Short-term (≤2 yrs) estuarine mudflat and saltmarsh sedimentation: High-resolution data from ultrasonic altimetery, rod surface-elevation table, and filter traps

Rates of short-term (up to 2 years) bed elevation change and sedimentation from mudflats to salt marshes were measured in a rapidly infilling macrotidal estuary using an original combination of three high-resolution techniques: an ultrasonic altimeter, the Rod Surface-Elevation Table (RSET) method, and filter traps. The Authie estuary is located on a straight, sand-rich coast and is undergoing rapid infill under the influence of flood-dominant tides reinforced by wave action. The estuarine sediment suite consists of both mud and sand derived from the sea, of sand derived from storm wave erosion of dunes lining the north bank of the estuary, and, to a much smaller extent, of mud from the river catchment. Bed elevation change and sedimentation rates show an expected increase with the duration of tidal flooding (hydroperiod) in both space and time. The estuarine bed sediment suite changes from sandy at the mouth to muddy within the low-energy inner estuary, where mudflats are rapidly accreting, paving the way for the formation of increasingly denser and mature salt marshes from the high-sedimentation pioneer zone to the upper marsh where annual sedimentation is very low. Recorded variability in rates of bed elevation change and sedimentation reflect the influence of estuarine macro-scale and local sediment transport and depositional processes in a macrotidal context dominated by high inputs of allochthonous sediments.     

Adaptive model of plankton dynamics for the North Atlantic

Plankton ecosystems in the North Atlantic display strong regional and interannual variability in productivity and trophic structure, which cannot be captured by simple plankton models. Additional compartments subdividing functional groups can increase predictive power, but the high number of parameters tends to compromise portability and robustness of model predictions. An alternative strategy is to use property state variables, such as cell size, normally considered constant parameters in ecosystem models, to define the structure of functional groups in terms of both behaviour and response to physical forcing. This strategy may allow us to simulate realistically regional and temporal differences among plankton communities while keeping model complexity at a minimum.We fit a model of plankton and DOM dynamics globally and individually to observed climatologies at three diverse locations in the North Atlantic. Introducing additional property state variables is shown to improve the model fit both locally and globally, make the model more portable, and help identify model deficiencies. The zooplankton formulation exerts strong control on model performance. Our results suggest that the current paradigm on zooplankton allometric functional relationships might be at odds with observed plankton dynamics. Our parameter estimation resulted in more realistic estimates of parameters important for primary production than previous data assimilation studies.Property state variables generate complex emergent functional relationships, and might be used like tracers to differentiate between locally produced and advected biomass. The model results suggest that the observed temperature dependence of heterotrophic growth efficiency [Rivkin, R.B., Legendre, L., 2001. Biogenic carbon cycling in the upper ocean: effects of microbial respiration. Science 291 (5512) 2398-2400] could be an emergent relation due to intercorrelations among temperature, nutrient concentration and growth efficiency. A major advantage of using property state variables is that no additional parameters are required, such that differences in model performance can be directly related to model structure rather than parameter tuning.     

Intraseasonal atmospheric variability and its interannual modulation in Central Africa

The spatial and temporal structures of the intraseasonal atmospheric variability over central Africa is investigated using 2.5°?×?2.5° daily outgoing longwave radiation (OLR) and National Centers for Environmental Prediction (NCEP) Reanalysis zonal winds for the period 1980–2010. The study begins with an overview of the Central African rainfall regime, noting in particular the contrast amongst Western and Eastern parts, with different topography and surface conditions features. The annual mean rainfall and OLR over the region revealed a zone of intense convective activity centered on the equator near 30°E, which extends southward and covers almost all the Congo forest. The annual cycle of rainfall reflects the classical bi-annual shift of Inter-Tropical Convergence Zone across the equatorial belt, between 10°S and 10°N. The result of the empirical orthogonal functions (EOFs) analysis has shown that the three leading EOF modes explain about 45?% of total intraseasonal variability. The power spectra of all the three corresponding principal components (PCs) peak around 45–50?days, indicating a Madden–Julian Oscillation (MJO) signal. The first mode exhibits high positive loadings over Northern Congo, the second over Southern Ethiopia and the third over Southwestern Tanzania. The PCs time series revealed less interannual modulation of intraseasonal oscillations for the Congo mode, while Ethiopian and Tanzanian modes exhibit strong interannual variations. H?vmoller plots of OLR, 200 and 850?hPa NCEP zonal winds found the eastward propagating features to be the dominant pattern in all the three times series, but this propagation is less pronounced in the OLR than in the 850 and 200?hpa zonal wind anomalies. An index of MJO strength was built by averaging the 30–50?day power for each day. A plot of MJO indices and El Ni?o Southern Oscillation (ENSO) cycle confirm a strong interannual modulation of MJO over Eastern central Africa partially linked with the ENSO events (El Ni?o and La Ni?a). Strong MJO activity is observed during La Ni?a years or during ENSO-neutral years, while weak or absent MJO activity is typically associated with strong El Ni?o episodes.     

