Formation of water masses and fronts due to density-induced current system

Several numerical experiments were carried out on the formation of water masses and their fronts such as observed in the Kii Channel in winter. Such water masses and fronts may caused by density-induced current system. The phenomenon is assumed to take place in the vertical two-dimensional plane not involving the effect of the earth's rotation. The linear momentum equation and the diffusion-advection equations of salinity and temperature are integrated with respect to time under a vertically hydrostatic condition. The result is that two rolls which correspond to the onshore water mass and the offshore water mass are formed with an accompanying front between them. The apparent diffusion coefficient reaches a relatively great amount inside the water masses and drops down to the eddy diffusivity level at the front. The dependence of the synoptic distributions of the temperature and salinity on several parameters is also examined. Finally another experiment is carried out involving the effect of the earth's rotation, which results in a rather different distribution pattern from that of the non-rotating model.     

The roughness height and drag law over the water surface based on the hypothesis of local equilibrium

A series of measurements of winds and wind-waves were carried out in wind-wave flumes. A data analysis based on the hypothesis of local equilibrium yielded a new empirical formula on the controversial quantity of roughness heightz ₀ over the water surface: , where the nondimensional roughness height is defined bygz ₀/u _* ² and the wave-wind parameterũ byω _p u _*/g, g being the gravitational acceleration,u _* the friction velocity of air,ω _p the peak frequency of wind-wave spectra. The obtained formula is compared with Charnock's (1955) and Toba's (1979) proposals; is constant in the former and inversely proportional toũ in the latter. As in Toba's, this formula immediately leads to a practically important conclusion that the drag coefficientC _d depends not merely on the usual variableU ₁₀ (wind velocity at 10m height over the water surface), but also on the surface state represented by wind-waves. An explicit expression is provided for the drag coefficient incorporating the wave-wind parameter; it covers the range ofC _d calculated from most of the previous drag formulas, by varying the wave-wind parameter.     

Influence of Salinity on pH and Aluminum Concentration on the Interaction of Acidic Red Soil with Seawater

Contamination of acidic red soil in the coastal areas of Okinawa Islands is a serious environmental problem. This study was conducted to examine the effects of the salinity on pH and aluminum concentration when the acidic red soil interacts with seawater. Acidic red soil from Gushikawa recreation center was fractionated into bulk soil, coarse sand and silt + clay. Different weights of each fraction were equilibrated with seawater solutions. The pH and concentrations of Al³⁺, Na⁺, K⁺, Ca²⁺ and Mg²⁺ were then analyzed in the extracts. The results showed a decreasing trend of pH with increasing soil to solution ratio while the extracted Al³⁺ revealed an increasing trend. The lowest pH values were 3.85, 4.06, 4.41, 4.66 and their corresponding highest Al³⁺ concentrations were 2.50, 1.01, 0.062 and 0.036 mmolL⁻¹ in the seawater extracts, one-tenth seawater extracts, one-hundredth seawater extracts and one-thousandth seawater solution extracts, respectively. Mostly, the concentrations of Na⁺, Ca²⁺, Mg²⁺ and especially K⁺ decreased with increasing soil weight in the high salinities but showed the opposite trend in the low salinity samples. Potassium concentration decreased by 39%, 53% and 40% in the seawater extracts, one-tenth and one-hundredth seawater extracts but increased by 200% in one-thousandth seawater extracts. The coincidence of the increase in Al³⁺ and H⁺ concentrations, and the decrease of Na⁺, K⁺, Ca²⁺ and Mg²⁺ concentrations in the solutions suggests ion exchange/adsorption, while the increased patterns, particularly at low salinity could be attributed to the dissolution of the species from the soils.     

Wind-wave spectra based on the hypothesis of local equilibrium

Wind-wave spectra measured in a wind-flume are analyzed according to the hypothesis of local equilibrium. The gross relation between the wave height and the frequency is reexamined to yield the basic validity of the 3/2-power law of Toba orE～? in the range of 0.4≦?≦1, where? is the wave-wind parameter defined by?=ω _p u _*/g; ω _p denotes the peak frequency of the wind-wave spectra,u _* the friction velocity andg the gravitational acceleration. Noticeable deviation is found, however, for?<0.4 or?>1. In particular, the data for large? suggest the existence of an upper limit of the wave nonlinearityE at about 5×10^?2, whereE=Eω _p ⁴ /g² withE the total power of the wind wave spectrum. Then, the spectral form is investigated in detail. As? decreases, the normalized spectrum becomes more gradual as a whole, but its forward (low frequency) part tends to show a steeper profile. In the high frequency region ( \(\tilde \omega \) >2.6), the spectrum is found to have a functional form likeu _* ² ω ^?3, which differs from the usualω-dependence asω ^?5 orω ^?4. It suggests weak dependence of the high-frequency spectra on the gravitational accelerationg and on the peak frequencyω _p ; spectral density at high frequencies may be saturated, so that its magnitude may be dominated by the frequencyω, the friction velocityu _*, the surface tension and the viscosity.     

