Stable isotope-guided analysis of congener-specific PCB concentrations in a Japanese coastal food web

Organisms collected from a coastal ecosystem in Japan were analyzed for concentrations of 205 polychlorinated biphenyls (PCBs) congeners; analyses were guided by δ¹³C and δ¹⁵N measurements. The regression slopes of log PCB concentration on δ¹⁵N value are regarded as indices of biomagnification in food webs. The slope (wet weight basis) of ΣPCBs was +0.104; the slope (lipid weight basis) was close to zero. Lipid content increased from 0.06% in a primary producer to 8.32% in the highest trophic level consumer. Hence, biomagnification of ΣPCBs (wet weight basis) can be attributed to increase of lipid content through the food web. For most of the congeners, the slopes (wet weight basis) exceeded those (lipid weight basis) by ca. 0.10. Slopes increased with increasing PCB chlorination levels between chlorine numbers 1–6; slopes decreased at higher chlorination levels. This decrease is likely caused by a decrease in membrane permeability with increasing molecular weight.     

Bioconcentration and biomagnification of polybrominated diphenyl ethers (PBDEs) through lower-trophic-level coastal marine food web

Bivalves, crabs, fishes, seawater, and sediment collected from the inner part of Tokyo Bay, Japan, were measured for 20 polybrominated diphenyl ether (PBDE) and 5 polychlorinated biphenyl (PCB) congeners. To determine the trophic levels of the organisms, carbon and nitrogen stable isotope ratios (δ¹³C and δ¹⁵N) were also measured. Bioconcentration factors of PBDE and PCB congeners increased as the octanol-water partition coefficient (K_ow) rose to log K_ow = 7, above which they decreased again. Biomagnification of PCBs and several PBDE congeners (BDE47, 99, 100, 153 and 154) up the trophic ladder was confirmed by a positive correlation between their concentrations and δ¹⁵N. Other PBDE congeners showed a negative or no correlation, suggesting their biotransformation through metabolism. The more hydrophobic congeners of both PBDEs (Br = 2-6) and PCBs (Cl = 6-9) were biomagnified more. It thus appears that PBDEs are less biomagnified than PCBs.     

On Structure and Temporal Variation of the Bifurcation Current off the Kii Peninsula

The Kii Bifurcation Current is often found along the southwest coast of the Kii Peninsula, and its frequency of occurrence reaches about 70% in the period from 1988 to 1996 (Takeuchi et al., 1998a). In order to clarify the structure and short-period variability of the Kii Bifurcation Current, detailed observations were made four times on board the R/V Seisui-maru of Mie University on October 29–31, 1996, on June 24–26, 1997, October 14–16, 1997, and December 3–4, 1997. The measured horizontal structure of the Kii Bifurcation Current indicates that the eastern portion of the Current (eastward flow near Cape Shionomisaki) consists of a part of the current zone of the Kuroshio. It is shown that the current structure, including the Kii Bifurcation Current in the vicinity of Cape Shionomisaki, is stable when the Kuroshio is flowing in a stationary straight path, but that the current structure is considerably changed when small-scale eddies pass by the cape. Such short-period variation can be monitored by using the daily variation of the sea level difference between Kushimoto and Uragami. In particular, in the case of October 29–31, 1996, when an eminent small-scale eddy passed by Cape Shionomisaki, and when the Kuroshio axis tentatively moved southwards about 50 km apart from the coast, the Kii Bifurcation Current seems to have disappeared.     

