Terpenoid composition and origin of amber from the Cape York Peninsula,Australia

The terpenoid composition of fossil resin from the Cape York Peninsula, Australia has been analysed by pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS) to determine its origin. The pyrolysis products were dominated by cadalene-based C₁₅ bicyclic sesquiterpenoids including some C₃₀–C₃₁ bicadinanes and bicadinenes typical of Class II resin derived from angiosperm plants of Dipterocarpaceae. This observation contrasts with the Araucariaceae (Agathis sp.) source previously suggested for the resin based on Fourier transform infrared (FTIR) analyses. Dipterocarpaceae are not known in Australian vegetation but grow abundantly in Southeast Asia including New Guinea, indicating that the geological origin of the amber is not the Australian mainland but could be traced to Southeast Asia.     

Using geovisual analytics to compare the performance of geographically weighted discriminant analysis versus its global counterpart,linear discriminant analysis

Geographically weighted spatial statistical methods are a family of spatial statistical methods developed to address the presence of non-stationarity in geographical processes, the so-called spatial heterogeneity. While these methods have recently become popular for analysis of spatial data, one of their characteristics is that they produce outputs that in themselves form complex multi-dimensional spatial data sets. Interpretation of these outputs is therefore not easy, but is of high importance, since spatial and non-spatial patterns in the results of these methods contain clues to causes of underlying non-stationarity. In this article, we focus on one of the geographically weighted methods, the geographically weighted discriminant analysis (GWDA), which is a method for prediction and analysis of categorical spatial data. It is an extension of linear discriminant analysis (LDA) that allows the relationship between the predictor variables and the categories to vary spatially. This produces a very complex data set of GWDA results, which include on top of the already complex discriminant analysis outputs (e.g. classifications and posterior probabilities) also spatially varying outputs (e.g. classification function parameters). In this article, we suggest using geovisual analytics to visualise results from LDA and GWDA to facilitate comparison between the global and local method results. For this, we develop a bespoke visual methodology that allows us to examine the performance of global and local classification method in terms of quality of classification. Furthermore, we are also interested in identifying the presence (or absence) of non-stationarity through comparison of the outputs of both methods. We do this in two ways. First, we visually explore spatial autocorrelation in both LDA and GWDA misclassifications. Second, we focus on relationships between the classification result and the independent variables and how they vary over space. We describe our visual analytic system for exploration of LDA and GWDA outputs and demonstrate our approach on a case study using a data set linking election results with a selection of socio-economic variables.     

Imagining the Dirty Green City

ABSTRACT

The green city is being elevated to the status of a self-evident good in the theory and practice of urban sustainability. A large literature documents the linked environmental, economic and well-being benefits associated with vegetating urban systems to maximise the ecosystem function. Contemporary urban greening seeks to challenge attempts to expel nature from the city in a quest for order and control. However, by imagining nature as a new mode of urban purification, much effort in the name of the green city inverts and reproduces dualistic understandings of natural and built space. In response, we disrupt the normative dialectics of purity and dirt that sustain this dualism to expose the untidy but fertile ground of the green city. We draw together Ash Amin’s four registers of the Good City – relatedness, rights, repair and re-enchantment – with the artworks of the Australian visual ecologist Aviva Reed. Our work seeks to enrich the practice of more-than-human urbanism through ‘dirt thinking’ by imagining the transformative possibilities in, of and for the dirty green city.     

Effect of Sample Digestion,Air Filter Contamination,and Post‐adsorption on the Analysis of Trace Elements in Air Particulate Matter

Inductively coupled plasma atomic emission spectrometry and inductively coupled plasma MS are the major analytical tools for trace elements in environmental matrices, however, the underestimate of certain trace elements in analysis of air particulate matter by these two techniques has long been observed. This has been attributed to incomplete sample digestion. Here, we demonstrate that the combined effects of sample digestion, air filter impurities, and post‐adsorption of the analytes contribute to the interference of the analysis. Particular attention should be paid to post‐adsorption of analytes onto air filters after acid digestion.     

