Influence of Drying on the Stiffness and Strength of Cement-Stabilized Soils

Nowadays, improving the strength and deformation properties of soft soils by deep soil mixing is a commonly used technique. There is also an increasing interest in the use of this technique for foundation/structural elements and excavation retaining walls applications. The compressive strength and elastic modulus of the soil mix material are key parameters in the design of these structures. However, there is very limited information available on the impact of exposure to air drying (in the case of retaining wall) on the strength and stiffness of cement stabilized soils. The aim of this study is to investigate the effects of different curing conditions (immersion in water, cycles of wetting and drying, continuous air drying) on the mechanical properties of soils treated with cement in the laboratory. Free–free resonance tests and unconfined compression tests were performed on specimens of silt and sand treated with blastfurnace slag cement. Strength increases more rapidly than stiffness between 7 and 30 days. The strength of stabilized soils submitted to cyclic wetting and drying before the cement hydration process is complete continues to increase. As long as the periods of drying do not induce microcracks, the stiffness of the treated soil specimens also increases with time. However, the stiffness is lower than for the specimens cured in water indicating a disruptive effect of the imposed wetting–drying cycles on stiffness. Continuous exposure to air drying inhibits strength development due to insufficient water for hydration. Significant stiffness decreases were observed on specimens of stabilized silt and are attributed to microcracking.     

Environmental controls on the development of Mississippian microbial carbonate mounds and platform limestones in southern Montagne Noire (France)

Late Mississippian carbonates in southern Montagne Noire are dominantly domical to laterally‐accreted microbial mounds in some formations, as well as stratiform microbial limestones occurring in hundreds of olistoliths within a flysch basin, constituting pieces of a giant puzzle that are used to help reconstruct a platform in a region that is no longer preserved. Petrographic data of limestone samples from 14 continuous long sections of olistoliths have been analyzed statistically, using multivariate clustering (Q‐mode) of the components/matrix/cement and canonical correspondence analysis that allow the reconstruction of the environmental parameters of carbonate microbial communities in space and time. Clustering analysis separated microbial and non‐microbial facies. The calculation of indices along the various axes from canonical correspondence analysis allows recognition of the controlling factors of the mounds and microbial growth as being turbidity, light penetration, bathymetry and storms. Turbidity and light penetration are the primary factors controlling the morphology of the microbial limestones. Representation of the light penetration and bathymetry indices on the stratigraphical sections defines two vertical environmental gradients. Light penetration can be subdivided into euphotic, euphotic–dysphotic and dysphotic‐aphotic conditions. The representation of the bathymetry allows the subdivision of samples into a deeper outer ramp, external mid‐ramp and internal mid‐ramp. The curve distance from the section base = f (index) suggests a cyclicity for the platform that cannot be compared with the onlap curve defined from other cratonic areas (Moscow Basin), and thus the cyclic succession of the Montagne Noire is interpreted to have been mostly tectonically‐controlled. Integration of the data allowed the reconstruction of the original Mississippian carbonate platform, where, up to the Mikhailovian, it appears to correspond to a platform morphology, with narrow shallow water facies and wide turbiditic systems, whereas the width of shallow‐water settings expanded during the Venevian to the Protvian, forming a ramp or distally‐steepened ramp with widespread microbial limestones.     

Datation UPb sur zircons des dolérites tholéiitiques pyrénéennes (ophites) à la limite Trias–Jurassique et relations avec les tufs volcaniques dits « infra-liasiques » nord-pyrénéens

The tholeiitic doleritic magmatism (ophites) in the Aspe valley of the Pyrenees has been dated on the Triassic–Jurassic boundary (199±2 Ma) by the UPb method on zircon (SHRIMP). Emplacement of the ophites was probably synchronous with that of the earliest ‘Infraliassic’ Ségalas tuffs. The ophites are thus related to the Central Atlantic Magmatic Province (CAMP) whose emplacement linked with the fracturing of Pangea, preceded the opening of the Atlantic Ocean. To cite this article: P. Rossi et al., C. R. Geoscience 335 (2003).     

