The spatial and temporal distributions of spheroidal carbonaceous particles from sediment core samples from industrial cities in Japan and China

Spheroidal carbonaceous particles (SCPs) are produced by the high-temperature combustion of fossil fuels and emitted in to the atmosphere. The distribution and concentration of SCPs in sediments have been used as a proxy for the distribution of pollutants emitted to the atmosphere. However, the effect on the distribution of SCPs due to industrial activity at nearby industrial cities is yet to be quantified. To clarify the origin of SCPs of ~20 μm in size that are preserved in sediments, we evaluated the abundance, surface morphology, and chemical composition of SCPs in sediment core samples recovered from industrial cities in Japan (Tokyo, Osaka, and Nagasaki) and China (Beijing), with the cities being located at least ~500 km away from each other. Vertical profiles of SCP concentration in sediment cores from the Japanese cities and Beijing are different, reflecting the contrasting industrial histories of the two countries. The SCPs from different cities show contrasting morphological and chemical characteristics, suggesting that ~20 μm SCPs in sediments from the industrial cities could represent the local combustion history in detail, as the influx of local SCPs is dominant at such sites.     

Spectroscopic properties of Cr-doped and Cr,Li-doped synthetic forsterite crystals

Cr-droped and Cr,Li-doped forsterite crystals were grown and their optical properties were investigated. It was shown that when only Cr is doped, Cr³⁺ is substituted at the site of low crystal field, and the energy level ²E lie above the ⁴T₂ level, while ⁴T₂ is just above ²E when Cr and Li are codoped. The difference was rationalized by a deformation of the Cr substituted site with the introduction of Li.     

Evidence for a thick and localized ultra low shear velocity zone at the base of the mantle beneath the central Pacific

Prominent postcursors to S/Sdiff waves with delays as large as 26 s are observed in Northern America for Papua New Guinea events. These waves sample the northern side of the Pacific large low shear velocity province revealed by global shear velocity (Vs) tomographic models. The emergence of the postcursors strongly depends on the epicenter-to-station azimuth, indicating that the waveforms are, in general, strongly affected by 3-dimensional (3D) heterogeneities. We limit our focus to an azimuthal range around 60°, measured clockwise from north at the epicenter, where the records show a relatively small azimuthal variation, suggesting a relatively small 3D effect there. In this azimuthal range we attempt 2D structural modelling along the great circle plane towards stations in southern US. First, we use a 2D ray theory to search for a range of models, which generate a postcursor to the main Sdiff phase with a delay time consistent with the observations. Then, for some typical models, we calculated waveforms at periods down to 5 s using the spectral element method. We obtained several models that provide synthetic waveforms in a fair agreement with the observations. The result shows that two types of low Vs regions are required to explain the data. One is a broad and weak anomaly region with a Vs reduction of 5% or so, constituting a part of the Pacific large low shear velocity province at the base of the mantle. The other is a laterally localized strong anomaly region with a more than 25% reduction of Vs within a thickness of at least 80 km and a width on the order of 500 km.     

Distribution of fault rocks in the fracture zone of the Nojima Fault at a depth of 1140 m: Observations from the Hirabayashi NIED drill core

Abstract Characteristics of deformation and alteration of the 1140 m deep fracture zone of the Nojima Fault are described based on mesoscopic (to the naked eye) and microscopic (by both optical and scanning electron microscopes) observations of the Hirabayashi National Research Institute for Earth Science and Disaster Prevention (NIED) drill core. Three types of fault rocks; that is, fault breccia, fault gouge and cataclasite, appear in the central part of the fault zone and two types of weakly deformed and/or altered rocks; that is, weakly deformed and altered granodiorite and altered granodiorite, are located in the outside of the central part of the fault zone (damaged zone). Cataclasite appears occasionally in the damaged zone. Six distinct, thin foliated fault gouge zones, which dip to the south-east, appear clearly in the very central part of the fracture zone. Slickenlines plunging to the north-east are observed on the surface of the newest gouge. Based on the observations of XZ thin sections, these slickenlines and the newest gouge have the same kinematics as the 1995 Hyogo-ken Nanbu earthquake (Kobe earthquake), which was dextral-reverse slip. Scanning electron microscopy observations of the freeze-dried fault gouge show that a large amount of void space is maintained locally, which might play an important role as a path for fluid migration and the existence of either heterogeneity of pore fluid pressure or strain localization.     