Seismic Reflection and Vibracoring Studies of the Continental Shelf Offshore Central and Western Long Island,New York

The ridge-and-swale topography on the continental shelf south of Fire Island, New York, is characterized by northeast-trending linear shoals that are shore attached and shore oblique on the inner shelf and isolated and shore parallel on the middle shelf. High-resolution seismic reflection profiles show that the ridges and swales occur independent of, and are not controlled by, the presence of internal structures (for example, filled tidal inlet channels, paleobarrier strata) or underlying structure (for example, high-relief Cretaceous unconformity). Grab samples of surficial sediments on the shelf south of Fire Island average 98 % sand. Locally, benthic fauna increase silt and clay content through fecal pellet production or increase the content of gravel-size material by contribution of their fragmented shell remains. Surficial sand on the ridges is unimodal at 0.33 mm (medium sand, about 50 mesh), and surficial sand in troughs is bimodal at 0.33 mm and 0.15 mm (fine sand, about 100 mesh). In addition to seismic studies, 26 vibracores were recovered from the continental shelf in state and federal waters from south of Rockaway and Long Beaches, Long Island, New York. Stratigraphic and sedimentological data gleaned from these cores were used to outline the geologic framework in the study area. A variety of sedimentary features were noted in the cores, including burrow-mottled sections of sand in a finer silty-sand, rhythmic lamination of sand and silty-sand that reflect cyclic changes in sediment transport, layers of shell hash and shells that probably represent tempestites, and changes from dark color to light color in the sediments that probably represent changes in the oxidation reduction conditions in the area with time. The stratigraphic units identified are an upper, generally oxidized,nearshore facies, an underlying fine-to medium-sand and silty-clay unit considered to be an estuarine facies, and a lower, coarse-grained, deeply oxidized, cross-laminated preHolocene unit. Grain-size analysis shows that medium-to fine-grained sand makes up most (68-99 %) of the surficial sediments. Gravel exists in trace amounts up to 19 %. Silt ranges between 3 % and 42 %, and clay ranges from 1 % to 10 %.     

Locating art worlds: London and the making of Young British art

The international prominence of Young British art (YBa) in the 1990s gave London a contemporary art movement to match its role as one of the world's key centres of art exchange. Examining the rise of YBa in retrospect, this paper is concerned with the difference place makes in helping to shape the (hi)story of art. It is argued that London's established role as an international art centre was crucial in providing the density of networks, associations and facilities necessary to sustain an international art movement. At the same time, YBa's success can be linked to London's changing status as a cultural capital, as well as profound changes in the business of contemporary art. Attention is drawn to the ways in which the international art world is dominated by networks formed within and across a limited number of world art cities.     

High-pressure synthesis of priderite and members of the lindsleyite-mathiasite and hawthorneite-yimengite series

Experiments investigating simplified members of the alkali-titanate mineral series priderite, lindsleyite-mathiasite (LIMA) and hawthorneite-yimengite (HAWYIM) confirm their stability at pressures between 3.5 and 5 GPa for priderite and LIMA, 4.3 and 5 GPa for HAWYIM at likely mantle solidus temperatures. Starting materials with K/Ba=1 resulted in solid-solutions for LIMA, whereas HAWYIM produced separate hawthorneite (K/Ba approx. 0.5) and nearly pure yimengite (K), indicating the existence of an asymmetric solvus for HAWYIM at high pressures. Priderite was examined with iron present as either Fe³⁺ or Fe²⁺; both are stable at 5 GPa, confirming the possible coexistence of priderite with diamond. X-ray powder diffraction data on end-members synthesized at high pressures and calculated reflection patterns improve the scope of diffraction data on these rare mantle minerals, with only small differences existing between the patterns for the synthetic minerals and those observed or expected for natural minerals.     

