Periodic ab initio Hartree-Fock study of trigonal and orthorhombic phases of boric oxides

The structure and electronic properties of trigonal and orthorhombic boric oxide (B₂O₃) are studied using periodic ab initio Hartree-Fock method. The optimised structural parameters for two B₂O₃ polymorphs are in good agreement with experimental data. The analyses of their electronic structures provide insights into the chemical nature of the B–O bond and the way in which it changes with the coordination number around boron and oxygen. Our quantum-chemical study suggests that the orthorhombic form is more ionic than the trigonal form and that the coordination number of boron around oxygen plays a more dominant role than that of oxygen around boron in B₂O₃ crystals.     

Phase diagrams describing solid-gas equilibria in the system Fe-Mg-Si-O-C-H,and its bearing on redox states of chondrites

Abstract— Phase diagrams describing solid-gas equilibria in the system Fe-Mg-Si-O-C-H under H-rich conditions (～700–2000 K and 10^?2–10^?20 atm of Ph ₂), including solar nebula conditions, were constructed based on thermochemical calculations. Boundaries of vaporous phases, which are the first phases to condense from a gas, can be obtained without calculating condensation temperatures of individual gas compositions because the numbers of major gaseous species are the same as those of components in the concerned systems. Fractionations by condensation and/or evaporation can be discussed easily in such phase diagrams. A thermal divide, which is a barrier that vapors cannot cross by a single cooling process, was recognized in the phase diagrams. This is present on the Fe-MgO-SiO₂-CO-H plane at high temperatures (≥500–700 K) and plays an important role in fractionations. Oxidizing states of ordinary chondrites and carbonaceous chondrites before aqueous alteration are located at the O-rich side of the thermal divide. Such oxidizing states can be formed from the solar gas by fractionation in the primordial solar nebula because the solar composition is located on the O-rich side. On the other hand, the reducing states of enstatite chondrites, located at the O-poor side, cannot be formed as long as the thermal divide is present. The reducing states can be obtained by CO to CH₄ molecular reaction at low temperatures (≤500–700 K), where the high-temperature thermal divide is absent. Addition of H₂O-rich and CH₄-rich ice can explain establishment of the redox states of ordinary and enstatite chondrites, respectively.     

Microbial responses using denaturing gradient gel electrophoresis to oil and chemical dispersant in enclosed ecosystems

Microbial responses to the addition of oil with or without a chemical dispersant were examined in mesocosm and microcosm experiments by using denaturing gradient gel electrophoresis of bacterial ribosomal DNA and direct cell counting. When a water-soluble fraction of oil was added to seawater, increases in cell density were observed in the first 24h, followed by a decrease in abundance and a change in bacterial species composition. After addition of an oil-dispersant mixture, increases in cell density and changes in community structure coincided, and the amount of bacteria remained high. These phenomena also occurred in response to addition of only dispersant. Our results suggest that the chemical dispersant may be used as a nutrient source by some bacterial groups and may directly or indirectly prevent the growth of other bacterial groups.     

Penetration into low-density media: In situ observation of penetration process of various projectiles

In order to understand the penetration process of projectiles into lower-density targets, we carry out hypervelocity impact experiments using low-density (60 mg cm^?3) aerogel targets and various types of projectiles, and observe the track formation process in the targets using a high-speed camera. A carrot shaped track, a bulbous, and a “hybrid” one consisting of bulbous and thin parts, are formed. The results of the high-speed camera observations reveal the similarity and differences on the temporal evolution of the penetration depth and maximum diameter of these tracks. At very early stages of an impact, independent of projectile type, the temporal penetration depth is described by hydrodynamic models for the original projectiles. Afterward, when the breakup of projectiles does not occur, intact projectiles continue to penetrate the aerogels. In the case of the breakup of projectiles, the track expands with a velocity of about a sound velocity of the aerogel at final stages. If there are large fragments, they penetrate deeper and the tracks become a hybrid type. The penetration of the large fragments is described by hydrodynamic models. Based on these results, we discuss the excavation near the impact point by shock waves.     