Dating multistage paleofluid percolations: A K-Ar and O/O study of fracture illites from altered Hercynian plutonites at the basement/cover interface (Poitou High, France)

Isotopic age determination of fluid events in basement fractures is of prime importance for the reconstruction of paleo-hydraulic regimes. However, material from fracture or wall-rock is not generally easily dated. In the case of fractures filled by minerals such as phyllosilicates, it can be expected that subsequent fluid circulation may cause partial alteration or recrystallization of the previous phyllosilicates, disturbing the isotope signature. Using a specific methodology, including the extraction process without contamination of the finest (<0.2 μm) authigenic fractions, identification of clay fractions by X-ray diffraction (XRD), scanning electron microscopy, and electron microprobe, analysis of stable isotope composition (D/H, δ¹⁸O) and K-Ar dating, fluid event ages can be estimated. This methodology was applied to the northwestern margin of the French Massif Central, where basinal brines have interacted with the sedimentary cover (infra-Toarcian formations) and the fractured Hercynian crystalline basement. During periods of unknown age, precipitates from brines sealed most basement fractures as carbonates, and a recrystallization of early Hercynian phengite (+chlorite) into illite and illite/smectite minerals occurred in the earlier fractures.XRD patterns show that the clay fraction is dominated by illite and ordered mixed-layer minerals having a relatively high amount of illite (I-S R3). In the shallowest samples beneath the paleo-surface, a late assemblage is identified as a mixture of I-S minerals, a part of them being characterized by significant amounts of swelling layers (I-S R0).The δD values of the clay fractions are fairly constant around −50 ± 10‰, but δ¹⁸O values of the same clay fractions display a wide range from 8‰ to 18‰ (SMOW). The study of the size fractions between 2 and 0.2 μm reveals a correlation between K-Ar ages and δ¹⁸O values, which cannot be related to a change in the relative amounts of clay minerals. Deep fractures (at depths of 570 and 923 m) are characterized by δ¹⁸O values around 10.3 ± 0.4‰ SMOW and old ages ranging from 253 to 272 Ma. The finest fractions (<0.2 μm) of clays located at shallow level (<300 m) beneath the paleo-surface yield the highest δ¹⁸O values (15.7-18.2‰) and the youngest K-Ar dates (188 to 198 Ma). These dates are likely to record the extensional episode and thermal anomaly related to the rifting of central Atlantic Ocean (c. 190 Ma). The other important thermal/extensional episode which affected the Aquitaine Basin, namely the opening of the Gascogne gulf at c. 120 Ma, is not detected by the K-Ar method on the clay fractions. We believe that resetting of clay-type K-Ar ages linked to recrystallization was favoured in the upper part of the basement where the ancient (Hercynian) clay minerals were destabilized by subaerial low-temperature alteration during Permo-Triassic times.From a methodologic point of view, the analytical characterization of several size fractions of clays from reactivated fractures, using both stable isotope geochemistry and K-Ar isotope geochemistry, can be considered as a powerful tool for dating fluid events when no suitable material for conventional methods is available.     

Mn, Fe, Zn and As speciation in a fast-growing ferromanganese marine nodule

The speciation of Mn, Fe, As, and Zn in a fast-growing (0.02mm/yr), shallow-marine, ferromanganese nodule has been examined by micro X-ray fluorescence, micro X-ray diffraction, and micro X-ray absorption spectroscopy. This nodule exhibits alternating Fe-rich and Mn-rich layers reflecting redox variations in water chemistry. Fe occurs as two-line ferrihydrite. The As is strictly associated with Fe and is mostly pentavalent, with an environment similar to that of As sorbed on or coprecipitated with synthetic ferrihydrite. The Mn is in the form of turbostratic birnessite with ∼10% trivalent manganese in the layers and probably ∼8% corner-sharing metal octahedra in the interlayers. The Zn is enriched on the rim of the nodule, associated with Mn. The Zn is completely (>90%) tetrahedrally coordinated and sorbed in the interlayers of birnessite on vacant layer Mn sites. The Zn and Mn species are similar to ones found in soils, suggesting common structural principles despite the differing formation conditions in these systems.     

Even-numbered <Emphasis Type="Italic">n</Emphasis>-alkanes/<Emphasis Type="Italic">n</Emphasis>-alkenes predominance in surface sediments of Gabes Gulf in Tunisia

We investigated the mineral composition and trace element contents of dustfall with different deposited phases at the Minqin Oasis, in China’s Hexi Corridor. The contents of elements such as Pb, Cd, Cu, As, Sb, Se, Rb, Cs, and Ba (believed to be of anthropogenic origin) indicated that the significance of human impacts on dust emissions increased from 1970s to the early 2000s. However, variations in the content of elements including Sc, Mn, Na, Cr, V, Eu, Ce, Nb, Zr, La, and Ce (believed to originate from natural processes such as physical and chemical weathering) show no obvious changes in the major potential dust source areas (PSAs) in this region. In addition, analysis of the assemblage of trace elements in dustfall indicated that the elements assumed to originate from anthropogenic and natural processes appear to be intertwined, leading to difficulties and uncertainties in identifying the PSAs and evaluating the significance of human impacts on dust emissions. Comparisons of the element contents of dustfall collected in Beijing and Minqin with similar data for Beijing show that under different conditions some differences in ranges are permitted; the contents of most trace elements were similar even though the dustfall in the two areas came from different sources. These results suggest that before attempting to identify major PSAs, researchers should perform an integrated analysis that includes the mineral, elemental, geomorphological, vegetation cover, climatic conditions, and other characteristics of the regions being studied.     

