Comparing the patterns of 20–70 days intraseasonal oscillations over Central Africa during the last three decades

In this paper, we used the Outgoing Longwave Radiation (OLR) data to compare the intraseasonal atmospheric variability patterns over Central Africa, during the last three decades. The spectral analysis indicates that for the three decades, the intraseasonal variability is dominated by 20–80 days periods band with the center near 40–50 days. The results of Empirical Orthogonal Functions (EOFs) analysis have shown that the amount of variance explained by the three retained EOFs are 41.6 % for 1981–1990, 44.2 % for 1991–2000 and 42.6 % for 2001–2010. For the three decades, the three leading EOFs retained exhibit high spatial loadings over Northern Congo, Southern Ethiopia, and Southwestern Tanzania. The power spectra of the leading principal components have their peaks near 40 days for the three decades, indicating MJO signal. The PCs time series revealed that the amplitude of intraseasonal oscillations (ISO) globally decreases from decade to another. The plot of ISO and El Niño-Southern Oscillation (ENSO) indices revealed that the lowest values of ISO strength generally correspond to the relatively large values of ENSO indices and inversely. The mean ISO strength and ISO fluctuations were highest during 1981–1990, and this period also corresponds to the highest fluctuations of ENSO signal.     

Fossil brines preserved in the St-Lawrence Lowlands, Québec, Canada as revealed by their chemistry and noble gas isotopes

Brines in Cambrian sandstones and Ordovician dolostones of the St-Lawrence Lowlands at Bécancour, Québec, Canada were sampled for analysis of all stable noble gases in order to trace their origin and migration path, in addition to quantifying their residence time. Major ion chemistry indicates that the brines are of Na-Ca-Cl type, possibly derived from halite dissolution. ⁸⁷Sr/⁸⁶Sr ratios and Ca excess indicate prolonged interactions with silicate rocks of the Proterozoic Grenville basement or the Cambrian Potsdam sandstone. The brines constrain a 2-3% contribution of mantle ³He and large amounts of nucleogenic ²¹Ne^∗ and ³⁸Ar^∗ and radiogenic ⁴He and ⁴⁰Ar^∗. ⁴He/⁴⁰Ar^∗ and ²¹Ne^∗/⁴⁰Ar^∗ ratios, corrected for mass fractionation during incomplete brine degassing, are identical to their production ratios in rocks. The source of salinity (halite dissolution), plus the occurrence of large amounts of ⁴⁰Ar^∗ in brines constrain the residence time of Bécancour brines as being older than the Cretaceous. Evaporites in the St-Lawrence Lowlands likely existed only during Devonian-Silurian time. Brines might result from infiltration of Devonian water leaching halite, penetrating into or below the deeper Cambrian-Ordovician aquifers. During the Devonian, the basin reached temperatures higher than 250 °C, allowing for thermal maturation of local gas-prone source rocks (Utica shales) and possibly facilitating the release of radiogenic ⁴⁰Ar^∗ into the brines. The last thermal event that could have facilitated the liberation of ⁴⁰Ar^∗ into fluids and contributed to mantle ³He is the Cretaceous Monteregian Hills magmatic episode. For residence times younger than the Cretaceous, it is difficult to find an appropriate source of salinity and of nucleogenic/radiogenic gases to the Bécancour brines.     

Numerical analysis of frost effects in porous media. Benefits and limits of the finite element poroelasticity formulation

The aim of this paper is to analyse the performance of a finite element formulation usable for predicting the mechanical consequences of frost effects on porous media. It considers the characteristics of porous media and how the frost action can be assessed. The problem is then separated into two parts: thermal and poromechanical calculations. The constitutive equations developed in the framework of poromechanics are presented and the implementation in a usual finite element poroelasticity formulation based on Zuber's method is adopted. An analysis of the time‐step influence on the convergence rate is given and leads us to propose a simple method in order to obtain objectivity of the finite element response and avoid over‐long calculations. Frost effect simulations are carried out on real porous media (two fired clays) as a case study. Although the experimental behaviour of the porous media subjected to frost action is in accordance with some observations, the calculated strains appear to be overestimated compared with measurements. The problem could be largely attributable to the difficulty of assessing permeability evolution during frost development. Copyright © 2011 John Wiley & Sons, Ltd.     