Long-term precipitation and stream discharge records at seven forested experimental watersheds along a latitudinal transect in Japan: Jozankei,Kamabuchi, Takaragawa,Tsukuba, Tatsunokuchi-yama,Kahoku and Sarukawa

This data note introduces a database of long-term daily total precipitation and stream discharge data for seven forested watersheds in Japan that have been continuously monitored by the Forestry and Forest Products Research Institute. Three of the watersheds started data collection in the 1930s. Forest cover across the sites ranges from cool to warm temperate regions with the latitude spanning from 31 to 44° N and annual precipitation ranging from 1200 to 3000 mm yr⁻¹. The effects of vegetation change via clearcutting, thinning and forest fire (among other stressors) on stream discharge can be analysed from the long-term observation sites. Moreover, this multi-site dataset allows for inter- and intra-site comparisons of annual water loss (difference of annual precipitation and stream discharge). These long-term datasets can provide comprehensive insights into the effects of climate change and other stressors on forested ecosystems, not only in Japan but across a spectrum of forest types, if combined with other long-term records from other forested watersheds across the world.     

Spinifex-like textured metaperidotites from the Higo Metamorphic Rocks,Japan, a possible high-pressure dehydration product of antigorite serpentinite

Spinifex-like textured metaperidotites from the Higo Metamorphic Rocks (HMR), west-central Kyushu, Japan, may be formed by high-pressure dehydration of antigorite, and may indicate deep subduction of serpentinite reaching a pressure–temperature condition of 1.6 GPa and 740–750 °C. Three rock types have been identified based on mineral assemblage and rock texture: Type I (L) consisting of medium-grained (1–5 cm long) olivine + enstatite + chromite ±tremolite with secondary talc and anthophyllite that occurs in low-grade metamorphic rocks of the biotite zone, Type I (H) of coarse-grained (up to 10 cm long) olivine + enstatite (with clinoenstatite lamella) + chromite ±tremolite with secondary talc that occurs in high-grade metamorphic rocks of the garnet-cordierite zone, and Type II composed of Al-spinel + chlorite + olivine + apatite + ilmenite with minor sodic gedrite in the garnet-cordierite zone together with Type I (H). Olivines in all rock types are mostly serpentinized during exhumation. The chromite-olivine thermometer gives 560–690 °C for Type I (L) rocks, and the spinel-olivine thermometer gives 610–740 °C for Type II rocks. The peak metamorphic pressure will be higher than 1.6 GPa based on the location of the experimentally determined invariant point (P = 1.6 GPa and T = 670 °C) of antigorite + forsterite + enstatite + talc + H₂O. This estimate is consistent with the occurrence of chlorite in Type II rocks, which is stable up to 890 °C at 2.0 GPa. The spinifex-like textured metaperidotites occur as small bodies in the low P/T type gneisses, implying tectonic juxtaposition of them probably during exhumation of the HMR. Recent findings of medium pressure (0.9–1.2 GPa) granulites and gneisses from the HMR may indicate that the HMR has a deep root into the wedge mantle from which the spinifex-like textured metaperidotites have derived.     

Investigation of local time dependence of Mercury's sodium exosphere based on a numerical simulation

Mercury has a surface-bounded exosphere (SBE) similar to that of the Moon. One of the atmospheric species, sodium, was found by ground-based observations to be the most prominent component. Mercury's sodium SBE is known to be non-uniform with respect to local time (LT) in low-latitude regions: the sodium column density in the dawn-side region is larger than that in the dusk-side region, and the sodium abundance is the largest in the morning-noon region. To reveal the production processes for the exosphere near Mercury's surface, the LT dependence of the exosphere was investigated through a numerical simulation. Three data sets of sodium column densities observed for the dawn-side hemisphere, observed by Sprague et al. [1997. Distribution and abundance of sodium in Mercury's atmosphere, 1985-1988. Icarus 12, 506-527], were compared with results simulated by a 3D Monte Carlo method, and the source rates and density of sodium of the planetary surface were estimated. In the simulation, the photon-stimulated desorption (PSD) and thermal desorption (TD) processes were assumed as the release mechanisms. The sodium source rates for the three data sets, at respective heliocentric distances of about 0.33, 0.42, and 0.44 AU, were estimated as 1-4×10⁸ Na/cm²/s with weak LT dependence. In contrast, the expected sodium surface density showed clear dependence on LT and the heliocentric distance. The sodium surface density decreases from early morning to noon by a few orders, and, particularly for large heliocentric distances, the surface is in a condition of sodium excess and depletion with respect to the surface sodium density assumed by Killen et al. [2004. Source rates and ion recycling rates for Na and K in Mercury's atmosphere. Icarus 171, 1-19] in the early morning and morning-noon regions, respectively. This study implies that the decrease in sodium surface density from the early morning to noon regions might produce the characteristic LT dependence in the low-latitude dawn-side region.     

