Partitioning of divalent transition elements between octahedral sheets of trioctahedral smectites and water

Using trioctahedral smectites synthesized at low temperature (25 and 75°C). partition coefficients have been determined for M²⁺ transition metals (Mn, Fe, Co, Ni, Cu, Zn) between octahedral sheets of smectites and water. These coefficients D_(M²⁺?Mg) = (M²⁺)/(Mg) solid/(M²⁺)/(Mg) liquid have high values near 10⁴ for Cu, 1000 for Ni, Co, Zn, 300 for Fe and 30 for Mn. All transition metals are strongly stabilized in the magnesian solid phase, even Mn which leads to noncrystallized products. Within the range of experimental uncertainties, it is found that tetrahedral substitution of Si by Al and differences in temperature (from 25 to 75°C) have no influence on partition coefficients. Experimental data are closely related to thermodynamic properties of the cations and on this basis other partition coefficients can be calculated, for the (M²⁺ ? Fe²⁺) pair for instance. The behaviour of transition metals is explained using crystal field theory.     

Statistical Characterization of the Flow Structure in the Rhine Valley

The flow structure at the intersection between the Rhine and the Seez valleys nearthe Swiss city of Bad Ragaz has been documented by means of wind and pressuremeasurements collected from 9 September to 10 November 1999 during the MesoscaleAlpine Programme (MAP) experiment. To understand better the dynamics of theageostrophic winds that develop in this part of the Rhine valley, some key questionsare answered in this paper including the following: (i) How does air blow at theintersection of the Rhine and Seez valleys? and (ii) what are the dynamical processes(mechanical or thermal) driving the flow circulations in the valleys? Statistical analysis of the wind and pressure patterns at synoptic scale and at the scaleof the valley shows that five main flow patterns, SE/S, NW/W, NW/N, NW/S, SE/N(wind direction in the Seez valley/wind direction in the Rhine valley) prevail. The SE/S regime is the flow splitting situation. It is mainly driven by a strong pressure gradient across the Alps leading to foehn, even though some nocturnal cases are generated bylocal thermal gradients. The NW/W and NW/N regimes are mechanically forced bythe synoptic pressure gradient (as the flow splitting case). The difference between thetwo regimes is due to the synoptic flow direction [westerly (northerly) synoptic flowfor the NW/W (NW/N) regime], showing that the Rhine valley (particularly from BadRagaz to Lake Constance) is less efficient in channelling the flow than the Seez valley.The NW/S (occurring mainly during nighttime) and SE/N (occurring mainly duringdaytime) regimes are mainly katabatic flows. However, the SE/N regime is also partlyforced at the synoptic scale during the foehn case that occurred between 18 October and 20 October 1999, with a complex layered vertical structure. This analysis also shows that, contrary to what was observed in a broad section of theupper Rhine valley near Mannheim, very few countercurrents were observed near BadRagaz where the valley width is much smaller.     

Relationship between erosion surfaces and Late Miocene Salinity Crisis deposits in the Valencia Basin (northwestern Mediterranean): evidence for an early sea‐level fall

Although the main events of the Messinian Salinity Crisis (MSC) are today mostly known, the exact succession of the different episodes remains unclear. This, in particular, is because (i) no drilling has reached the base of the Salt, and thus the onset of the MSC in the basins is unknown, and (ii) lateral correlations between the margins and the deep basins are missing. The Valencia Basin, which is intermediate in depth between the marginal basins and the deep basins, is an ideal location for studying the transitional domain. It displays the relationships between the polygenic erosion on the margins, the deposition of the thin Upper Evaporites bracketed by basal and top erosion surfaces in the central part of the basin, and the thick MSC sequence in the deep oceanic Provençal Basin. Early detrital deposits located below the MSC sequence of the deep basin suggest an early lowering of the sea level prior to the MSC desiccation.     

The Canadian Meteorological Centre's Atmospheric Transport and Dispersion Modelling Suite

This paper describes the integrated suite of Lagrangian transport and dispersion models in operation at the Canadian Meteorological Centre. These models have been in use for several years and are applied to many types of environmental emergencies covering spatial scales from the very local to the global. The Modèle Lagrangien Courte Distance (MLCD) is used for atmospheric spills of the order of a few kilometres. The Modèle Lagrangien de dispersion de particules d'ordre 1 (MLDP1) is normally used for events affecting areas less than 100?km; Modèle Lagrangien dispersion de particules d'ordre zéro (MLDP0) is used for events of continental and global consequences. The Modèle Lagrangien dispersion de particules mode mixte (MLDPmm) alternates between first-order and zeroth-order depending on criteria specified by the user. The theoretical bases of the models are presented, and the main algorithms used in their implementation are discussed. Modelling of the diffusion processes is based on a stochastic differential equation with the assumption of quasi-stationary Gaussian turbulence, locally homogeneous in the horizontal. The practical aspects of the operational implementation are also described. Using these models, results from simulations of real cases on scales ranging from the very local, to a few kilometres, to regional (approximately 100?km) to continental (approximately 1000?km) and to global (approximately 10,000?km) are compared and validated with available observational data.     

