Isotopic evidence for temporal variation in proportion of seasonal precipitation since the last glacial time in the inland Pacific Northwest of the USA

Large-scale atmospheric circulation patterns determine the quantity and seasonality of precipitation, the major source of water in most terrestrial ecosystems. Oxygen isotope (δ¹⁸O) dynamics of the present-day hydrologic system in the Palouse region of the northwestern U.S.A. indicate a seasonal correlation between the δ¹⁸O values of precipitation and temperature, but no seasonal trends of δ¹⁸O records in soil water and shallow groundwater. Their isotope values are close to those of winter precipitation because the Palouse receives  75% of its precipitation during winter. Palouse Loess deposits contain late Pleistocene pedogenic carbonate having ca. 2 to 3‰ higher δ¹⁸O values and up to 5‰ higher carbon isotope (δ¹³C) values than Holocene and modern carbonates. The late Pleistocene δ¹⁸O values are best explained by a decrease in isotopically light winter precipitation relative to the modern winter-dominated infiltration. The δ¹³C values are attributed to a proportional increase of atmospheric CO₂ in soil CO₂ due to a decrease in soil respiration rate and ¹³C discrimination in plants under much drier paleoclimate conditions than today. The regional climate difference was likely related to anticyclonic circulation over the Pleistocene Laurentide and Ice Sheet.     

Colonization of Sulfurovum sp. on the gill surfaces of Alvinocaris longirostris, a deep-sea hydrothermal vent shrimp

Deep‐sea hydrothermal vents are unique light‐independent ecosystems that are sustained by chemosynthetic bacteria. For many of the invertebrates inhabiting in such environments, bacteria play essential roles in both energy acquisition and detoxification of potentially toxic gases such as H₂S. In this study, the bacterial flora present on the gills of Alvinocaris longirostris (Bresiliidae: Caridea), a shrimp inhabiting hydrothermal vents (1532 m depth) at the Hatoma Knoll of the Okinawa Trough, was investigated. Bacterial 16S rDNA fragments were successfully amplified from the gills and 70% of these fragments showed an identical pattern in the restriction fragment length polymorphism analysis. These fragments were assigned to the ribotype AL‐1. Phylogenetic analyses suggest that AL‐1 forms a monophyletic clade with Sulfurovum spp. (ε‐Proteobacteria). Fluorescence in situ hybridization for AL‐1 and electron microscopy showed the presence of short‐rod bacteria lining up on the cuticular layer of the surface of the gill filaments. These results suggest that bacterial association with gills also occurs in bresiliid shrimps.     

Sonophotocatalysis of endocrine-disrupting chemicals

Sonolysis and photolysis often exhibit synergistic effects in the degradation of organic molecules. An assay of fish oocyte maturation provides an appropriate experimental system to investigate the hormonal activities of chemical agents. Oocyte maturation in fish is triggered by maturation-inducing hormone (MIH), which acts on receptors on the oocyte surface. A synthetic estrogen, diethylstilbestrol (DES), possesses inducing activity of fish oocyte maturation, and a widely used biocide, pentachlorophenol (PCP), exhibits a potent inhibitory effect on fish oocyte maturation. In this study, the effects of the combined treatment by sonolysis with photolysis (sonophotocatalysis) to diminish the hormonal activity of DES and the maturation preventing activity of PCP was examined. By sonophotocatalysis, hormonal activity of DES was completely lost within 30min and the inhibiting activity of PCP was lost within 120min. These results demonstrated that sonophotocatalysis is effective for diminishing the endocrine-disrupting activity of chemical agents.     