Hydrocarbon pollution of the Mediterranean coastline of Morocco

Organic geochemical study of hydrocarbon pollution of the Mediterranean coastline of Morocco (Tangier-Nador) was performed during March–April 2002. It corresponds to a preliminary work representing an initial assessment of oil contamination of Moroccan coast.Three coastal sites corresponding to Tangier, Tetouan and Nador, representing the main built-up area of this marine region, were selected for superficial sediments, water and organism sampling. Results showed high contamination levels in these three selected sites, known as the most exposed areas to urban and industrial discharges. The maximal contamination corresponding to the sum of non-aromatic (NAH) and polycyclic aromatic hydrocarbons (PAH) encountered in sediment samples was about 553 μg/g (dw). Nevertheless, even a small city agglomeration without any industrial activity showed high values reaching 370 μg/g (dw), which confirm the important hydrocarbons input coming from discharges of fishing ships and oil transporting tankers.The obtained results from this survey reflecting in part the important amounts drained via effluents toward the Moroccan Mediterranean coasts, presented to the concerned authorities drove to the realization of the project of treatment of the wastewater.They later expect to lower rates by 50%, which is still insufficient for a fragile ecosystem such as the Mediterranean and sensitive to anthropogenic effects.     

Analysis of the Excavation Deviations Impact on Geological Radioactive Waste Repository Performance

Numerical simulations of the transport of radionuclide from high-level radioactive waste stored in geological repositories often do not take into account construction defects in the repository. The potential impact of drilling and excavation deviation from the engineer planned design is a priori considered negligible. We conducted computations on repository geometries that contain deviations from horizontal of a few degrees. The analysis of the results shows that the impact of deviation defects varies from 9 to 16%. A perfect control of the galleries and waste repository cell orientations is then of concern for radioactive waste repository construction, failing which numerical simulations must be conducted on the worst geometric configuration or margin errors added. On the other hand, if the orientation control is precise enough, a modification of the repository design including controlled deviations from the horizontal may be of interest.     

Reconstruction of Horizontal Plasma Motions at the Photosphere from Intensitygrams: A Comparison Between DeepVel,LCT, FLCT,and CST

Direct measurements of plasma motions in the photosphere are limited to the line-of-sight component of the velocity. Several algorithms have therefore been developed to reconstruct the transverse components from observed continuum images or magnetograms. We compare the space and time averages of horizontal velocity fields in the photosphere inferred from pairs of consecutive intensitygrams by the LCT, FLCT, and CST methods and the DeepVel neural network in order to identify the method that is best suited for generating synthetic observations to be used for data assimilation. The Stein and Nordlund (Astrophys. J. Lett.753, L13, 2012) magnetoconvection simulation is used to generate synthetic SDO/HMI intensitygrams and reference flows to train DeepVel. Inferred velocity fields show that DeepVel performs best at subgranular and granular scales and is second only to FLCT at mesogranular and supergranular scales.     

Physical partitioning of mercury in till: an example from central British Columbia, Canada

The physical partitioning of Hg into different grain size fractions of till is predominantly controlled by the primary bedrock mineralogy, the distance of glacial transport, and the relative stability of cinnabar (HgS) in the soil weathering environment. At sites located short distances down-ice from bedrock cinnabar mineralization, the highest Hg concentrations in unoxidized till were measured in the sand- and granule-sized fractions reflecting the abundance of cinnabar in those size ranges. Similar partitioning was measured in oxidized till as cinnabar was found to be relatively resistant to postglacial weathering. Discrete clay-sized cinnabar grains obtained from the unoxidized till were viewed under the scanning electron microscope and suggest that the terminal grade of cinnabar is in the clay-sized range. In till collected from areas barren of cinnabar mineralization, the highest Hg levels were found in the clay-sized fraction which is attributed to the high adsorption of Hg by clay minerals.     

Limit analysis for saturated porous media without fluid flow calculation

Application of yield design to porous media usually requires a preliminary calculation of the fluid flow net. The stability analysis is then carried out with seepage forces associated with the flow. We assume here that the flow is steady and that the yield criterion is defined by a function of the effective stress tensor. The formulation that we propose here allows taking into account seepage force in the expression of the kinematic stability conditions by means of hydraulic boundary conditions without calculation of the fluid flow. One obtains a formulation of the kinematic condition similar to the case of classic, non-porous media. The method is illustrated by two examples: a cylinder subjected to fluid flow and a vertical cut. It can be adapted to various boundary conditions and to the case of a criterion defined by a function of a generalized effective stress tensor. We also give a method to derive rigorous lower bounds using approximate fluid pressure field. Copyright © 2004 John Wiley & Sons, Ltd.