Estimating groundwater residence time using multiple regression model based on fluoride dissolution: an exploration of possibilities

High levels of fluoride concentration were observed in deep groundwater of the Mizunami area in Central Japan. Fluoride occurs mainly due to the reaction between granitic basement rock and groundwater. Granites were collected, crushed to powder, and then allowed to react with purified water for 80 days. Water–rock interaction results showed that the major factor affecting fluoride concentration is the residence time of the groundwater. Coexisting ions have also some contribution toward fluoride concentration. The groundwater residence time in the Mizunami area was estimated by applying results of water–rock interaction to correspond with field data. A regression model relating fluoride concentration, residence time, and coexisting ions was developed. The parameters of the regression model were determined using the genetic algorithms technique. Residence time was estimated by extrapolating experimental data to correspond with filed data. Near the recharge area, residence times in the potential fluoride source rock varied between 1 and 2,000 years, whereas near the discharge area residence times were in excess of tens of thousands of years. The groundwater residence time was also estimated by the groundwater particle-tracking-flow model. The estimates of groundwater residence time based on geochemical regression model were often larger than estimates of groundwater residence time developed by particle-tracking analysis using a groundwater flow model. There were large uncertainties—on the order of 10–10,000 years—in the estimates based on geochemical data.     

The origin of fluoride-rich groundwater in Mizunami area, Japan — Mineralogy and geochemistry implications

The aim of this paper was to explore new factors that might be reasons for the occurrence of fluoride-rich groundwater in the area around a construction site. During the construction of two deep shafts of the Mizunami Underground Research Laboratory (MIU) in Mizunami city, central Japan, a large quantity of groundwater with high fluoride concentration was charged into the shafts. Chemical investigation carried out during the excavation revealed that fluoride concentrations in the area around the MIU site greatly exceeded those prescribed by Japanese standards. Therefore, the origin of fluoride ion was experimentally investigated. Samples were collected from the core of a deep borehole drilled in the study area. The weathering - and alteration levels of the collected granites varied greatly. Granitic powders were used to measure fluoride content in the granitic rock mass. The fluoride content ranged between 200 and 1300 mg/kg. The powders were reacted with purified water for 80 days. The results of water–rock interaction showed granitic rock to be one of the main sources of fluoride-rich groundwater in Mizunami area. Fluoride concentrations in these solutions that were shaken for 80 days varied between 2 and 7 mg/l. This change may have occurred as a result of the spatial distribution of fluoride ions in the granite mass as evidenced by mineralogical analysis of fluoride content in several specimens. X-ray powder diffraction analysis of the rock before- and after the water–rock interaction tests manifested that the presence of fluorite mineral was relatively small compared to other minerals. The degree of weathering and alteration might be an additional factor causing dissolution of fluoride-rich minerals. However, it was difficult to interpret the change in fluorite composition by X-ray diffraction analysis.     

Impacts of the local land-use system in a semi-arid region of northeastern China on soil properties, crop growth, and weed communities

We examined changes in soil properties, crop biomass, and weed communities in the Horqin Sandy Land of China to elucidate cropland degradation. We studied three local cropland types having periods of cultivation of up to 20 years: maize cropland on lowlands without irrigation (nonirrigated lowland), maize cropland on flat sandy lands with irrigation (irrigated flatland), and bean-centered cropland on sand dunes without irrigation (nonirrigated dunes). Soil properties and crop biomass were more degraded in nonirrigated lowland and nonirrigated dunes than in irrigated flatland. Weed communities in the nonirrigated croplands were the type that become established in drier conditions, whereas wetland weeds were more abundant on irrigated flatland. Trends of change in each indicator did not always occur in parallel and differed statistically among the cropland types. Monitoring these indicators within the context of local land-use systems can provide scientific evidence on which to base local management practices or recommendations for change.     

Additionality reconsidered: lax criteria may not benefit developing countries

Abstract

International negotiation on the additionality issue of the CDM (Clean Development Mechanism) seems to be proceeding without sufficient information or understanding. Especially apparent is a lack of recognition that the non-additional CERs (certified emission reductions) generated by relaxing the additionality criteria may lead to economic losses for developing countries. This article quantitatively reconfirms the effects of non-additional CERs on the international community, while clarifying that the generation of non-additional CERs in excess of a certain number will eventually lead to negative consequences for developing countries, even if these countries were able to acquire all the non-additional CERs. Furthermore, the Discussion section demonstrates that future system design would significantly affect the benefits of developing countries as well as the overall environmental integrity of the Kyoto mechanisms.     