Laboratory Study of the Bidirectional Reflectance of Powdered Surfaces: On the Asymmetry Parameter of Asteroid Photometric Data

We performed laboratory experiments on the bidirectional reflectance of powdered surfaces of dunite, graphite, and Allende (CV3) and Gao (H5) meteorites. The particle size of each sample varied from tens to hundreds of micrometers. The absolute bidirectional reflectance was determined for two ranges of phase angle: from 2° to 80° at 0° angle of incidence and from 2° to 155° at 75° angle of incidence. The phase angle was incremented every 1° in between 2° and 5° and every 10° between 10° and 150°. We determined the Hapke parameters and found that the values of the asymmetry parameter retrieved for most of the samples were positive when the coverage of the phase angle was wide, 2° to 155°, although the values derived from remote sensing instruments on asteroid flyby missions have been negative or nearly zero. Among our sample surfaces, only those of graphite, Allende, and Gao with particle sizes of hundreds micrometers show negative or nearly zero values. The single-scattering albedos determined for the Gao samples are comparable to the values of S-class asteroids, while those for the Allende samples are much larger than those of C-class asteroids.     

Crustal thermal regime inferred from magnetic anomaly data and its relationship to seismogenic layer thickness: The Japanese islands case study

The seismogenic layer thickness correlates with surface heat flow beneath the Japanese islands. However, this correlation is shown at restricted area, where seismic activity is high. In order to overcome this spatial limitation, we used another approach to estimate the regional thermal structure in the crust beneath the Japanese islands with more uniform coverage. The bottom depths of the magnetized crust determined from the spectral analysis of residual magnetic anomalies is generally interpreted as the level of the Curie point isotherm. We applied this method to estimate the crustal thermal structure in square windows of 2.125° × 2.125°. The obtained depths ranging from 11 to 30 km with average value of 18 km, correlate with the seismogenic layer thickness. It suggests that the Curie point depth is a useful indicator of the crustal thermal structure in these regions.     

Thermal maturity of a fold–thrust belt based on vitrinite reflectance analysis in the Western Foothills complex, western Taiwan

Burial depth, cumulative displacement, and peak temperature of frictional heat of a fault system are estimated by thermal analysis in the fold–thrust belt of the Western Foothills complex, western Taiwan based on the vitrinite reflectance technique. The regional thermal structure across the complex reveals that the rocks were exposed to maximum temperatures ranging from 100 °C to 180 °C, which corresponds to a burial depth of 3.7–6.7 km. A large thermal difference of 90 °C were observed at the Shuilikeng fault which make the eastern boundary of the fold–thrust belt where it is in contact with metamorphic rock of Hsuehshan Range. The large thermal difference corresponds to cumulative displacements on the Shuilikeng fault estimated to be in the range of 5.2–6.9 km. However, thermal differences in across the Shuangtung and Chelungpu faults cannot be determined apparently due to small vertical offsets. The large displacement observed across the Shuilikeng fault is absent at the other faults which are interpreted to be younger faults within the piggyback thrust system. Localized high temperatures adjacent to fault zones were observed in core samples penetrating the Chelungpu fault. Three major fracture zones were observed at core lengths of 225 m, 330 m, and 405 m and the two lower zones which comprise dark gray narrow shear zones. A value of vitrinite reflectance of 1.8%, higher than the background value of 0.8%, is limited at a narrow shear zone of 1 cm thickness at the fracture zone at 330 m. The estimated peak temperature in the range of 550–680 °C in the shear zone is far higher than the background temperature of 130 °C, and it is interpreted as due to frictional heating during seismic faulting.     

