Removal of lead (II) from synthetic and batteries wastewater using agricultural residues in batch/column mode

The present article explores the ability of five different combinations of two adsorbents (Arachis hypogea shell powder and Eucalyptus cameldulensis saw dust) to remove Pb(II) from synthetic and lead acid batteries wastewater through batch and column mode. The effects of solution pH, adsorbent dose, initial Pb(II) concentration and contact time were investigated with synthetic solutions in batch mode. The Fourier transform infrared spectroscopy study revealed that carboxyl and hydroxyl functional groups were mostly responsible for the removal of Pb(II) ions from test solutions. The kinetic data were found to follow pseudo-second-order model with correlation coefficient of 0.99. Among Freundlich and Langmuir adsorption models, the Langmuir model provided the best fit to the equilibrium data with maximum adsorption capacity of 270.2 mg g^?1. Column studies were carried out using lead battery wastewater at different flow rates and bed depths. Two kinetic models, viz. Thomas and Bed depth service time model, were applied to predict the breakthrough curves and breakthrough service time. The Pb(II) uptake capacity (q _e = 540.41 mg g^?1) was obtained using bed depth of 35 cm and a flow rate of 1.0 mL min^?1 at 6.0 pH. The results from this study showed that adsorption capacity of agricultural residues in different combinations is much better than reported by other authors, authenticating that the prepared biosorbents have potential in remediation of Pb-contaminated waters.     

Hydrogeochemical investigation and groundwater quality assessment of Pratapgarh district,Uttar Pradesh

Hydogrochemical investigation of groundwater resources of Paragraph district has been carried out to assess the solute acquisition processes and water quality for domestic and irrigation uses. Fifty-five groundwater samples were collected and analyzed for pH, electrical conductivity, total dissolved solids, hardness, major anions (F^?, Cl^?, NO₃, HCO₃ ^?, SO₄ ^2?) and cations (Ca²⁺, Mg²⁺, Na⁺, K⁺). Study results reveal that groundwater of the area is alkaline in nature and HCO₃ ^?, Cl^?, Mg²⁺, Na⁺ and Ca²⁺ are the major contributing ions to the dissolved solids. The hydrogeochemical data suggest that weathering of rock forming minerals along with secondary contributions from agricultural and anthropogenic sources are mainly controlling the groundwater composition of Pratapgarh district. Alkaline earth metals (Ca²⁺+Mg²⁺) exceed alkalis (Na⁺+K⁺) and weak acid (HCO₃ ^?) dominate over strong acids (Cl^?+SO₄ ^2?) in majority of the groundwater samples. Ca-Mg-HCO₃ and Ca-Mg-Cl-HCO₃ are the dominant hydrogeochemical facies in the groundwater of the area. The computed saturation indices demonstrate oversaturated condition with respect to dolomite and calcite and undersaturated with gypsum and fluorite. A comparison of groundwater quality parameters in relation to specified limits for drinking water shows that concentrations of TDS, F^?, NO₃ ^? and total hardness exceed the desirable limits in many water samples. Quality assessment for irrigation uses reveal that the groundwater is good for irrigation. However, values of salinity, sodium adsorption ratio (SAR), residual sodium carbonate (RSC), %Na and Kelley index are exceeding the prescribed limit at some sites, demanding adequate drainage and water management plan for the area.     

Nine years of GPS measurements of crustal deformation at Imphal,Indo-Burmese wedge

We report results of 9 years of GPS measurements of crustal deformation at Imphal, Manipur, a site located in the Indo-Burmese wedge of northwest Sunda arc. The analysis of these measurements suggests that the site moves at a rate of about 36.3±0.5 mm/year towards N55° in the ITRF2008. With respect to the Indian plate it moves at a rate of 16.7 mm/year towards N222°, i.e., predominantly towards southwest. The site is located about 15 km east of the Churachandpur Mao fault (CMF), which is reported to accommodate part of the India-Sunda motion. The site motion is not significantly affected by the earthquakes that occurred in the nearby region. However, the 2004 Sumatra-Andaman earthquake caused a coseismic displacement of ～ 3–5 mm predominantly towards southwest. The site motion is almost linear, with some seasonal variation, and does not show any evidence of accelerated slip or slow earthquake on the CMF or along the plate boundary.     

Avalanche hazard mitigation in east Karakoram mountains

Natural Hazards - Karakoram mountains range in north-western part of Himalayas is about 500 km in length and hosts some of the world’s highest peaks and longest glaciers. It is...     

Evaluation of a probabilistic approach to simulation of alkalinity and electrical conductivity at a river bank filtration site

In river bank filtration, impurities present in the river water travel with the bank filtrate towards the pumping well. During this passage, certain types of impurities, such as turbidity, total coliform, and so forth, may get attenuated; however, it is interesting to note that some of the instant raw river water quality parameters, such as alkalinity and electrical conductivity, increase after the passage of water through the porous medium. This occurs because water, when passing through the soil pores, absorbs many of the solutes that cause an increase in alkalinity and electrical conductivity. Measurements at a river bank filtration site for a year showed that alkalinity of 116–32 mg l^?1 in river water increased to 222.4–159.9 mg l^?1 in the river bank filtered water. Likewise, the electrical conductivity increased from 280–131 μS cm^?1 to 462–409.6 μS cm^?1. This study uses a probabilistic approach for investigating the variation of alkalinity and electrical conductivity of source water that varies with the natural logarithm of the concentration of influent water. The probabilistic approach has the potential of being used in simulating the variation of alkalinity and electrical conductivity in river bank filtrate. Copyright © 2011 John Wiley & Sons, Ltd.     