Molecular line mapping of the giant molecular cloud associated with RCW 106 – II. Column density and dynamical state of the clumps

We present a fully sampled C¹⁸O (1–0) map towards the southern giant molecular cloud (GMC) associated with the H  ii region RCW 106, and use it in combination with previous ¹³CO (1–0) mapping to estimate the gas column density as a function of position and velocity. We find localized regions of significant ¹³CO optical depth in the northern part of the cloud, with several of the high-opacity clouds in this region likely associated with a limb-brightened shell around the H  ii region G333.6−0.2. Optical depth corrections broaden the distribution of column densities in the cloud, yielding a lognormal distribution as predicted by simulations of turbulence. Decomposing the ¹³CO and C¹⁸O data cubes into clumps, we find relatively weak correlations between size and linewidth, and a more sensitive dependence of luminosity on size than would be predicted by a constant average column density. The clump mass spectrum has a slope near −1.7, consistent with previous studies. The most massive clumps appear to have gravitational binding energies well in excess of virial equilibrium; we discuss possible explanations, which include magnetic support and neglect of time-varying surface terms in the virial theorem. Unlike molecular clouds as a whole, the clumps within the RCW 106 GMC, while elongated, appear to show random orientations with respect to the Galactic plane.     

Origin of a unique impact-melt rock—the L-chondrite Ramsdorf

Abstract— We have studied a unique impact-melt rock, the Ramsdorf L chondrite, using optical and scanning microscopy and electron microprobe analysis. Ramsdorf contains not only clast-poor impact melt (Begemann and Wlotzka, 1969) but also a chondritic portion (>60 g) with what appears at low magnification to be a normal, well-defined chondritic texture. However, detailed studies at high magnification show that >90 vol% of the crystals in the chondritic portion were largely melted by the impact: the chondrules lack normal microtextures and are ghosts of the original features. The only relics from the precursor chondrules are olivine crystals, which have the highest melting temperature (～1620 °C). Pyroxene-rich chondrules were so extensively melted that no phenocrysts were preserved and the melt crystallized in situ before significant mixing with exterior olivine-rich melts. Fine-grained pyroxene chondrule ghosts have sharper boundaries with the matrix than porphyritic olivine and pyroxene chondrule ghosts, probably because pyroxene-rich melts are significantly more viscous. Complex textures that formed by injection of melt along cracks and fractures in relic olivines suggest that the chondritic portion of Ramsdorf formed directly from petrologic type 3–4 material by strong shock. We infer that Ramsdorf was largely melted by shock pressures of ～75–90 GPa and that chondrule ghosts and relic olivine phenocrysts were locally preserved by rapid cooling. Quenching was not due to the addition of cold clasts into the melt but to heterogeneous shock heating that only caused internal melting of large olivines and pyroxenes. Ramsdorf appears to be one of the most heavily shocked meteorites that has retained some trace of its original texture.     

Calibration and validation of the ocean color version-3 product from ADEOS OCTS

We present calibration and validation results of the OCTS’s ocean color version-3 product, which mainly consists of the chlorophyll-a concentration (Chl-a) and the normalized water-leaving radiance (_nL_w). First, OCTS was calibrated for the inter-detector sensitivity difference, offset, and absolute sensitivity using external calibration source. It was also vicariously calibrated using in-situ measurements for water (Chl-a and_nL_w) and atmosphere (optical thickness), which were acquired synchronously with OCTS under cloud-free conditions. Second, the product was validated using selected 17 in-situ Chl-a and 11 in-situ_nL_w measurements. We confirmed that Chl-a was estimated with an accuracy of 68% for Chl-a less than 2 mg/m³, and_nL_w from 94% (band 2) to 128% (band 4). Geometric accuracy was improved to 1.3 km. Stripes were significantly reduced by modifying the detector normalization factor as a function of input radiance.