms and the analytic integration of the terms of the electric field. Application to practical cases first illustrates the distortion of the electrostatic curves by reference to DC sounding curves. The limitation in depth of investigation is then emphasized: in practice, the investigation is limited by the skin depth corresponding to the frequency used. The examples of the soundings obtained in the city of Alexandria (Egypt) demonstrate the importance of using the complete calculation for very conductive grounds.     

Sources of Cd, Cu, Ni and Zn in Portuguese coastal waters

In order to identify the major sources of trace metals (TM) in the Portuguese coastal waters, 58 surface water samples were collected during September 1988. The area sampled extended from the Tagus Estuary (down to a salinity of 25) to cape Ste Marie on the southern coast of Portugal. Dissolved metal concentrations in the fully marine waters ranged from 30 to 250 pM for Cd, 0.7–15 nM for Cu, 0.9–20 nM for Zn and 1.8–4.5 nM for Ni. Within the Tagus Estuary (salinity 25), concentrations increased to 3400 pM for Cd, 26 nM for Cu, 14 nM for Ni and 230 nM for Zn.The large-scale distribution of these metals is dominated by two strong continental sources, both probably linked to the exploitation of pyrite ores. In the Tagus Estuary, TM enrichments can be mostly attributed to a pyrite roasting plant located on the shore in front of Lisbon. Concerning the south Portuguese shelf waters, several hypotheses are proposed to explain their elevated metal concentrations. We particularly discussed the likely influence of the Tinto/Odiel rivers located 100 km eastward, an influence well known in the shelf waters of the Gulf of Cadiz. These rivers are extremely metal-rich because of acid mine tailings originating from their catchment. Between these two regions, upwelling of relatively metal-poor water largely contributes to the dilution of the continental inputs. Indeed, water exchanges on the shelf linked to the upwelling involve water fluxes 500 times higher than the Tagus River flow, and renew the coastal waters that are thus cleaned from terrestrial contamination. Contrary to many other upwelling systems in non-contaminated areas, the Portuguese upwelling does not act as a source of trace-metal enrichment of the continental margin waters.     

A multimodel comparison for assessing water temperatures under changing climate conditions via the equilibrium temperature concept: case study of the Middle Loire River,France

This paper investigates three categories of models that are derived from the equilibrium temperature concept to estimate water temperatures in the Loire River in France and the sensitivity to changes in hydrology and climate. We test the models' individual performances for simulating water temperatures and assess the variability of the thermal responses under the extreme changing climate scenarios that are projected for 2081–2100. We attempt to identify the most reliable models for studying the impact of climate change on river temperature (T_w). Six models are based on a linear relationship between air temperatures (T_a) and equilibrium temperatures (T_e), six depend on a logistic relationship, and six rely on the closure of heat budgets. For each category, three approaches that account for the river's thermal exchange coefficient are tested. In addition to air temperatures, an index of day length is incorporated to compute equilibrium temperatures. Each model is analysed in terms of its ability to simulate the seasonal patterns of river temperatures and heat peaks. We found that including the day length as a covariate in regression‐based approaches improves the performance in comparison with classical approaches that use only T_a. Moreover, the regression‐based models that rely on the logistic relationship between T_e and T_a exhibit root mean square errors comparable (0.90 °C) with those obtained with a classical five‐term heat budget model (0.82 °C), despite a small number of required forcing variables. In contrast, the regressive models that are based on a linear relationship T_e = f(T_a) fail to simulate the heat peaks and are not advisable for climate change studies. The regression‐based approaches that are based on a logistic relationship and the heat balance approaches generate notably similar responses to the projected climate changes scenarios. This similarity suggests that sophisticated thermal models are not preferable to cruder ones, which are less time‐consuming and require fewer input data. Copyright © 2012 John Wiley & Sons, Ltd.     

Using land cover changes and demographic data to improve hydrological modeling in the Sahel

At the beginning of the drought in the Sahel in the 1970s and 1980s, rainfall decreased markedly, but runoff coefficients and in some cases, absolute runoff increased. This situation was due to the conversion of the land cover from natural vegetation with a low annual runoff coefficient, to cropland and bare soils, whose runoff coefficients are higher. Unless they are adapted, hydrological conceptual models, such as GR2M, are unable to reproduce this increase in runoff. Despite the varying environmental and climatic conditions of the West African Sahel, we show that it is possible to increase the performance of the GR2M model simulations by elaborating a time‐varying soil water holding capacity and to incorporate this value in the annual maximum amount of water to be stored in reservoir A of the model. We looked for interactions between climate, rural society, and the environment. These interactions drive land‐cover changes in the Sahel, which in turn drive the distribution of rainfall between infiltration, evaporation, and runoff and hence the water resources, which are vital in this region. We elaborated several time series of key indicators linked to these interactions. We then integrated these changes in the runoff conditions of the GR2M model through the maximum value of the reservoir capacity. We calculated annual values of water holding capacity using the annual values of four classes of land cover, natural vegetation, cultivated area, bare soil, and surface water. We then used the hydrological model with and without this time‐varying soil value of A and compared the performances of the model under the two scenarios. Whatever the calibration period used, the Nash–Sutcliffe index was always greater in the case of the time‐varying A time series.     

