Interactive effect of cadmium and zinc on chromium uptake in spinach grown in Vertisol of Central India

A pot culture experiment was conducted to study impact and interaction of multi-metals on growth, yield and metals uptake by spinach (variety All Green). Three levels of each chromium (0, 50 and 100 mg/kg), cadmium (0, 1 and 2 mg/kg) and zinc (0, 10 and 20 mg/kg) in combinations (total treatments 3 × 3 × 3 = 27) were applied in a Vertisol (5 kg). The results showed that increasing the concentration of chromium, cadmium and zinc in soil enhanced the respective metal concentrations in spinach root and shoot. When cadmium at 2 mg/kg along with chromium at 100 mg/kg soil was applied, chromium concentration and uptake were decreased in root and shoot. Meanwhile, zinc application had no significant effect on chromium uptake and concentration in spinach biomass. From the results, it was concluded that cadmium at higher dose had an antagonistic effect over chromium. On the other hand, in chromium, cadmium and zinc combinations particularly at their higher levels, a competition among each other was found. Therefore, the findings could be used as guidelines for controlling and management of heavy metals pollution in farmland.     

Propagation of Love type waves in a non-homogeneous layer lying over a vertically semi-infinite homogeneous isotropic medium

Summary The aim of this paper is to study the propagation of love-type waves in a homogeneous half-space overlain by a heterogeneous crust with various types of heterogenety. Frequency equations are obtained in each of the cases and numerical calculations are done in some cases and the results thus obtained are compared with those done byJeffreys andMitra [3]²).     

Coastal circulation along the central west coast of India during cyclone Phyan: measurements and numerical simulations

Measurements and numerical simulations carried out off Mumbai coast for the period 22 October?C22 November 2009 showed significant variations in water level and currents during cyclone Phyan. Changes in the meridional component of the current velocity were found to be highly significant during Phyan. The strong southward flow due to the cyclone resulted in a complete nullification of a flood current and continued the net flow towards south for approximately 18?h. This enhanced the ebb flow by about 0.12?m/s off Worli and 0.16?m/s off Satpati. The shift in the cyclone generated currents towards north resulted in an enhancement of flood current by 0.3?m/s off Worli and 0.2?m/s off Satpati. During the first 7?h of Phyan, a strong current system associated with an anti-cyclonic eddy was formed off Mangalore, which propagated towards north up to Ratnagiri and disappeared while the cyclone entered the land. Water level variations of 0.38 and 0.44?m were observed due to Phyan off Worli and Satpati, respectively. Positive and negative surges, that is, a fall in water level up to ?20?cm and a rise up to 20?cm, were observed during Phyan and these were associated with shift in the wind direction.     

Holocene tectono-geomorphic evolution of Haryana plains,Western Ganga plain,India

Haryana plain is the drainage divide between the Ganga plain in the east and the Indus plain in the west. Being a part of the Himalayan foreland, its geomorphology, sedimentation processes, and tectonism are broadly controlled by the Himalayan tectonics. Soil and geomorphological mapping in Haryana plain bring out geomorphic features such as paleochannels, various active drainage patterns, and landforms such as old fluvial plains, floodplains, piedmonts, pediments, terminal fans, and eolian plains. Based on the degree of soil development, and Optical stimulated luminescence (OSL) ages, the soil-geomorphic units were grouped into six members (QIMS-I to VI) (Quaternary Indus Morphostratigraphic Sequence) of a morphostratigraphic sequence: QIMS-VI 9.86–5.38 Ka, QIMS-V 5.38–4.45 Ka, QIMS-IV 4.45–3.60 Ka, QIMS-III 3.60–2.91 Ka, QIMS-II <?2.91–1.52 Ka, and QIMS-I <?1.52 Ka. OSL chronology of different geomorphic features suggests six episodes of tectono-geomorphic evolution in the region since 10 Ka. Neotectonic features such as nine faults, two lineaments, and five fault-bounded tectonic blocks have been identified. Independent tilting and sagging of the blocks in response to neotectonics have resulted in modification of landforms, depositional processes, and hydro-geomorphology of the region. Major rivers like the Yamuna, the Ghaggar, and the Sutlej show different episodes of shifting of their courses. Lineament controlled few extinct channels have been recorded between 20 and 25 m depth below the surface in the ground-penetrating radar (GPR) profiles. These buried channels are aligned along the paleo-course of the Lost Saraswati River interpreted from the existing literature and hence are considered as the course of the lost river. Seven terminal fans have been formed on the downthrown blocks of the associated faults. The Markanda Terminal Fan, the first of such features described, is indeed a splay terminal fan and was formed by a splay distributary system of the Markanda River. Association of three terminal fans of different ages with the Karnal fault indicates the segment-wise development of the fault from west to east. Also, comparison with other such studies in the Ganga plain to further east suggests that the terminal fans formed by streams with distributary drainage pattern occur only in semiarid regions as in the present area and thus are indicators of semiarid climate/paleoclimate. Though the whole region is tectonically active, the region between the Rohtak fault and Hisar fault is most active at present signified by the concentration of earthquake epicenters.     

