A synthetic crystal of coesite, SiO2, has been found to contain microtwins. The (100) reflection twin has been made evident on incoherent (010) planes. The twin structure is directly imaged by high resolution electron microscopy at 2,5 Å resolution, allowing an atomic model to be proposed. This twin could be incoherent on large surfaces and the dislocation density is predicted. The X-ray crystallographic data are analyzed critically in view of the presence of such defects in single crystals. The mutual orientation between a silicon matrix and coesite precipitates in Czochralski-silicon annealed specimens is proposed to be non unique as a consequence of the easy twinning of coesite. 相似文献
It is now well established that a number of terrestrial and aquatic microorganisms have the capacity to oxidize and precipitate Mn as phyllomanganate. However, this biomineralization has never been shown to occur in plant tissues, nor has the structure of a natural Mn(IV) biooxide been characterized in detail. We show that the graminaceous plant Festuca rubra (red fescue) produces a Zn-rich phyllomanganate with constant Zn:Mn and Ca:Mn atomic ratios (0.46 and 0.38, respectively) when grown on a contaminated sediment. This new phase is so far the Zn-richest manganate known to form in nature (chalcophanite has a Zn:Mn ratio of 0.33) and has no synthetic equivalent. Visual examination of root fragments under a microscope shows black precipitates about ten to several tens of microns in size, and their imaging with backscattered and secondary electrons demonstrates that they are located in the root epidermis. In situ measurements by Mn and Zn K-edge extended X-ray absorption fine structure (EXAFS) spectroscopy and X-ray diffraction (XRD) with a micro-focused beam can be quantitatively described by a single-phase model consisting of Mn(IV) octahedral layers with 22% vacant sites capped with tetrahedral and octahedral Zn in proportions of 3:1. The layer charge deficit is also partly balanced by interlayer Mn and Ca. Diffracting crystallites have a domain radius of 33 Å in the ab plane and contain only 1.2 layers (8.6 Å) on average. Since this biogenic Mn oxide consists mostly of isolated layers, basal 00l reflections are essentially absent despite its lamellar structure. Individual Mn layers are probably held together in the Mn–Zn precipitates by stabilizing organic molecules. Zinc biomineralization by plants likely is a defense mechanism against toxicity induced by excess concentrations of this metal in the rhizosphere. 相似文献
In France, the Devonian–Carboniferous Variscan orogeny developed at the expense of continental crust belonging to the northern margin of Gondwana. A Visean–Serpukhovian crustal melting has been recently documented in several massifs. However, in the Montagne Noire of the Variscan French Massif Central, which is the largest area involved in this partial melting episode, the age of migmatization was not clearly settled. Eleven U–Th–Pbtot. ages on monazite and three U–Pb ages on associated zircon are reported from migmatites (La Salvetat, Ourtigas), anatectic granitoids (Laouzas, Montalet) and post-migmatitic granites (Anglès, Vialais, Soulié) from the Montagne Noire Axial Zone are presented here for the first time. Migmatization and emplacement of anatectic granitoids took place around 333–326 Ma (Visean) and late granitoids emplaced around 325–318 Ma (Serpukhovian). Inherited zircons and monazite date the orthogneiss source rock of the Late Visean melts between 560 Ma and 480 Ma. In migmatites and anatectic granites, inherited crystals dominate the zircon populations. The migmatitization is the middle crust expression of a pervasive Visean crustal melting event also represented by the “Tufs anthracifères” volcanism in the northern Massif Central. This crustal melting is widespread in the French Variscan belt, though it is restricted to the upper plate of the collision belt. A mantle input appears as a likely mechanism to release the heat necessary to trigger the melting of the Variscan middle crust at a continental scale. 相似文献
Mesozoic rift basins locally bounding metamorphic core complexes have been recognized in Transbaikalia and northern China.
Numerous basement outcrops located between these two regions, in eastern Mongolia, are considered as pre-Palaeozoic in age.
One of these, the Ereendavaa Range, appears as a gneissic core marked by amphibolite-facies metamorphic conditions. The range
is overlain to the NW by the unmetamorphosed Mesozoic Onon Basin. Below the basin, the upper part of the range consists of
a gently NW-dipping shear zone associated with top-to-the-NW motion. The structural pattern is consistent with syn-extensional
exhumation of the range. Preliminary geochronological data indicate that the shear zone is late Jurassic to early Cretaceous
in age, coeval with the Onon Basin. These new data from eastern Mongolia constitute a link between Transbaikalia and northern
China, indicating that NW–SE extensional Mesozoic tectonics occurred throughout the entire region. 相似文献
In the analysis of geographical spillovers, a commonly accepted hypothesis is that the different actors of innovation need to be physically closed to one another because the transfer of tacit knowledge implies frequent face-to-face relations. This hypothesis is put under closer examination in this paper. The first section analyses the need for economic agents to be closely located to develop research and innovative activities, starting with the analysis of their need for co-ordination and using some case studies. Based on the example of three French regions, the second section examines the importance given by the local development policies to geographical proximity in order to support the rapid development of local networks favouring innovation. In both sections, nonlocal relations appear as a key factor to develop innovation. As a conclusion, nonlocal relations should be encouraged by local development policies in the same way as local relations. 相似文献
Ion-microprobe U–Pb zircon dating of lower-crust metasedimentary granulite are reported on samples from two localities in Europe in order to determine (a) how this environment recorded the Variscan and eo-Alpine events, and (b) whether the transition between the two orogenic cycles was continuous or separated by a gap. The samples come from enclaves hosted by Miocene volcanoes at Bournac in the French Massif Central, and from the granulitic metasedimentary basement of the Alpine Santa Lucia nappe in Corsica, on the South European paleomargin of the Ligurian branch of the Tethys Sea. The zircon ages from Bournac range between 630 and 430 Ma and between 380 and 150 Ma with a major frequency peak at 285 Ma; the zircons older than 430 Ma are interpreted as detrital, whereas those younger than 380 Ma are considered to have formed by metamorphic processes after burial in the lower crust. Zircon ages from Santa Lucia range from to 356 to 157 Ma, with exception of one inherited Archean grain, and are interpreted like the younger Bournac zircons as having been formed by metamorphic processes.
In a granulite metamorphic environment, as opposed to an anatectic environment, new zircon growth can occur in the solid state. Once Zr has been incorporated into zircon, however, it is difficult to remobilize without dissolution; thus Zr available for new zircon growth must result from the breakdown of Zr-bearing minerals during prograde and/or retrograde events. In this light, the U–Pb zircon-age probability curves are interpreted as markers for major tectonometamorphic events, as suggested by the close correspondence between peaks in the curve and geological events recorded in the upper-crust, such as magma emplacement and basin subsidence.
Evidence of a tectonometamorphic gap between the Variscan and Alpine orogeneses is provided by the Santa Lucia zircon-age probability curve, which reveals a probable interlude during the Variscan–Alpine transition between 240 and 210 Ma. Here, the peak at 240 Ma is interpreted as the very beginning of crustal extension and the low at 210 Ma as a period of quiescence prior to the formation of an active margin and oceanization. 相似文献