Hammond Hill Research Catchment: Supporting hydrologic investigations of rooting zone and vegetation water dynamics under climate change

The Hammond Hill Research Catchment (HH) is a small (120 ha), temperate, second order tributary to Six Mile Creek, Cayuga Lake, and the Great Lakes (42.42°, −76.32°). The HH has been monitored since January 2017 for the purpose of understanding how recent infiltration mixes with antecedent soil water on hillslope forest floors and the spatial and temporal patterns of Root Water Uptake (RWU) by temperate northeastern US tree species (eastern hemlock [Tsuga canadensis], American beech [Fagus grandifolia], and sugar maple [Acer saccharum]). These data are informing us about the hydrologic consequences of anticipated tree species composition change and supporting the development of more refined ecohydrological models. The glaciated catchment is underlain by a shallow confining siltstone layer (1–1.5 m depth) and densely covered with an approximately 60 year old regrowth mixed species forest of hemlock, beech, and other deciduous tree species common to the northeastern US. Current datasets from the HH include precipitation snow water equivalent, discharge, and associated isotopic water compositions, δ²H & δ¹⁸O. Measurements of (top 10 cm) soil water content, as well as bulk soil water and hemlock and beech xylem isotopic compositions are made at several locations across a topographic wetness gradient. The near-term role of the HH is to support an understanding of the environmental and ecological drivers of plant RWU competition. All data from the HH are publicly available.     

Separation of magnetic anomalies into induced and remanent magnetization contributions

Inversion of magnetic data is complicated by the presence of remanent magnetization, and it provides limited information about the magnetic source because of the insufficiency of data and constraint information. We propose a Fourier domain transformation allowing the separation of magnetic anomalies into the components caused by induced and remanent magnetizations. The approach is based on the hypothesis that each isolated source is homogeneous with a uniform and specific Koenigsberger ratio. The distributions of susceptibility and remanent magnetization are subsequently recovered from the separated anomalies. Anomaly components, susceptibility distribution and distribution of the remanent and total magnetization vectors (direction and intensity) can be achieved through the processing of the anomaly components. The proposed method therefore provides a procedure to test the hypotheses about target source and magnetic field, by verifying these models based on available information or a priori information from geology. We test our methods using synthetic and real data acquired over the Zhangfushan iron-ore deposit and the Yeshan polymetallic deposit in eastern China. All the tests yield favourable results and the obtained models are helpful for the geological interpretation.     

Mechanical response of a piezoelectric composite transducer subjected to a thermal field

Summary The present paper studies the mechanical response of a piezoelectric composite transducer—with an elastic compliance partly constant and partly variable with time—acted upon by suitable thermal field besides the electrical voltage. The Laplace transform has been applied to solve the problem.     

Regional character of induced magnetic variations in India

Variations recorded simultaneously at eight Indian stations during a magnetic storm are analysed to obtain the power spectra for each component using the fast Fourier transform. For two selected peaks, observed for H at all stations, at 49.5- and 70-min periods, a complex demodulation is performed for each component. From the variations thus obtained, horizontal polarization ellipses are drawn for four events of 49.5-min period. The variation of the demodulates and polarization ellipses at the stations shows a regional character which coincides with the physiographic grouping of the stations. Anomalously large Z variations are observed at the equatorial stations, which are near the sea. A distinct feature is the suppression of H at Trivandrum where the polarization ellipses confirm the E-W trend of the induced currents in this region. The overall similarity of the horizontal variations is demonstrated by these ellipses. Horizontal disturbance vectors at Annamalainagar, Trivandrum and Sabhawala confirm channelled currents located previously. At Shillong, the induced effects are evident and the currents are deduced to flow eastward, directly beneath the station.The overall regional similarities in variations are clearly manifested.     

Effects of linear and exponential heterogeneity on the dynamic response of a moving load in an irregular isotropic half-space: a comparative study

Heterogeneity, being a trivial feature inside the earth or in a geostructure, makes a strong basis for its consideration in the study of geomechanics. Inclusion of the concept of heterogeneity along with irregularity in the medium brings a novelty to the existing literature related to the study of the moving load. The present study investigates the effects of linear and exponential heterogeneity on the dynamic response due to a normal load moving with constant velocity on a rough irregular heterogeneous isotropic half-space in a comparative approach. Expressions for both normal and shear stresses for either case of heterogeneity have been established in closed form. Substantial effects of the affecting parameters such as depth, irregularity factor, maximum depth of irregularity, frictional coefficient, linear heterogeneity parameter and exponential heterogeneity parameter on normal and shear stresses for both the cases of heterogeneity have been observed. Numerical computation has been carried out and the effects of said parameters have been meticulously examined by means of graphs. Moreover, different cases of heterogeneity and homogeneity along with various types of irregularity namely rectangular, parabolic and no irregularity are compared which serve as a focal theme of the study.