Internal vein texture and vein evolution of the epithermal Shila-Paula district,southern Peru

The epithermal Shila-Paula Au–Ag district is characterized by numerous veins hosted in Tertiary volcanic rocks of the Western Cordillera (southern Peru). Field studies of the ore bodies reveal a systematic association of a main E–W vein with secondary N55–60°W veins—two directions that are also reflected by the orientation of fluid-inclusion planes in quartz crystals of the host rock. In areas where this pattern is not recognized, such as the Apacheta sector, vein emplacement seems to have been guided by regional N40°E and N40°W fractures. Two main vein-filling stages are identified. stage 1 is a quartz–adularia–pyrite–galena–sphalerite–chalcopyrite–electrum–Mn silicate–carbonate assemblage that fills the main E–W veins. stage 2, which contains most of the precious-metal mineralization, is divided into pre-bonanza and bonanza substages. The pre-bonanza substage consists of a quartz–adularia–carbonate assemblage that is observed within the secondary N45–60°W veins, in veinlets that cut the stage 1 assemblage, and in final open-space fillings. The two latter structures are finally filled by the bonanza substage characterized by a Fe-poor sphalerite–chalcopyrite–pyrite–galena–tennantite–tetrahedrite–polybasite–pearceite–electrum assemblage. The ore in the main veins is systematically brecciated, whereas the ore in the secondary veins and geodes is characteristic of open-space crystallization. Microthermometric measurements on sphalerite from both stages and on quartz and calcite from stage 2 indicate a salinity range of 0 to 15.5 wt% NaCl equivalent and homogenization temperatures bracketed between 200 and 330°C. Secondary CO₂-, N₂- and H₂S-bearing fluid inclusions are also identified. The age of vein emplacement, based on ⁴⁰Ar/³⁹Ar ages obtained on adularia of different veins, is estimated at around 11 Ma, with some overlap between adularia of stage 1 (11.4±0.4 Ma) and of stage 2 (10.8±0.3 Ma). A three-phase tectonic model has been constructed to explain the vein formation. Phase 1 corresponds to the assumed development of E–W sinistral shear zones and associated N60°W cleavages under the effects of a NE–SW shortening direction that is recognized at Andean scale. These structures contain the stage 1 ore assemblage that was brecciated during ongoing deformation. Phase 2 is a reactivation of earlier structures under a NW–SE shortening direction that allowed the reopening of the preexisting schistosity and the formation of scarce N50°E-striking S2-cleavage planes filled by the stage 2 pre-bonanza minerals. Phase 3 coincides with the bonanza ore emplacement in the secondary N45–60°W veins and also in open-space in the core of the main E–W veins. Our combined tectonic, textural, mineralogical, fluid-inclusion, and geochronological study presents a complete model of vein formation in which the reactivation of previously formed tectonic structures plays a significant role in ore formation.     

The ground calibration setup of OMEGA and VIRTIS experiments: description and performances

Hyperspectral imagery is an essential technique for remote sensing of surfaces and atmospheres of planetary objects. However, given the instrumental complexity of coupling imaging and spectroscopy, in particular in the infrared, an in-depth ground calibration is mandatory to enable an unbiased and optimized data reduction.This paper presents the ground calibration setup designed and implemented for the visible and near infrared imaging spectrometers VIRTIS/ROSETTA, and OMEGA/MARS-EXPRESS, and summarizes the main results obtained in validating the required performances.     

Automated Detection of Coronal Loops Using a Wavelet Transform Modulus Maxima Method

We propose and test a wavelet transform modulus maxima method for the automated detection and extraction of coronal loops in extreme ultraviolet images of the solar corona. This method decomposes an image into a number of size scales and tracks enhanced power along each ridge corresponding to a coronal loop at each scale. We compare the results across scales and suggest the optimum set of parameters to maximize completeness, while minimizing detection of noise. For a test coronal image, we compare the global statistics (e.g. number of loops at each length) to previous automated coronal-loop detection algorithms.     

Quantitative Control of Migration: A Geostatistical Attempt

This paper is devoted to a geostatistical attempt at modeling migration errors when localizing a reflector in the ground. Starting with a probabilistic velocity model and choosing the simple geometrical optics background for the wave propagation in such media, we give the expression of the errors. This may be quantified provided the covariance of the velocity field is known. Variance of arrival times at constant offset is related to the covariance of the velocity field at hand. A practical application is given in the same paragraph. After that we give a typical schema for migration and uncertainty modeling: starting with seismic data, we make the weak seismic inversion. We then obtain the covariance of the velocity field that we use for simulating migration errors. The main issues of this methodology are discussed in the last paragraph.