Characterization of Chlorination By-products in Cooling Effluents of Coastal Nuclear Power Stations

In power stations, the cooling effluents are chlorinated to avoid excessive biofouling. Yet, this disinfecting treatment leads to the formation of halogenated by-products. In spite of possible toxicity of such compounds towards aquatic organisms, there is an evident lack of information on the formation of halogenated compounds in chlorinated seawater samples. So, this study was undertaken to identify and quantify halogenated compounds (i.e. trihalomethanes, haloacetonitriles, halophenols and haloacetic acids) in effluents from three French nuclear power stations. In addition, experiments conducted in the laboratory allowed the determination of the kinetics of formation of the main compounds detected: bromoform, dihaloacetonitrile, 2,4,6-tribromophenol and dibromoacetic acid. Good agreement was obtained between the experiments conducted either on site or in the laboratory. In particular, evidence was given on the formation of brominated compounds (due to the high concentrations of bromide ions in seawater).     

Apports des méthodes hydrodynamiques à l’étude du fonctionnement des aquifères karstiques de l’Atlas de Beni-Mellal (Maroc)

Résumé

Le massif karstique de Beni-Mellal, dans le Haut Atlas (Maroc), est constitué essentiellement par des calcaires dolomitiques du Lias qui présentent en surface des figures de dissolution spectaculaires. Le massif est situé entre 500 m et 2 400 m d’altitude et alimente plusieurs sources dont la plus importante est celle d’Aïn Asserdoune. La quasi-totalité des sources émergent au niveau des contacts chevauchants qui limitent le Jurassique calcaire des formations tertiaires sousjacentes du piémont. L’étude des débits classés et du tarissement ainsi que l’analyse corrélatoire et spectrale des chroniques pluies – débits du système karstique drainé par la source d’Aïn Asserdoune permettent de caractériser cet aquifère. Il s’agit d’un aquifère inertiel qui assure le flot de base. Cet aquifère est caractérisé par l’existence de réserves dynamiques importantes. Il est influencé par un karst superficiel fonctionnant en période de hautes eaux ainsi que par des apports latéraux provenant des compartiments voisins du massif de Beni-Bellal.     

Environmental controls on the development of Mississippian microbial carbonate mounds and platform limestones in southern Montagne Noire (France)

Late Mississippian carbonates in southern Montagne Noire are dominantly domical to laterally‐accreted microbial mounds in some formations, as well as stratiform microbial limestones occurring in hundreds of olistoliths within a flysch basin, constituting pieces of a giant puzzle that are used to help reconstruct a platform in a region that is no longer preserved. Petrographic data of limestone samples from 14 continuous long sections of olistoliths have been analyzed statistically, using multivariate clustering (Q‐mode) of the components/matrix/cement and canonical correspondence analysis that allow the reconstruction of the environmental parameters of carbonate microbial communities in space and time. Clustering analysis separated microbial and non‐microbial facies. The calculation of indices along the various axes from canonical correspondence analysis allows recognition of the controlling factors of the mounds and microbial growth as being turbidity, light penetration, bathymetry and storms. Turbidity and light penetration are the primary factors controlling the morphology of the microbial limestones. Representation of the light penetration and bathymetry indices on the stratigraphical sections defines two vertical environmental gradients. Light penetration can be subdivided into euphotic, euphotic–dysphotic and dysphotic‐aphotic conditions. The representation of the bathymetry allows the subdivision of samples into a deeper outer ramp, external mid‐ramp and internal mid‐ramp. The curve distance from the section base = f (index) suggests a cyclicity for the platform that cannot be compared with the onlap curve defined from other cratonic areas (Moscow Basin), and thus the cyclic succession of the Montagne Noire is interpreted to have been mostly tectonically‐controlled. Integration of the data allowed the reconstruction of the original Mississippian carbonate platform, where, up to the Mikhailovian, it appears to correspond to a platform morphology, with narrow shallow water facies and wide turbiditic systems, whereas the width of shallow‐water settings expanded during the Venevian to the Protvian, forming a ramp or distally‐steepened ramp with widespread microbial limestones.     