Correlation between El Niño–Southern Oscillation (ENSO) and precipitation in South‐east Asia and the Pacific region

The relationship between El Niño–Southern Oscillation (ENSO) events versus precipitation anomalies, and the response of seasonal precipitation to El Niño and La Niña events were investigated for 30 basins that represent a range of climatic types throughout South‐east Asia and the Pacific region. The teleconnection between ENSO and the hydroclimate is tested using both parametric and non‐parametric approaches, and the lag correlations between precipitation anomalies versus the Southern Oscillation Index (SOI) several months earlier, as well as the coherence between SOI and precipitation anomalies are estimated. The analysis shows that dry conditions tend to be associated with El Niño in the southern zone, and part of the middle zone in the study area. The link between precipitation anomalies and ENSO is statistically significant in the southern zone and part of the middle zone of the study area, but significant correlation was not observed in the northern zone. Patterns of precipitation response may differ widely among basins, and even the response of a given river basin to individual ENSO events also may be changeable. Copyright © 2003 John Wiley & Sons, Ltd.     

U–Pb dating of detrital zircon from Permian successions of the South Kitakami Belt,Northeast Japan: Clues to the paleogeography of the belt

The South Kitakami Belt in the northeast Japan is unique in presence of a thick Paleozoic–Mesozoic sedimentary rocks. The Permian sedimentary succession in the Maiya area of this belt is divided into the Nishikori, Tenjinnoki, and Toyoma formations, in ascending stratigraphic order. The Tenjinnoki Formation includes the Yamazaki Conglomerate Member containing granitic clasts. We performed U–Pb dating for detrital zircon of one sample of tuffaceous sandstone from the Nishikori Formation, six samples of sandstone from the Tenjinnoki and Toyoma formations, and five granitic clasts from the Yamazaki Conglomerate using laser ablation-inductively coupled plasma-mass spectrometry. Our dating results show that the tuffaceous sandstone sample has two age peaks at 287 and 301 Ma for the Nishikori Formation, three age peaks at 320–300, 290, and 270 Ma for the Tenjinnoki and Toyoma Formation, and ages of 311, 300, and 270 Ma from granitic clasts of the Yamazaki Conglomerate. In addition, older ages of 452–435 and 380 Ma were obtained from some zircon grains of the sandstone and granitic clasts. Our results suggest igneous activity in these periods. The South Kitakami Belt's origin with respect to continental blocks has been discussed in regard of the margin of North China Block or South China Block. Based on the stratigraphic ages and timing of igneous activity, we conclude that during the Permian the South Kitakami Belt was located at the margin of the South Central Asian Orogenic Belt, near the Solonker-Xra Moron-Changchun suture and the North China Block in East Asia.     

Eccentricity cycles shown by early Pleistocene planktonic foraminifers of the Omma Formation, Sea of Japan

There is a continuous record of planktonic foraminifers for oxygen isotope stages 50 to 26 (ca. 1.5–1.0 Ma) in the early Pleistocene Omma Formation near Kanazawa City, Central Japan, on the Sea of Japan coast. The warm-water species Globigerinoides ruber entered the Sea of Japan with the Tsushima Current during all interglacial periods and went locally extinct in the succeeding glacial periods. This implies that the marine climate of the Sea of Japan varied predominantly with the 41,000-year period of Earth's orbital obliquity. However, the relative abundances of G. ruber in marine isotope stages 47, 43 and 31 are significantly higher than those in other interglacial stages. These stages correspond to periods when eccentricity-modulated precession extremes were aligned with obliquity maxima. The Tsushima Current is a branch of the warm Kuroshio Current which is the strong northwestern component of the subtropical North Pacific Ocean gyre. Our data imply that the early Pleistocene climate in the northwestern Pacific was influenced not only by obliquity cycles but also by eccentricity cycles. This study also supports the climate model regarding eccentricity's role in the origin of low-frequency climate changes before the late Pleistocene ice ages.     

Statistical analyses and modeling approaches to hydrodynamic characteristics in alluvial aquifer

This study is aimed at quantifying the difference in aquifer's response to recharge between some different locations in a fan aquifer and a delta aquifer for a preliminary study of revealing mechanisms of water transport in alluvial aquifer. The aquifer's response to recharge is statistically quantified with the two viewpoints: (1) timing and volume of recharge and (2) time length of aquifer's holding water. For the first point, a statistical model that links precipitation and groundwater level is introduced, and its parameters are identified using correlation analysis. Our results show that the recharge rate at the toe is higher than that at the apex and at the delta. For the second point, the concept of ‘memory effect’ of aquifer is adopted and quantified using the autocorrelation and spectral analyses. Our results show that the memory effect is longer at the toe of fan than at the apex, and thus, a temporary increase of water level has about five times as long‐term influence on subsequent water levels at the toe of the fan as at the apex. This study demonstrates that the statistical analyses and modeling of hydrological data are useful for characterizing aquifer's hydrodynamics. Copyright © 2012 John Wiley & Sons, Ltd.