Chemical and structural control of the partitioning of Co, Ce, and Pb in marine ferromanganese oxides

The oxidation state and mineral phase association of Co, Ce, and Pb in hydrogenetic, diagenetic, and hydrothermal marine ferromanganese oxides were characterized by X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) spectroscopy and chemical extraction. Cobalt is trivalent and associated exclusively with the Mn oxide component (vernadite). Cerium is tetravalent in all genetic-type oxides (detection limit for Ce(III) ∼ 5 at. %), including Fe-rich areas (ferrihydrite) of hydrogenetic oxides, and is associated primarily with vernadite. Thus, the extent of a Ce anomaly does not result from variations in redox conditions, but appears to be kinetically controlled, decreasing when the growth rate increases from hydrogenetic to diagenetic to hydrothermal oxides. Lead is divalent and associated with Mn and Fe oxides in variable proportions. According to EXAFS data, Pb is mostly sorbed on edge sites at chain terminations in Fe oxide and at layer edges in Mn oxide (ES complex), and also on interlayer vacancy sites in Mn oxide (TCS complex). Sequential leaching experiments, spectroscopic data, and electrochemical considerations suggest that the geochemical partitioning in favor of the Mn oxide component decreases from Co to Ce to Pb, and depends on their oxidative scavenging by Mn and Fe oxides.     

Stochastic Post-Processing of CFSR Daily Precipitation across Canada

Reanalyses, based on numerical weather prediction methods assimilating past observations, provide continuous precipitation datasets and represent interesting options for assessing the climatology of regions with sparse station networks (e.g., northern Canada). However, reanalysis series cannot be used directly because of possible biases and mismatch between their spatial and temporal resolutions with that needed for local applications. To address these issues, a Stochastic Model Output Statistics (SMOS) approach was selected to post-process precipitation series simulated by the Climate Forecast System Reanalysis (CFSR) across Canada. This approach uses CFSR precipitation as a covariate and is based on two regression models: the first one is a logistic regression that deals with precipitation occurrence, and the second is a vector generalized linear model for precipitation intensity. At-site post-processed daily precipitation series are randomly generated using the SMOS approach, and selected climate indicators from the Expert Team on Climate Change Detection and Indices, which is jointly sponsored by the Commission for Climatology of the World Meteorological Organization's (WMO) World Climate Data and Monitoring Programme, the Climate Variability and Predictability Programme of the World Climate Research Programme, and the Joint WMO-IOC Technical Commission for Oceanography and Marine Meteorology (CCI/CLIVAR/JCOMM) are estimated and compared with corresponding observed and CFSR values. The two models in the SMOS approach, in addition to adequately correcting systematic biases, produced better predictions than the climatology of the wet and dry and intensity sequences. Additionally, the SMOS generally yields consistent climate indices when compared with those from CFSR without post-processing, though there is still room for improvement for specific indices (e.g., annual maximum of cumulative wet days).     

Slip rate of trench‐parallel normal faulting along the Mejillones Fault (Atacama Fault System): Relationships with the northern Chile subduction and implications for seismic hazards

The recent tectonics of the arid northern Chile Andean western forearc is characterized by trench‐parallel normal faults within the Atacama Fault System (AFS). Since the 1995‐Mw 8.1 Antofagasta earthquake, the mechanism driving this recent and localized extension is considered to be associated with the seismic cycle within the subduction zone. Analyzing morphotectonic patterns along these faults allows examining the seismic potential associated with the subduction zone. Using field Digital Elevation Models and in situ‐produced cosmogenic ¹⁰Be, we determined a 0.2 mm/a long‐term slip rate along the Mejillones Fault, one of the most prominent structures within the AFS. This result suggests that the AFS corresponds to slow slip rate faults despite the rapid subduction context. However, the size of coseismic slips observed along the AFS faults suggests that larger subduction earthquakes (Mw > 8.1) may occur episodically in the area.     

Fradkin-Bacry-Ruegg-Souriau perihelion vector for Gorringe-Leach equations

We show that every generalized Gorringe-Leach equation admits an associated Fradkin-Bacry-Ruegg-Souriau’s vector which, in general, is only a piecewise conserved quantity. In the case of dualizable generalized Gorringe-Leach equations, which include the case of conservative motions in central power law potentials, the image sets of the FBRS vectors for dual classes are dual images of each other.