Datation Ar/Ar des leucogranites sous couverture du complexe plutonique de Charroux–Civray (Vienne)Ar/Ar dating of leucogranites in the sediment-covered Charroux–Civray complex (Vienne)

⁴⁰Ar/³⁹Ar dating on muscovites, performed on leucogranitic intrusions of Charroux–Civray plutonic complex, points out the existence of two peraluminous magmatic activities, whose equivalents are known in the Limousin: (1) garnet-bearing leucogranitic veins at ca. 340 Ma; (2) a specialised leucogranite associated with W ± Sn deposits at ca 310 Ma. However, available ⁴⁰Ar/³⁹Ar data do not allow us to provide further data concerning the age and the geometry at depth of a large leucogranitic body identified by geophysics. To cite this article: P. Alexandre et al., C. R. Geoscience 334 (2002) 1141–1148.     

The geologic history of the Caribbean-Cocos plate boundary with special reference to the Nicoya ophiolite complex (Costa Rica) and D.S.D.P. results (Legs 67 and 84 off Guatemala): A synthesis

The Pre-Upper Senonian basement of Costa Rica crops out in the Santa Elena and Nicoya peninsulas. From south to north and from base to top the basement includes: the Esperanza, Matapalo and Santa Elena units. The Esperanza unit is Albian-Santonian in age and consists mainly of pillow basalt and massive basalt flows. The Matapalo unit includes Callovian to Cenomanian radiolarite and includes massive basalt flows, basalt, and dolerite basement. The Santa Elena unit contains ultramafic and mafic rocks in which harzburgite is the major component. The most important tectonic features of the Nicoya Complex are the large Santa Elena and Matapalo nappes. Nappe emplacement was from north to south during upper Santonian time. The sedimentary cover of the Nicoya Complex comprises:

1. (1) the Campanian El Viejo Formation that consists of shallow-water sediments in the north (Santa Elena Peninsula) and the Campanian-Maastrichtian Sabana Grande Formation of deep-water origin in the South (Nicoya Peninsula);

2. (2) Paleocene strata indicating deposition in a deep-water environment comprises the Rivas, Las Palmas and Samara Formations;

3. (3) a post-upper Eocene (?) sequence that consists of the shallow-water Barra Honda and Montezuma Formations.

Two unconformities are significant geological features of the upper-Senonian to Tertiary history of Costa Rica. The lower one is at the base of the Sabana Grande Formation and marks a major change in the geologic conditions (basalt is scarce in the Campanian-Tertiary series); the upper unconformity at the base of the Barra Honda and Montezuma Formations is not as major as the lower one. During post-Campanian time, normal faulting occurred in two stages separated by a strong erosional phase.The geology of the landward slope of the adjacent Middle America Trench is outlined by interpreting multifold seismic reflection records off the west coast of Costa Rica and the DSDP Legs 67 and 84 transects off Guatemala. The western Caribbean plate boundary may have been under extensional stress for the last 75 m.y. The strong landward-dipping reflectors of the Middle America Trench landward slope off Guatemala could be equivalent to the on-land pre-Campanian overthrusts of Costa Rica. The available data are consistent with the Convergent Extensional margin concept.     

Cadmium transport in sediments by tubificid bioturbation: An assessment of model complexity

Biogeochemistry of metals in aquatic sediments is strongly influenced by bioturbation. To determine the effects of biological transport on cadmium distribution in freshwater sediments, a bioturbation model is explored that describes the conveyor-belt feeding of tubificid oligochaetes. A stepwise modelling strategy was adopted to constrain the many parameters of the model: (i) the tubificid transport model was first calibrated on four sets of microspheres (inert solid tracer) profiles to constrain tubificid transport; (ii) the resulting transport coefficients were subsequently applied to simulate the distribution of both particulate and dissolved cadmium. Firstly, these simulations provide quantitative insight into the mechanism of tubificid bioturbation. Values of transport coefficients compare very well with the literature, and based on this, a generic model of tubificid bioturbation is proposed. Secondly, the application of the model to cadmium dataset sheds a light on the behaviour of cadmium under tubificid bioturbation. Cadmium enters the sediment in two ways. In one pathway, cadmium enters the sediment in the dissolved phase, is rapidly absorbed onto solid particles, which are then rapidly transported to depth by the tubificids. In the other pathway, cadmium is adsorbed to particles in suspension in the overlying water, which then settle on the sediment surface, and are transported downwards by bioturbation. In a final step, we assessed the optimal model complexity for the present dataset. To this end, the two-phase conveyor-belt model was compared to two simplified versions. A solid phase-only conveyor-belt model also provides good results: the dissolved phase should not be explicitly incorporated because cadmium adsorption is fast and bioirrigation is weak. Yet, a solid phase-only biodiffusive model does not perform adequately, as it does not mechanistically capture the conveyor-belt transport at short time-scales.     