A simple two-way coupling method of BEM and VOF model for random wave calculations

A numerical method, which combines the boundary element method (BEM) and the volume of the fluid method (VOF method), has been presented to solve wave–structure interactions; the intense wave motion at the proximity of the structure is modeled by the VOF method and the rest of the fluid region is modeled by the BEM. The combined method can considerably reduce the time-consuming VOF domain, and thus practically makes it possible to apply the VOF method for random wave calculations, in which long time computations are usually required to obtain statistically meaningful results, and therefore the use of the single-VOF model often becomes prohibitive in terms of computational time and storage memories. A VOF model CADMAS-SURF, which is based on SMAC scheme and had been constructed by a number of VOF researchers in coastal engineering in Japan, is used in the combined BEM–VOF model. The two-way coupling treatment, which enables us to deal with bidirectional wave propagations, which was originally given for the SOLA-VOF model by Yan et al. (2003a) and later improved by Kim et al. (2007), was modified for the SMAC scheme. The coupling treatments are described in detail in the paper. The validity of the combined BEM–VOF model was investigated by comparing the numerical results with the theoretical results for the propagations of Stokes 5th order waves and random waves.     

Geotechnical Characteristics of Volcanic Soils Taken from Recent Eruptions

Recent volcanic eruptions at Mt. Unzen (Japan) in 1990 and Mt. Pinatubo (Philippines) in 1991 produced voluminous amounts of ash and sediments which inundated widespread areas. In later rehabilitation and reconstruction, it is practical and economical to use these freshly deposited sediments as materials for foundations and embankments. However, the geotechnical properties of young volcanic products have not been fully investigated. Accordingly, we investigated the geotechnical characteristics of volcanic soils associated with three recent eruptions, namely, the Unzen and Izu-Oshima eruptions of 1990 and 1986, respectively, in Japan and the Pinatubo eruption of 1991 in the Philippines. We specifically investigated index properties, permeability and compaction characteristics, and strength and deformation behavior in drained conditions. Additionally, we examined the dynamic properties and liquefaction characteristics of samples taken from Mt. Pinatubo. The results showed that the geotechnical characteristics of the deposits generally varied with the sampling sites. Depending on the location, either upstream or downstream from a volcano, the preferential sizing due to alluvial deposition affects engineering properties of the deposits. For example, volcanic sediments upstream from Mt. Pinatubo have high compressibility and low cyclic strength, whereas those taken downstream show dilative tendencies and high liquefaction strength.     

Localization of VLF ionospheric exit point by comparison of multipoint ground-based observation with full-wave analysis

In order to estimate the dynamic structure of the VLF ionospheric exit point, we conducted multipoint ground-based observation of the natural VLF emissions at three unmanned sites: West Ongul (69°01′ S, 39°30′ E), Skallen (69°40′ S, 39°24′ E), and H100 (69°18′ S, 41°19′ E) around Japanese Syowa station, Antarctica, during a whole year of 2006. In this observation, we developed three sets of unmanned autonomous observation systems for natural VLF emissions. Each observation system consists of two crossed vertical loop antennas to pick-up North–South (NS) and East–West (EW) magnetic components, a multi-channel analyzer, and a data logger. The intensity and polarization of NS and EW magnetic components are obtained in 4 spaced frequency (0.5, 1.0, 2.0, and 6.0 kHz) channels by the multi-channel analyzer.The VLF emissions observed at the three sites exhibit an interesting difference in the wave intensity as well as the polarization that allows important information about the locations of their ionospheric exit point to be determined. Firstly, to find the distinct exit point, we have theoretically calculated the spatial distributions of the wave intensity and the polarization on the Earth for VLF whistler mode waves coming down from the magnetized ionosphere, by using the full-wave analysis. Then, we have compared the calculated results with the observed data, to evaluate the possible locations of the ionospheric exit point for the auroral hiss events.As an example, the direction of the estimated ionospheric exit point for the auroral hiss event at 31 March 2006 was found to be consistent with a bright aurora region. However, in this case, the estimated ionospheric exit point was located a few hundred kilometers equatorward of the associated aurora. This would suggest that the ray paths for the auroral hiss could be different from the directions of the geomagnetic field lines for auroral precipitation.     