Reconstruction of specific mass balance for glaciers in Western Himalaya using seasonal sensitivity characteristic(s)

Seasonal sensitivity characteristics (SSCs) were developed for Naradu, Shaune Garang, Gor Garang and Gara glaciers, Western Himalaya to quantify the changes in mean specific mass balance using monthly temperature and precipitation perturbations. The temperature sensitivities were observed high during summer (April–October) and precipitation sensitivities during winter months (November–March), respectively. The reconstructed mass balance correlates well with the field and remote sensing measurements, available between 1980 and 2014. Further, SSCs were used with the monthly mean temperatures and precipitation estimates of ERA 20CM ensemble climate reanalysis datasets to reconstruct the specific mass balance for a period of 110 years, between 1900 and 2010. Mass balance estimates suggest that the Shaune Garang, Gor-Garang and Gara glaciers have experienced both positive and negative mass balance, whereas the Naradu glacier has experienced only negative mass balance since 1900 AD. Further, a cumulative loss of \(-133 \pm 21.5\) m.w.e was estimated for four glaciers during the observation period. This study is the first record from Indian Himalaya in evaluating the mass balance characteristics over a century scale.     

Spatio-temporal dynamics of heavy metals in sediments of the river estuarine system: Mahanadi basin (India)

Dynamics of heavy metals in the surface sediments of Mahanadi river estuarine system were studied for three different seasons. This study demonstrates that the relative abundance of these metals follows in the order of Fe > Mn > Zn > Pb > Cr > Ni ≥ Co > Cu > Cd. The spatial pattern of heavy metals supported by enrichment ratio data, suggests their anthropogenic sources possibly from various industrial wastes and municipal wastes as well as agricultural runoff. The metal concentrations in estuarine sediments are relatively higher than in the river due to adsorption/accumulation of metals on sediments during saline mixing, while there is a decreasing trend of heavy metal concentrations towards the marine side. The temporal variations for metals, such as Fe, Mn, Zn, Ni and Pb exhibit higher values during monsoon season, which are related to agricultural runoff. Higher elemental concentrations are observed during pre-monsoon season for these above metals (except Ni) at the polluted stations and for metals, such as Cr, Co and Cd at all sites, which demonstrate the intensity of anthropogenic contribution. R-mode factor analysis reveals that “Fe–Mn oxy hydroxide”, “organic matter”, “CaCO₃”, and “textural variables” factors are the major controlling geochemical factors for the enrichment of heavy metals in river estuarine sediment and their seasonal variations, though their intensities were different for different seasons. The relationships among the stations are highlighted by cluster analysis, represented in dendrograms to categorize different contributing sites for the enrichment of heavy metals in the river estuarine system.     

Utilization of ochre as an adsorbent to remove Pb(II) and Cu(II) from contaminated aqueous media

The ability of ochre to remove Pb(II) and Cu(II) from aqueous media has been studied by batch sorption studies varying the contact time, initial metal concentration, initial solution pH and temperature to understand the adsorption behaviour of these metals through adsorption kinetics and isotherms. The pH of the solution and the temperature controlled the adsorption of metal ions by ochre and rapid uptake occurred in the first 30 min of reaction. The kinetics of adsorption followed a pseudo-second-order rate equation (R ² > 0.99) and the isotherms are well described by the Freundlich model. Adsorption of metals onto ochre is endothermic in nature. Between the two metals, Pb(II) showed more preference towards the exchangeable sites on ochre than Cu(II). This study indicates that ochre is a very effective adsorbent in removing Pb(II) and Cu(II) from the aqueous environment with an adsorptive capacity of 0.996 and 0.628 mg g^?1 and removal efficiency of 99.68 and 62.80 %, respectively.