Direct Multiple-Point Geostatistical Simulation of Edge Properties for Modeling Thin Irregularly Shaped Surfaces

Thin, irregularly shaped surfaces such as clay drapes often have a major control on flow and transport in heterogeneous porous media. Clay drapes are often complex, curvilinear three-dimensional surfaces and display a very complex spatial distribution. Variogram-based stochastic approaches are also often not able to describe the spatial distribution of clay drapes since complex, curvilinear, continuous, and interconnected structures cannot be characterized using only two-point statistics. Multiple-point geostatistics aims to overcome the limitations of the variogram. The premise of multiple-point geostatistics is to move beyond two-point correlations between variables and to obtain (cross) correlation moments at three or more locations at a time using training images to characterize the patterns of geological heterogeneity. Multiple-point geostatistics can reproduce thin irregularly shaped surfaces such as clay drapes, but this is often computationally very intensive. This paper describes and applies a methodology to simulate thin, irregularly shaped surfaces with a smaller CPU and RAM demand than the conventional multiple-point statistical methods. The proposed method uses edge properties for indicating the presence of thin irregularly shaped surfaces. Instead of pixel values, edge properties indicating the presence of irregularly shaped surfaces are simulated using snesim. This method allows direct simulation of edge properties instead of pixel properties to make it possible to perform multiple-point geostatistical simulations with a larger cell size and thus a smaller computation time and memory demand. This method is particularly valuable for three-dimensional applications of multiple-point geostatistics.     

Compressional- and transpressional-stress pattern for Pliocene and Quaternary brittle deformation in fore arc and intra-arc zones (Andes of Central and Southern Chile)

Kinematic analysis of fault slip data for stress determination was carried out on Late Miocene to Quaternary rocks from the fore arc and intra-arc regions of the Chilean Andes, between 33° and 46° south latitudes. Studies of Neogene and Quaternary infilling (the Central Depression), as well as plutonic rocks of the North Patagonian Batholith along the Liquiñe–Ofqui Fault Zone, have revealed various compressional and/or transpressional states of stress. In the Pliocene, the maximum compressional stress (σ₁) was generally oriented east–west. During the Quaternary, the deformation was partitioned into two coeval distinctive states of stress. In the fore arc zone, the state of stress was compressional, with σ₁ oriented in a N–S to NNE–SSW direction. In the intra-arc zone the state of stress was transpressional with σ₁ striking NE–SW. Along the coast, in one site (37°30′S) the Quaternary strain deformation is extensional, with an E–W direction, which can be explained by a co-seismic crustal bending readjustment.     

A late Triassic 40Ar/39Ar age for the El Hammam high-REE fluorite deposit (Morocco): mineralization related to the Central Atlantic Magmatic Province?

El Hammam is the only fluorite mine in Morocco (production 100,000 t/year). The fluorite mineralization is in an array of fluorite–calcite veins and is characterized by unusually high REE content in carbonate minerals (1,400 ppm in calcite; up to 2,000 ppm in siderite) and in fluorite (about 600 ppm). Since the 1960s, the genesis of the deposit has been attributed to a mesothermal hydrothermal event connected with late-Variscan granitic intrusions. Precise ⁴⁰Ar/³⁹Ar dating of hydrothermal K-feldspar yields an age of formation of the El Hammam deposit at 205 ± 1 Ma. Its genesis is therefore associated in time and space with the development of the Triassic–Jurassic basins and the associated anorogenic continental flood basalts of the Moroccan Mesetian Middle Atlas. The source of the hydrothermal mineralization (magmatic and/or metamorphic) is discussed.