Permeability measurements of natural and experimental volcanic materials with a simple permeameter: Toward an understanding of magmatic degassing processes

Permeability measurement of quenched volcanic porous materials is an important approach to understand permeability development and degassing of vesicular silicic magmas. In this study, we developed a gas permeameter to measure permeability of natural samples and experimental products. The permeameter has broad measurement ranges of pressure difference (10¹–10⁵ Pa) and gas-flow rate (10^− 9–10^− 5 m³/s). These ranges enable us to measure viscous permeability in the range of 10^− 17–10^− 9 m² for 1 centimeter-scale samples, using the Forchheimer equation, which includes the inertial effect of gas flow permeating through the samples. In addition, we improved the procedure for performing permeability measurements of mm-sized products of decompression experiments. Although a previous study reported the first permeability data for vesicular silicic glass products of decompression experiments, we found an overestimation in their permeability data due to problems in sample preparation, especially for very low permeability samples. Our improved measurements give lower permeability values than those of Takeuchi et al. (2005)(Takeuchi, S., Nakashima, S., Tomiya, A., Shinohara, H., 2005. Experimental constraints on the low gas permeability of vesicular magma during decompression. Geophys. Res. Lett., 32, L10312 doi:10.1029/2005GL022491).     

A submersible study of the western intersection of the Mid-Atlantic ridge and Kane fracture zone (WMARK)

In 1994, a joint Japanese-American dive program utilizing the worlds deepest diving active research submersible (SHINKAI 6500) was carried out at the western ridge-transform intersection (RTI) of the Mid-Atlantic Ridge and Kane transform in the central North Atlantic Ocean. A total of 15 dives were completed along with surface-ship geophysical mapping of bathymetry, magnetic and gravity fields. Dives at the RTI traced the neovolcanic zone up to, and for a short distance (2.5 km) along, the Kane transform. At the RTI, the active trace of the transform is marked by a narrow valley (<50 m wide) that separates the recent lavas of the neovolcanic zone from the south wall of the transform. The south wall of the transform at the western RTI consists of a diabase section near its base between 5000 and 4600 m depth overlain by basaltic lavas, with no evidence of gabbro or deeper crustal rocks. The south wall is undergoing normal faulting with considerable strike-slip component. The lavas of the neovolcanic zone at the RTI are highly magnetized (17 A m^–1) compared to the lavas of the south wall (4 A m^–1), consistent with their age difference. The trace of the active transform changes eastwards into a prominent median ridge, which is composed of heavily sedimented and highly serpentinized peridotites. Submersible observations made from SHINKAI find that the western RTI of the Kane transform has a very different seafloor morphology and lithology compared to the eastern RTI. Large rounded massifs exposing lower crustal rocks are found on the inside corner of the eastern RTI whereas volcanic ridge and valley terrain with hooked ridges are found on the outside corner of the eastern RTI. The western RTI is much less asymmetric with both inside and outside corner crust showing a preponderance of volcanic terrain. The dominance of low-angle detachment faulting at the eastern RTI has resulted in a seafloor morphology and architecture that is diagnostic of the process whereas crust formed at the WMARK RTI must clearly be operating under a different set of conditions that suppresses the initiation of such faulting.     

Influence of Seasonal Pumping on Groundwater Sources and Flow System,Nagaoka Plain,Japan

Intensive groundwater development in the urban area of the Nagaoka Plain, Japan, has induced changes in the pH and saturation index of calcite in groundwater. To account for these chemical changes, it is important to determine seasonal variations of recharge and the groundwater flow system in the aquifer. This study identified the sources and flow system of groundwater in this urban area by a comprehensive method using stable isotope data and a numerical groundwater model of the Nagaoka Plain. Stable isotope evidence shows that the groundwater is recharged by meteoric water originating from low‐elevation areas rather than the mountains surrounding the plain. The water table in the study area is drawn down during the winter and recovers in the other seasons. Numerical modeling shows that discharge occurs primarily along the Shinano River during the recovery period, whereas discharge is centered in urbanized areas during the drawdown period, when a conical depression of the water table stimulates recharge from the immediate area. These results are indications of a local groundwater flow system, with its recharge area between the Shinano River and the urban areas, which is governed by intensive seasonal groundwater extraction.     