Suspended sediment and dissolved load budgets of two Amazonian rivers from the Guiana Shield: Maroni River at Langa Tabiki and Oyapock River at Saut Maripa (French Guiana)

This study presents the data collected within the framework of an Observatory of Research in Environment on the Amazonian Basin—the ORE HYBAM. It relates to the dissolved and solid loads of the two main rivers of French Guiana, the Maroni and Oyapock rivers, running on the Guiana Shield and draining respectively 64 230 and 24 630 km². The low coefficient of variation of the average annual flows of the two rivers indicates an inter‐annual hydrological stability probably related to the immediate vicinity of the Atlantic Ocean. The sedimentary load is mainly composed of quartz and kaolinite. The total suspended solid (TSS) concentrations are among the world's lowest values; they range from 1 to 130 mg l⁻¹ during the hydrological cycle, with averages of 22 and 12 mg l⁻¹, for the Maroni and Oyapock rivers, respectively. The seasonal variability of these values is significantly higher than that of hydrologic flows, but without simple relationship with the discharge. Water chemical composition of the two rivers indicates a very weak mineralization, very similar to that found in the Amazonian rivers running on the Brazilian and Guianese shields, and in the Congo River and its tributaries in the Central African Shield. Seasonal variations are observed in both basins; they correspond to higher concentrations during low water stage (from October to February) and to more diluted water during the flood, from April to July. A signature enriched in Cl⁻ is present at the Saut Maripa station on the Oyapock River indicating a more marked influence of the trade winds in this basin. The computation of atmospheric contributions to ions budget indicated a weak contribution for Ca²⁺ and Mg²⁺, which originates mainly from water‐rock interactions in both stations, while more than half of Na⁺ is derived from atmospheric inputs. Copyright © 2010 John Wiley & Sons, Ltd.     

Resazurin as an indicator of reducing capacity for analyzing the physiologic status of deep-sea bacterium Photobacterium phosphoreum ANT-2200

Journal of Oceanology and Limnology - Resazurin (RZ) is a weakly fluorescent blue dye and can be reduced irreversibly to highly fluorescent pink resorufin (RF) that is reduced reversibly to...     

Strain-induced magma degassing: insights from simple-shear experiments on bubble bearing melts

Experiments have been performed to determine the effect of deformation on degassing of bubble-bearing melts. Cylindrical specimens of phonolitic composition, initial water content of 1.5 wt.% and 2 vol.% bubbles, have been deformed in simple-shear (torsional configuration) in an internally heated Paterson-type pressure vessel at temperatures of 798–848 K, 100–180 MPa confining pressure and different final strains. Micro-structural analyses of the samples before and after deformation have been performed in two and three dimensions using optical microscopy, a nanotomography machine and synchrotron tomography. The water content of the glasses before and after deformation has been measured using Fourier Transform Infrared Spectroscopy (FTIR). In samples strained up to a total of γ ∼ 2 the bubbles record accurately the total strain, whereas at higher strains (γ ∼ 10) the bubbles become very flattened and elongate in the direction of shear. The residual water content of the glasses remains constant up to a strain of γ ∼ 2 and then decreases to about 0.2 wt.% at γ ∼ 10. Results show that strain enhances bubble coalescence and degassing even at low bubble volume-fractions. Noticeably, deformation produced a strongly water under-saturated melt. This suggests that degassing may occur at great depths in the volcanic conduit and may force the magma to become super-cooled early during ascent to the Earth’s surface potentially contributing to the genesis of obsidian.     

Assessing the contribution of electrical resistivity tomography (ERT) and self-potential (SP) methods for a water well drilling program in fractured/karstified limestones

ERT and SP investigations were conducted in carbonate rocks of the Dinant Synclinorium (Walloon Region of Belgium) to find suitable locations for new water wells in zones with little hydrogeological data. Since boreholes information needed to be representative of the area, large fractured zones were searched for the drillings. Large ERT profiles (320 to 640 m) allowed us to image the resistivity distribution of the first 60 m of the subsurface and to detect and characterize (in terms of direction, width and depth) fractured zones expected to be less resistive. Data errors, depth of investigation (DOI) indexes and sensitivity models were analyzed in order to avoid a misinterpretation of the resulting images. Self-potential measurements were performed along electrical profiles to complement our electrical results. Some negative anomalies possibly related to preferential flow pathways were detected. A drilling campaign was conducted according to geophysical results. ‘Ground truth’ geological data as well as pumping tests information gave us a way to assess the contribution of geophysics to a drilling program. We noticed that all the wells placed in low resistivity zones associated with SP anomalies provide very high yields and inversely, wells drilled in resistive zones or outside SP anomalies are limited in terms of capacity. An apparent coupling coefficient between SP signals and differences in hydraulic heads was also estimated in order to image the water table.