The Uptake Coefficient of I2 on Various Aqueous Surfaces

Uptake coefficient of I₂ on aqueous surfaces was measured by using an impinging flow method. Dependence of the uptake coefficient on the gas-liquid contact time and pH was investigated. The uptake coefficient was (3.7± 2.0)×10^–4 at 120 ms, 293 K and pH = 5.6. In the alkaline region, the uptake coefficient was larger by one order of magnitude than that in the neutral and acidic region. The I₂ uptake on KI solutions and synthetic sea water solutions was also measured. According to the analysis by the reactive uptake model, the uptake of I₂ was shown to be mainly determined by liquid phase reactions and the accommodation coefficient of I₂ on aqueous surfaces was estimated to be 0.01.     

Electromagnetic anomalies associated with 1995 Kobe earthquake

Occurrences of anomalous electro-magnetic phenomena at varied frequency ranges, covering ELF to VHF, have been reported in relation to the 17 January 1995 Kobe earthquake (M7.2), by several independent research groups. Prominent pre-seismic peaks, which could have been emitted from the focal area, were observed on 9-10 January in ELF, VLF, LF and HF ranges. Whether these changes were truly related to the earthquake is not certain, because atmospheric (thunderbolt discharge) activities also peaked on 9-10 January. The nomalous changes were markedly enhanced toward the catastrophe in agreement with many reports on unusual radio/TV noise. Anomalous transmission of man-made electromagnetic waves in VLF and VHF ranges was also detected from a few days before the earthquake, indicating the possibility that the ionosphere above the focal zone was disturbed at the final stage of the earthquake preparation process.     

Phase transition of potassium sulfate,K2SO4 (II); dielectric constant and electrical conductivity

The phase transition of K₂SO₄ has been investigated by measurements of the dielectric constant and electrical conductivity, correlated with the structural point of view. Using single crystals, the temperature dependences of the dielectric constants and electrical conductivities were measured at frequencies of 0.3, 1, 3, and 5 MHz in the temperature range from 20° to 640 °C. Within this range, the dielectric constant does not reach a maximum, but near the phase-transition temperature at 587° C, the dielectric constant along the c axis shows a larger discontinuity than those along the a and b axes. The temperature dependence of the dielectric constant is consistent with the disordered structure of the high temperature form. Based on the parabolic increase of the dielectric constant in the temperature range from 582° to 587° C, it is likely that the phase transition propagates through an intermediate state. The electrical conductivity coefficients of K₂SO₄ increase with increasing temperature, exhibiting semiconducting character above the phase-transition temperature. In the high-temperature form, the electrical conductivity along the a axis exceeds that along the c axis. Since the electrical conductivity of K₂SO₄ is mainly ionic in character, the migration of K⁺ ions makes a major contribution to the conduction process.     

Paleolimnological investigation of recent acidity changes in Sawanoike Pond, Kyoto, Japan

Sawanoike Pond, an artificial reservoir constructed ca. 150 yrs. ago, lies in an area geologically sensitive to acidification and contains water that is presently weakly acidic (pH 5.5; alkalinity 15 eq 1^-1). Sediments from a core obtained from the northern part and a core from the central part of the pond were analyzed for organic matter, total organic carbon, total nitrogen, natural and artificial radionuclides, pollen, diatoms, metals and spheroidal carbonaceous particles. A peaty silt layer at the bottom of the central core was replaced by a silt layer initially rich in humic substances, but became more mineral-rich near the surface. Although most of the dominant diatoms throughout the cores were acidophilous taxa, some acidobiontic species increased moderately in abundance after the middle 1960's. Diatom-inferred pH values for the northern core are relatively low before about 1930, then increase, reaching a maximum level between the 1930's and the late 1940's. They then decrease to the surface and reach minimum level during the middle 1980's. Diatom-inferred pH declined by 0.4-0.5 units in the northern core and 0.2-0.3 units in the central core since ca. 1910, when vegetation around the shore changed to a community similar to that of recent years. An increase in labile Pb, Zn, Cd and spheroidal carbonaceous particles, indicative of atmospheric deposition of fossil fuel combustion by-products, preceded the decline in inferred pH. The inferred pH decline of the pond could be an acidification due to acidic precipitation caused by fossil fuel combustion.