Rates of net assimilation and respiration of amino acids by marine bacteria

The selectivity of amino acid assimilation by marine bacteria was examined using seven kinds of¹⁴C-amino acids and the acid hydrolysate of¹⁴C-labelled proteins. It was found that the net assimilation and respiration by marine bacteria followed MICHAELIS-MENTEN kinetics for all of amino acids used in our experiments. Maximum velocities of amino acids were 0.01 to 0.19g carbon/hour per 2×10⁷ cells for net assimilation and less than 0.18g carbon/hour per 2×10⁷ cells for respiration at 20C. The velocity of gross assimilation was found with the following order: phenylalanine>valine, glutamic acid>serine, arginine>tryptophan>glycine. The assimilation velocities of amino acids in these laboratory works showed almost the same order as those in field experiments. The assimilation velocity of an amino acid was influenced by coexisting another amino acids or glucose. The assimilation velocity in lower substrate range of amino acids was directly proportional to the number of bacterial cells in the range from 6×10² to 3×10⁴ cells per ml. No linear relation between the assimilation velocity of amino acids and reciprocal of absolute temperature was found, but a marked bending was observed at 15 to 20C. The velocity at the optimum temperature was three to six times of that at 5C.     

Simultaneous Measurement of Hydrogen Peroxide and Fe Species (Fe(II) and Fe<Subscript>(tot)</Subscript>) in Okinawa Island Seawater: Impacts of Red Soil Pollution

The northern part of Okinawa Island suffers from red soil pollution—runoff of red soil into coastal seawater—which damages coastal ecosystems and scenery. To elucidate the impacts of red soil pollution on the oxidizing power of seawater, hydrogen peroxide (HOOH) and iron species including Fe(II) and total iron (Fe_(tot), defined as the sum of Fe(II) and Fe(III)) were measured simultaneously in seawater from Taira Bay (red-soil-polluted sea) and Sesoko Island (unpolluted sea), off the northern part of Okinawa Island, Japan. We performed simultaneous measurements of HOOH and Fe(II) because the reaction between HOOH and Fe(II) forms hydroxyl radical (•OH), the most potent environmental oxidant. Gas-phase HOOH concentrations were also measured to better understand the sources of HOOH in seawater. Both HOOH and Fe(II) in seawater showed a clear diurnal variation, i.e. higher in the daytime and lower at night, while Fe_(tot) concentrations were relatively constant throughout the sampling period. Fe(II) and Fe_(tot) concentrations were approximately 58% and 19% higher in red-soil-polluted seawater than in unpolluted seawater. Gas-phase HOOH and seawater HOOH concentrations were comparable at both sampling sites, ranging from 1.4 to 5.4 ppbv in air and 30 to 160 nM in seawater. Since Fe(II) concentrations were higher in red-soil-polluted seawater while concentrations of HOOH were similar, •OH would form faster in red-soil-polluted seawater than in unpolluted seawater. Since the major scavenger of •OH, Br⁻, is expected to have similar concentrations at both sites, red-soil-polluted seawater is expected to have higher steady-state •OH concentrations.     

Standing Crops of Planktonic Ciliates and Copepod Nauplii in the Subarctic North Pacific and the Bering Sea in Summer

Abundances and biomasses of planktonic ciliates and copepod nauplii, major components of the microzooplankton community, were investigated in the subarctic North Pacific and the Bering Sea in summer of 1997. Their regional variation was illustrated by demarcating the entire area into five regions. Ciliates always predominated both in abundance (>94%) and biomass (>78%) over nauplii. Regional means of ciliates in the water column were higher in the Alaskan Gyre (120 × 10⁶ cells/m²) and the Western Subarctic Gyre (110 × 10⁶ cells/m²) in terms of abundance, and rich in the Bering Sea Gyre (360 mgC/m²) and the Western Subarctic Gyre (340 mgC/m²) in terms of biomass. By contrast, standing crops of ciliates were poor in the Oyashio Region (67 × 10⁶ cells/m²; 170 mgC/m²) and the Transition Region (64 × 10⁶ cells/m²; 160 mgC/m²). The values of biomass reported here are generally in agreement with the values reported previously from the Bering Sea Gyre and the Alaskan Gyre but are considerably higher than the previous value found in the Western Subarctic Gyre. No significant correlations could be found between chlorophyll a crop and standing crops of ciliates and copepod nauplii over the entire subarctic North Pacific and the Bering Sea during this summer.     

Determination of cadmium,lead and copper in interstitial water by anodic stripping voltammetry

This paper gives the results of determination of cadmium, lead and copper in interstitial water of the coastal sediment, Seto Inland Sea, Japan by using anodic stripping voltammetry. An aliquot of 4–5 ml interstitial water separated from 30–70 ml of sediment is used for the simultaneous determination of ionic cadmium, lead and copper. No significant differences were observed on the content of trace metals between surface water and interstitial water of the top of the sediment.     

Sedimentation rates and heavy metal pollution of sediments in the Seto Inland Sea

In the Hiuchi-Nada area of the Seto Inland Sea, Japan, sedimentation rates were determined with the Pb-210 technique, and heavy metals in sediments were also analyzed. Sediments were collected in twelve short sediment cores and a long sediment core, using 1-m and 6-m gravity corers.The sedimentation rates vary from 0.14 to 0.31 g cm^–2yr^–1. The highest sedimentation rate was observed in the central part of the area, while lower sedimentation rates were observed in the eastern part.In Hiuchi-Nada, a remarkable increase in copper and zinc contents is noticeable as early as the 1800's. Over the past 240 years a copper smelter at the south-western side of this area has been causing serious pollution of the sediment. Now, anthropogenic copper and zinc loads into the sediment are 123 and 376 ton yr^–1 compared to natural copper and zinc loads of 82 and 401 ton yr^–1, respectively. The highest level of copper and zinc pollution was observed in the 1960's, when the relative enrichments above background values (copper; 19 and zinc; 93 mg kg^–1) were 5.5 and 2.8, respectively.