Siderophile element characteristics of acapulcoite–lodranites and winonaites: Implications for the early differentiation processes of their parent bodies

We have studied magnetic fractions of five acapulcoites, three lodranites, and two winonaites to investigate chemical compositions of their precursor materials and metallic partial melting processes occurring on their parent bodies. One winonaite metal is similar in composition to low Au, low Ni IAB iron subgroup, indicating genetic relationship between them. Magnetic fractions of chondrule‐bearing acapulcoite and winonaite have intermediate chemical compositions of metals between H chondrites and EL chondrites. This fact indicates that the precursor materials of acapulcoite–lodranites and winonaites were similar to H and/or EL chondrites in chemical compositions. Magnetic fractions in acapulcoite–lodranites have a large variety of chemical compositions. Most of them show enrichments of W, Re, Ir, Pt, Mo, and Rh, and one of them shows clear depletion in Re and Ir relative to those of chondrule‐bearing acapulcoite. Chemical compositional variations among acapulcoite–lodranite metals cannot be explained by a single Fe‐Ni‐S partial melting event, but a two‐step partial melting model can explain it.     

Interannual variations in low potential vorticity water and the subtropical countercurrent in an eddy-resolving OGCM

Interannual-to-decadal variations in the subtropical countercurrent (STCC) and low potential vorticity (PV) water and their relations in the North Pacific Ocean are investigated on the basis of a 60-year-long hindcast integration of an eddy-resolving ocean general circulation model. Although vertically coherent variations are dominant for STCC interannual variability, a correlation analysis shows that an intensified STCC vertical shear accompanies lower PV than usual to the north on 25.5- to 26.1-σ_θ isopycnal surfaces, and intensified meridional density gradient in subsurface layers, consistent with Kubokawa’s theory (J Phys Oceanogr 29:1314–1333, 1999). The low-PV signals appear at least 2 years before peaks of STCC, propagating southwestward from the subduction region.     

Phase F,a new hydrous magnesium silicate synthesized at 1000 °C and 17 GPa: Crystal structure and estimated bulk modulus

The structure of phase F, a non-stoichiometric hydrous silicate synthesized in a uniaxial, split-sphere, multi-anvil apparatus at conditions of 17 GPa and 1000° C, has been solved and refined in space group P6₃cm, using synchrotron X-ray data for a single crystal of a size 18 × 24 × 30 μm. The composition and unit cell for phase F are Mg_3.35Si_5.51H_7.26O₁₈, a=5.073(3) Å, c=14.013(9) Å, 7= 312.3(5) ų. The structure contains layers with many similarities to superhydrous phase B. The layers of oxygen atoms are stacked in the ABCBAC-type double cubic closest packing arrangement. The bulk modulus of phase F was estimated from the structural and compositional relationship to superhydrous phase B and periclase.     

Uranium and Thorium Isotope Distribution in an Offshore Bottom Sediment Core of the Selenga Delta, Lake Baikal, Siberia

Distribution of uranium and thorium isotopes in a short sediment core obtained offshore of the Selenga Delta in Lake Baikal, Siberia, was investigated to establish their sedimentary behaviors and to look for a linkage to paleoenvironmental changes. The sediments were composed of dominantly fine detrital materials (70–85%) and a relatively high sedimentation rate (ca. 0.03 cm y⁻¹). The depth profile of ²³⁸U content in bulk sediment samples showed a large variation of 70–123 Bq kg⁻¹, while ²³²Th profile showed a relatively narrow range from 36 to 56 Bq kg⁻¹. The observed ²³⁴U/²³⁸U activity ratios revealed a marked disequilibrium ranging from 1.53 to 1.84 with a mean value of 1.71 ± 0.07, demonstrating the presence of 50–80% authigenic ²³⁸U in the bulk sediments. The distribution of this authigenic ²³⁸U did not display any clear correlation with variations in sediment composition (organic, carbonate, Bio-SiO₂ and mineral contents) including grain size median. The profile of terrigenous ²³⁸U showed a relatively similar pattern to that of ²³²Th. Results of sequential leaching indicate that ²³⁸U in Fe–Mn oxyhydroxides fractions were responsible for the distribution of authigenic ²³⁸U rather than in Bio-SiO₂ fraction. The distribution of authigenic ²³⁸U in the bottom sediments may be explained by the fluctuation of U adsorption capacity on particles including organic matter and Fe–Mn oxyhydroxides before they entered the lake. This study highlights the potential use of authigenic and terrigenous U (Th) signatures in sediments to trace the behavior of U (Th) and to reconstruct environmental (e.g., hydrological) changes in the lake catchment area.     

Extracting fair-weather data from atmospheric electric-field observations at Syowa Station, Antarctica

At Syowa Station (69.0°S, 39.6°E), located on East Ongul Island near the continent of Antarctica, atmospheric electric-field observations started in 1968 and had been carried out intermittently. An improved electric-field mill at Syowa Station had and obtained better-quality atmospheric electric-field data from February 2005 to January 2006. After a 1-year interruption, the observations resumed in January 2007.The atmospheric electric-field data from Syowa Station are often contaminated due to local disturbances caused by near-ground meteorological phenomena. We examined correlations between the atmospheric electric field and near-ground weather from February 2005 to January 2006 and from February 2007 to January 2008, and proposed a criterion to extract “fair-weather” electric-field data based on wind speed and cloud coverage data. The diurnal variation of fair-weather data in January followed the shape of the so-called Carnegie curve. Fair-weather data obtained during a substorm showed some correspondence between the atmospheric electric field and variations in the geomagnetic field. This newly developed extraction method may enable the use of atmospheric electric-field data for studying the solar terrestrial environment.     