Seismic performance evaluation of single damped‐outrigger system incorporating buckling‐restrained braces

The outrigger system is an effective means of controlling the seismic response of core‐tube type tall buildings by mobilizing the axial stiffness of the perimeter columns. This study investigates the damped‐outrigger, incorporating the buckling‐restrained brace (BRB) as energy dissipation device (BRB‐outrigger system). The building's seismic responses are expected to be effectively reduced because of the high BRB elastic stiffness during minor earthquakes and through the stable energy dissipation mechanism of the BRB during large earthquakes. The seismic behavior of the BRB‐outrigger system was investigated by performing a spectral analysis considering the equivalent damping to incorporate the effects of BRB inelastic deformation. Nonlinear response history analyses were performed to verify the spectral analysis results. The analytical models with building heights of 64, 128, and 256 m were utilized to investigate the optimal outrigger elevation and the relationships between the outrigger truss flexural stiffness, BRB axial stiffness, and perimeter column axial stiffness to achieve the minimum roof drift and acceleration responses. The method of determining the BRB yield deformation and its effect on overall seismic performance were also investigated. The study concludes with a design recommendation for the single BRB‐outrigger system.     

Experimental and numerical studies on buckling restrained braces with posttensioned carbon fiber composite cables

There has been an increasing interest in using residual deformation as a seismic performance indicator for earthquake resistant building design. Self-centering braced structural systems are viable candidates for minimizing residual deformations following a major earthquake. Hence, this study proposes an alternative type of buckling restrained brace (BRB) with externally attached posttensioned (PT-BRB) carbon fiber composite cables (CFCCs). The steel core of the brace is used as an energy dissipator, whereas the CFCCs provide the self-centering force for minimizing residual story drifts. Three proof-of-concept specimens are designed, fabricated, and cyclically tested at different posttensioning force levels. The CFCC behavior to obtain cyclic response, including the anchorage system, is examined closely. A parametric study is also conducted to show the effect of the different configurations of PT-BRBs on the inelastic response. Furthermore, optimal brace parameters are discussed to realize design recommendations. The results indicated that the implementation of partially self-centering BRBs in building frames can lead to the target residual displacements. A stable behavior is obtained for the proposed PT-BRBs when subjected to the loading protocol specified in the American Institute of Steel Construction (AISC) 2016 Seismic Provisions.     

Lithological,structural, and chronological relationships between the Sanbagawa Metamorphic Complex and the Cretaceous Shimanto Accretionary Complex on the central Kii Peninsula,SW Japan

It is essential to clarify the lithological, structural, and chronological relationships between the Sanbagawa Metamorphic Complex (MC) and the Cretaceous Shimanto Accretionary Complex (AC) for understanding the tectonic evolution of SW Japan. To this end, we carried out a detailed field survey of the Sanbagawa MC and the Cretaceous Shimanto AC on the central Kii Peninsula, where they are in direct contact with each other. We also conducted U–Pb dating of detrital zircons from these complexes. The field survey showed that the boundary between the Iro Complex of the Sanbagawa MC and the Mugitani Complex of the Shimanto AC, Narai Fault, shows a sinistral sense of shear with a reverse dip‐slip component, and there are significant differences in the strain intensity and the degree of recrystallization between the two complexes across this fault. Detrital zircon U–Pb dating indicates that the Iro Complex in the hanging wall of the Narai Fault shows a significantly younger maximum depositional age than the Mugitani Complex in the footwall of the fault, and an apparently large gap in the MDA of ca. 35 Myr exists across this fault. This large age gap across the Narai Fault suggests that this fault is an essential tectonic boundary fault within the Cretaceous accretionary–metamorphic complexes on the Kii Peninsula, and is considered to be an out‐of‐sequence thrust. In addition, a similar shear direction and a large age gap have been identified across the Ui Thrust, which marks the boundary between the Kouyasan and Hidakagawa belts of the Cretaceous Shimanto AC. The Cretaceous accretionary–metamorphic complexes record the large‐scale tectonic juxtapositions of complexes, and these juxtaposed structures had been caused by sinistral–reverse movements on the tectonic boundary faults such as the Narai Fault and the Ui Thrust.