Datation UPb sur zircons des dolérites tholéiitiques pyrénéennes (ophites) à la limite Trias–Jurassique et relations avec les tufs volcaniques dits « infra-liasiques » nord-pyrénéens

The tholeiitic doleritic magmatism (ophites) in the Aspe valley of the Pyrenees has been dated on the Triassic–Jurassic boundary (199±2 Ma) by the UPb method on zircon (SHRIMP). Emplacement of the ophites was probably synchronous with that of the earliest ‘Infraliassic’ Ségalas tuffs. The ophites are thus related to the Central Atlantic Magmatic Province (CAMP) whose emplacement linked with the fracturing of Pangea, preceded the opening of the Atlantic Ocean. To cite this article: P. Rossi et al., C. R. Geoscience 335 (2003).     

Datation Ar/Ar des leucogranites sous couverture du complexe plutonique de Charroux–Civray (Vienne)Ar/Ar dating of leucogranites in the sediment-covered Charroux–Civray complex (Vienne)

⁴⁰Ar/³⁹Ar dating on muscovites, performed on leucogranitic intrusions of Charroux–Civray plutonic complex, points out the existence of two peraluminous magmatic activities, whose equivalents are known in the Limousin: (1) garnet-bearing leucogranitic veins at ca. 340 Ma; (2) a specialised leucogranite associated with W ± Sn deposits at ca 310 Ma. However, available ⁴⁰Ar/³⁹Ar data do not allow us to provide further data concerning the age and the geometry at depth of a large leucogranitic body identified by geophysics. To cite this article: P. Alexandre et al., C. R. Geoscience 334 (2002) 1141–1148.     

Cadmium transport in sediments by tubificid bioturbation: An assessment of model complexity

Biogeochemistry of metals in aquatic sediments is strongly influenced by bioturbation. To determine the effects of biological transport on cadmium distribution in freshwater sediments, a bioturbation model is explored that describes the conveyor-belt feeding of tubificid oligochaetes. A stepwise modelling strategy was adopted to constrain the many parameters of the model: (i) the tubificid transport model was first calibrated on four sets of microspheres (inert solid tracer) profiles to constrain tubificid transport; (ii) the resulting transport coefficients were subsequently applied to simulate the distribution of both particulate and dissolved cadmium. Firstly, these simulations provide quantitative insight into the mechanism of tubificid bioturbation. Values of transport coefficients compare very well with the literature, and based on this, a generic model of tubificid bioturbation is proposed. Secondly, the application of the model to cadmium dataset sheds a light on the behaviour of cadmium under tubificid bioturbation. Cadmium enters the sediment in two ways. In one pathway, cadmium enters the sediment in the dissolved phase, is rapidly absorbed onto solid particles, which are then rapidly transported to depth by the tubificids. In the other pathway, cadmium is adsorbed to particles in suspension in the overlying water, which then settle on the sediment surface, and are transported downwards by bioturbation. In a final step, we assessed the optimal model complexity for the present dataset. To this end, the two-phase conveyor-belt model was compared to two simplified versions. A solid phase-only conveyor-belt model also provides good results: the dissolved phase should not be explicitly incorporated because cadmium adsorption is fast and bioirrigation is weak. Yet, a solid phase-only biodiffusive model does not perform adequately, as it does not mechanistically capture the conveyor-belt transport at short time-scales.     