Geochronological review of Sambagawa metamorphic belt in Southwest Japan

Based on almost all available published age data, the protolith ages, peak metamorphic ages and cooling rate of the Sambagawa metamorphic belt have been discussed and the latest constraints on the ages of the Sambagawa metamorphism and subduction-related accretionary evolutions were summarized. Peak metamorphic conditions attained within the Kuma nappe complex at ca. 145～185 Ma, and uplift through ca. 500℃ at ca. 150 Ma and 350～400℃ at ca. 110～ 115 Ma. The protolith sediments of the Besshi nappe complex were accumulated and subsequently progressively subducted and suffered high P-T prograde metamorphism during the Kuma nappe complex uplifting. The Besshi nappe complex arrived maximum metamorphic conditions at ca. 110 ～ 120 Ma and subsequently started rapid uplift with the cooling rate of ca. 14.2℃/Ma at ca. 75 ～85 Ma, followed with the cooling rate of ca. 6.0 ～8.9℃/Ma. The Oboke nappe complex started subduction later than other tectonic units and arrived the peak metamorphic conditions at ca. 75 Ma, which followed by the uplift with a cooling rate of ca. 8℃/Ma.     

Spatial gradient analysis of urban green spaces combined with landscape metrics in Jinan City of China

1IN T R O D U C T IO NUrban green spaces can be consideredas the outdoorplacesintheurban covered with significanatmounts ofvegetation,naturalor manmade,as opposed to areasthatare paved or having buildingon them(JIM andC HEN,2003;SHIVANAND and SUZANA,2005)…     

The temporal record and sources of atmospherically deposited fly-ash particles in Lake Akagi-konuma,a Japanese mountain lake

Fly-ash particles comprising spheroidal carbonaceous particles (SCP) and inorganic ash spheres (IAS), produced from industrial fossil-fuel combustion, are found in lake sediments throughout the world where they provide an historical record of atmospheric pollutant deposition. These particles have been widely used to assess the temporal and spatial distribution of industrial atmospheric pollution in both freshwater and terrestrial environments in Europe and the USA. However, there have been very few palaeolimnological fly-ash studies undertaken in Japan and none in Japanese mountain lakes. Here, we present the historical SCP and IAS records from a radiometrically dated sediment core taken from Lake Akagi-konuma (36°31′ 54″N, 139°11′ 32″E; elevation 1,470 m) located 100 km north-west of Tokyo. Meteorological data and back trajectory analyses confirm potential sources both within Japan and further afield in China and South Korea. SCP contamination began in the 1950s and increased rapidly to a peak in the mid-1980s. It is thought this represents contamination of Japanese origin, principally oil-fired power stations within 150 km of the lake. The profile of IAS, almost solely coal-derived, shows a rapid increase in the 1970s, in contrast to the record of coal consumption in Japan. The IAS record is therefore thought to reflect long-range transport from coal combustion sources in eastern China which started to expand in the 1970s. This raises concerns over the potential impact on Japanese mountain areas from recent rapid increases in, and predicted acceleration of, emissions from this industrial process. The scale of SCP contamination recorded in Lake Akagi-konuma is equivalent to moderately impacted mountain lakes in Europe, but is at the upper end of the range for remote lakes in the western United States.     

Paleoposition of Southwest Japan at 16 Ma: Implication from paleomagnetism of the Miocene Ichishi Group

New paleomagnetic data from shallow-marine sediments of the Ichishi Group suggest a clockwise tectonic rotation of Southwest Japan in the Middle Miocene. Samples have been collected from mud or tuff layers at 17 sites. Stability of remanent magnetization has been examined by using alternating field and thermal demagnetization. The polarity sequence, composed of four normal and seven reversed polarity sites, is correlated to Polarity Epoch 16 (15.2–17.6 Ma), based on micropaleontological assignment of the upper Ichishi Group to Blow's Zone N8. The mean paleomagnetic direction of the 11 sites shows an anomalous declination toward the northeast. This result suggests that Southwest Japan was subjected to a clockwise rotation through 45° since 16 Ma. The clockwise rotation can be explained by the drift of Southwest Japan associated with the spreading of the Japan Sea during the Middle Miocene.     

Pin‐supported walls for enhancing the seismic performance of building structures

An application of a pin‐supported wall‐frame system in retrofitting an eleven‐story steel reinforced concrete frame is introduced. The retrofit aims at enhancing integrity and avoiding weak story failure in an existing moment‐resisting frame. Seismic performance of the building before and after the retrofit is assessed through nonlinear dynamic analysis. The results show that the pin‐supported walls are effective in controlling the deformation pattern of the ductile frame and hence in avoiding weak story failure. With the well‐controlled deformation pattern, carefully arranged energy dissipating devices are able to concentrate energy dissipations so that damage to the rest of the structure can be significantly reduced. Copyright © 2012 John Wiley & Sons, Ltd.