Pseudosection analysis for talc-Na pyroxene-bearing piemontite-quartz schist in the Sanbagawa Belt, Japan

Abstract Various modes of occurrence of talc were identified in piemontite‐quartz schists collected from schist and eclogite units in the Kotsu area of the Sanbagawa Belt, eastern Shikoku, Japan. They can be classified into the following types: (A) matrix and (B) pull‐apart talc. The matrix talc is associated with aegirineaugite or glaucophane in the eclogite unit and with albite or chlorite in the schist unit. The pull‐apart talc is developed at the pull‐apart of microboudin structures of Na‐amphibole, along with albite or chlorite in samples from both units, suggesting that the pull‐apart talc was formed by Na‐amphibole consuming reactions in both units. The talc–aegirineaugite–phengite association is found in a thin layer (a few millimetres thick), with higher Na₂O/(Na₂O + Al₂O₃ + MgO) ratio in the ANM (Al₂O₃–Na₂O–MgO) diagram projected from phengite, epidote and other minerals, in the eclogite unit. Crystals of aegirineaugite have decreased jadeite content [= 100 × Al/(Na + Ca)] and increased aegirine content [= 100 × (Na – Al)/(Na + Ca)] from the core (ca Jd₄₀Aeg₄₀Di₂₀) to the rim (ca Jd₂₃Aeg₅₃Di₂₄), and are replaced by winchite and albite in varying degrees at the crystal margins. Na‐amphibole is glaucophane/crossite, commonly rimmed by Al‐poor crossite or winchite at the margin in the eclogite unit, although it is relatively homogeneous crossite in the schist unit. These textures suggest that the talc‐phengite‐(aegirineaugite or glaucophane) assemblage equilibrated during an early stage of metamorphism and the pull‐apart talc was formed at a later stage in the eclogite unit. A plausible petrogenetic grid in the NCKFe³⁺MASH system with excess piemontite (regarded as epidote), hematite, quartz and water, pseudosection analysis for the aegirineaugite‐bearing layer and the observed mineral assemblages suggest that the talc‐aegirineaugite‐phengite assemblage is stable under high pressure conditions (ca 560–580°C and 18–20 kbar). The pull‐apart talc was formed at ca 565–580°C and 9.5–10.5 kbar by the reaction of glaucophane/crossite + paragonite = talc + albite during the decompression stage, suggesting that the piemontite‐quartz schist in the eclogite unit experienced high‐pressure metamorphism at ca 50–60 km depth and was then exhumed to ca 30 km depth under nearly adiabatic conditions.     

40Ar/39Ar ages and zircon petrochronology for the rear arc of the Izu-Bonin-Marianas intra-oceanic subduction zone

Long-lived intra-oceanic arcs of Izu-Bonin-Marianas (IBM)-type are built on thick, granodioritic crust formed in the absence of pre-existing continental crust. International Ocean Discovery Program Expedition 350, Site U1437, explored the IBM rear arc to better understand continental crust formation in arcs. Detailed petrochronological (U–Pb geochronology combined with trace elements, oxygen and hafnium isotopes) characterizations of zircon from Site U1437 were carried out, taking care to exclude potential contaminants by (1) comparison of zircon ages with ship-board palaeomagnetic and biostratigraphic ages and ⁴⁰Ar/³⁹Ar geochronology, (2) analysing zircon from drill muds for comparison, (3) selectively carrying out in situ analysis in petrographic thin sections, and (4) minimizing potential laboratory contamination through using pristine equipment during mineral separation. The youngest zircon ages in Site U1437 are consistent with ⁴⁰Ar/³⁹Ar and shipboard ages to a depth of ~1390 m below sea floor (mbsf) where Igneous Unit Ig 1 yielded an ⁴⁰Ar/³⁹Ar age of 12.9 ± 0.3 Ma (all errors 2σ). One single zircon (age 15.4 ± 1.0 Ma) was recovered from the deepest lithostratigraphic unit drilled, Unit VII (1459.80–1806.5 mbsf). Site U1437 zircon trace element compositions are distinct from those of oceanic and continental arc environments and differ from those generated in thick oceanic crust (Iceland-type) where low-δ¹⁸O evolved melts are produced via re-melting of hydrothermally altered mafic rocks. Ti-in-zircon model temperatures are lower than for mid-ocean ridge rocks, in agreement with low zircon saturation temperatures, suggestive of low-temperature, hydrous melt sources. Zircon oxygen (δ¹⁸O = 3.3–6.0‰) and hafnium (εHf = + 10–+16) isotopic compositions indicate asthenospheric mantle sources. Trace element and isotopic differences between zircon from Site U1437 rear-arc rocks and the Hadean detrital zircon population suggest that preserved Hadean zircon crystals were probably generated in an environment different from modern oceanic convergent margins underlain by depleted mantle.