Direct Multiple-Point Geostatistical Simulation of Edge Properties for Modeling Thin Irregularly Shaped Surfaces

Thin, irregularly shaped surfaces such as clay drapes often have a major control on flow and transport in heterogeneous porous media. Clay drapes are often complex, curvilinear three-dimensional surfaces and display a very complex spatial distribution. Variogram-based stochastic approaches are also often not able to describe the spatial distribution of clay drapes since complex, curvilinear, continuous, and interconnected structures cannot be characterized using only two-point statistics. Multiple-point geostatistics aims to overcome the limitations of the variogram. The premise of multiple-point geostatistics is to move beyond two-point correlations between variables and to obtain (cross) correlation moments at three or more locations at a time using training images to characterize the patterns of geological heterogeneity. Multiple-point geostatistics can reproduce thin irregularly shaped surfaces such as clay drapes, but this is often computationally very intensive. This paper describes and applies a methodology to simulate thin, irregularly shaped surfaces with a smaller CPU and RAM demand than the conventional multiple-point statistical methods. The proposed method uses edge properties for indicating the presence of thin irregularly shaped surfaces. Instead of pixel values, edge properties indicating the presence of irregularly shaped surfaces are simulated using snesim. This method allows direct simulation of edge properties instead of pixel properties to make it possible to perform multiple-point geostatistical simulations with a larger cell size and thus a smaller computation time and memory demand. This method is particularly valuable for three-dimensional applications of multiple-point geostatistics.     

Pilot field experiment with canister-embedding clay under simulated repository conditions

Precompacted annular clay blocks surrounding a casing with a heater were emplaced in a borehole with 20 cm diameter and 2.8 m depth in granite. The heater was in operation for 8 months and raised the temperature of the clay to 176°C close to the casing. At the extraction the clay was completely water-saturated close to the rock and it had experienced an increased water content also close to the hot casing.

Mineralogical changes of the Ca-smectite clay were indicated by a slight increase in CEC and by an XRD-based conclusion that the content of low-charge smectite increased, while the initial content of kaolinite was reduced.     

Quantitative assessment on basin-scale hydrological services of wetlands

Despite recognizing the importance of hydrological function of wetlands, basin-scale wetlands services have rarely been investigated. The PHYSITEL/HYDROTEL modelling platform was used to quantitatively assess the impact of wetlands on quickflow and baseflow with paired simulation scenarios in Duobukuli River Basin, namely with wetlands and without wetlands.Simulation results showed that wetlands exert significant impact on basin hydrological processes by decreasing streamflow and altering streamflow regime(magnitude, frequency, duration and time of flow events). The intensity(significant or not) of wetlands influences on quickflow had daily, monthly and annual variation. Wetlands significantly attenuated quickflow during flood season while slightly support daily, monthly and annual baseflow. The average quickflow attenuation and baseflow support of wetlands were 5.89% and 0.83%, respectively. Although the intensity and effect(mitigation or augment) of wetlands on streamflow temporally varied at daily, monthly, seasonal and annual scales, wetland overall mitigated quickflow and augment baseflow in Duobukuli River Basin. Our results could provide insights for future decision-making for rehabilitation and conservation of wetlands as well as integrated basin water resources management.     

Observed Trends in Total Vertical Column Abundances of Atmospheric Gases from IR Solar Spectra Recorded at the Jungfraujoch

Since 1984, about 15000 high quality infrared solar spectra have beenrecorded with state-of-the-art grating and Fourier transform spectrometersat the International Scientific Station of the Jungfraujoch, Switzerland.Nonlinear least squares spectral curve fitting of selected microwindowscontaining isolated and well characterized lines of 20 telluric gases haveallowed to retrieve their total vertical column abundances above thestation, leading to observational data bases essential to derive long- andshort-term changes experienced by these species during the last 12 years. Inthis paper, we focus on atmospheric gases of particular interest within thecontext of the EUROTRAC/TOR (Tropospheric Ozone Research) project; secularevolution as well as seasonal cycles of the minor constituentsCH₄, CO and of the trace gasesC₂H₆, OCS, C₂H₂, HCNand H₂CO are reported and discussed. The long-livedN₂O is included as a tracer of the dynamic activity of theatmosphere.