Assessing the impact of modern recharge on a sandstone aquifer beneath a suburb of Doncaster, UK

A major water quality issue in urban areas underlain by a productive aquifer is the impact of modern recharge. Using a variety of sample sources including multi-level boreholes, detectable concentrations of CFCs and SF₆ have been found throughout the upper 50 m of the saturated aquifer beneath a suburb of Doncaster, UK, indicating that modern (<50-year old) recharge has penetrated to at least this depth. Additional support for this deep penetration is provided by the detection of sulphite-reducing clostridia and faecal streptococci. Despite the upper aquifer being a poorly cemented sandstone, the residence time indicators suggest that some modern recharge is travelling via fracture systems in addition to that moving down by simple piston flow. However, the overall impact of 80 years of steady urbanisation on water quality in the aquifer beneath this suburb has in general been limited. This is attributed to a combination of factors including previous land use, dilution by direct recharge of rainfall through green-space areas including gardens, and locally high storage in the friable upper aquifer.     

Petrological characterization of the source components of potassic magmas: geochemical and experimental constraints

The source mineralogy and conditions of origin of the three main groups of ultrapotassic rocks are outlined by combining experimental constraints and an abstraction of evidence from whole-rock chemistry (including volatiles), tectonic setting and xenolith contents. Lamproites originate from a depleted source rock which was strongly re-enriched at a later stage, thus producing mica-harzburgite. Melting conditions are H₂O-rich and in most cases strongly reducing. Kamafugites originate from a clinopyroxene-reich source, also with abundant mica, in more oxidizing, CO₂-rich conditions. Members of the third group form in a relatively fertile spinel-peridotite also containing abundant clinopyroxene and mica. Contrasting effects of variation in (i) pressure of melting and (ii) oxygen fugacity, emphasize the importance of these parameters in the sources of ultrapotassic rocks.

Currently popular models for the origin of ultrapotassic melts by partial melting of phlogopite-bearing lherzolite are inconsistent with the now extensive array of liquidus experimental results on ultapotassic rock compositions. The discrepancy between partial melting models and liquidus results is attributed to the implicit, invalid assumption in the partial melting models that incompatible elements are homegeneously distributed on a large scale. Non-peridotitic assemblages rich in mica and pyroxenes which may be completely free of olivine must have an important role in the genesis of potassic rocks as spatially restricted components of inhomogeneous source regions.     

Evidence for Archean ocean crust with low high field strength element signature from diamondiferous eclogite xenoliths

Late Archean (2.57 Ga) diamond-bearing eclogite xenoliths from Udachnaya, Siberia, exhibit geochemical characteristics including variation in oxygen isotope values, and correlations of δ¹⁸O with major elements and radiogenic isotopes which can be explained by an origin as subducted oceanic crust. Trace element analyses of constituent garnet and clinopyroxene by Laser-ICPMS are used to reconstruct whole-rock trace element compositions, which indicate that the eclogites have very low high field strength element (HFSE) concentrations and Zr/Hf and Nb/Ta ratios most similar to modern island arcs or ultradepleted mantle. Although hydrothermal alteration on the Archean sea floor had enough geochemical effect to allow the recognition of its effects in the eclogites and thus diagnose them as former oceanic crust, it was not severe enough to erase many other geochemical features of the original igneous rocks, particularly the relatively immobile HFSEs. Correlations of the trace element patterns with oxygen isotopes show that some, generally Mg-richer, eclogites originated as lavas, whereas others have lower δ¹⁸O and higher Sr and Eu contents indicating an origin as plagioclase-bearing intrusive rocks formed in magma chambers within the ocean crust. Major and trace element correlations demonstrate that the eclogites are residues after partial melting during the subduction process, and that their present compositions were enriched in MgO by this process. The original lava compositions were picritic, but not komatiitic, whereas the intrusives had lower, basaltic MgO contents. The HFSE signature of the eclogites may indicate that ocean floor basalts of the time were relatively close to island arcs and recycled material, which would be consistent with a larger number of smaller oceanic plates. Their composition appears to indicate that komatiitic ocean crust compositions were restricted to the early Archean which is not known to be represented among the eclogite xenolith population.