Development of design storm hyetographs in hyper-arid and arid regions: case study of Sultanate of Oman

The temporal distribution of the design storm is an important input in hydrological models. This research aims to develop design storm profiles representative of arid and hyper-arid areas based on actual storm recordings. Two hundred thirty-six rainfall storms were collected from seventeen rainfall gauges that cover the coastal zone of Oman for the period from 1993 to 2007. Storms were classified into four categories according to their total durations. Design storm hyetographs were derived from raw rainfall records for all four categories using the Alternating Block Method (ABM) and were also computed by ABM applied on the Intensity-Duration-Frequency (IDF) curves. Both design storm profiles were compared and it was found that the ABM_IDF storm profiles were equivalent to the four ABM_Storms profiles from a practical point of view as they produce similar peak discharges. The storm profiles developed in the current research were also compared to the commonly used Soil Conservation Service (SCS) dimensionless distributions and the UK50 storm profiles. The results showed that the most conservative commonly used SCS type II and the UK50 summer profiles are not safe to be used in design purposes in arid and hyper arid regions, despite their wide utilization in many codes of practice in these regions. The study recommends using the newly developed dimensionless storm profiles derived from the actual records.     

Contribution of the geomagnetism to the region of the massif Jbel Saghro geology,Eastern Anti-Atlas,Morocco

Our investigation relates to the interpretation of the magnetic data of Jbel Saghro, by aeromagnetic processing using Geosoft and ArcGis software. The data were obtained from digitizing the preexisting maps. From the magnetic field anomaly maps, different anomalies were identified with differences in intensities, sizes, and shapes and in being isolated or interfered. The directions are in general ENE-WSW, NNW-SSE, W-E, and NW-SE which are in good agreement with the general tectonic structure of the region. In order to correspond the anomalies to their natural sources and their geometrical configuration, it was necessary to calculate the residual polar. This avoids the presence of two lobes for the same source, what makes it possible to delimit the geological sources laterally. Thus, the attribution of each magnetic anomaly to its geological source becomes possible. Indeed, generally magnetic anomaly of strong intensities and big wavelengths is associated to very magnetized structures related to the Precambrian basement, and the negative a.m. is connected to structures of weak magnetization located in general in the cover. The application of the tilt angle filter allowed the localization of the outcrops of the inliers and new geophysical lineaments. On the other hand, the local maxima of the horizontal gradient made it possible to reveal the large structural features concerning the main tectonic events of the area.     

Robust approach for optimal positioning and ranking potential rainwater harvesting structure (RWH): a case study of Iraq

Rainwater harvesting (RWH) structure is considered as the best solution to conserve water for arid regions. The selection of RWH location is based on several key determinants such as hydrology, environment, topography, and socio-economic. This study proposed a robust methodology to identify and select the location of RWH using geographical information systems (GIS) and remote sensing (RS) with multi-criteria decision techniques in areas where data are scarce. Several thematic maps were extracted such as vegetation cover, soil group, slope, land use, and digital elevation (DEM). The RWH sites were ranked based on four major indexes: evaporation, cost-benefit, sediment, and hydrological index. Sensitivity analysis shows that the variance inverse (VI) and rank order method (ROM) considered all indices that effect ranking as compared to the analytic hierarchy process (AHP) and fuzzy-AHP. Sensitivity analysis also proved that the proposed method is suitable to be used for RWH site selection in arid regions.     

Retention of a heavy metal by marl collected from aquifer substratum

One of the objectives of this work is to characterize marl samples collected from the bedrock aquifer (at 30 m depth) of Wadi Al Ghoula located in Draria southwest of Algiers. The other objective is to make a kinetics study, linear and non-linear isotherm study, and mass transfer study of the adsorption of copper onto marl in aqueous solution. The fitness of kinetics and isotherm models was evaluated by using some error analysis function. One of the major results using an XRF technique is an evidence of the presence of calcite in the weight of 13.82%. The XRD patterns of these samples confirmed the presence of montmorillonite, kaolinite, illite, calcite, and quartz. On the other hand, the FTIR analysis clarified the presence of calcite. The specific surface area of 20,999 m²/g was obtained using the BET, which indicates that the material has a predominance for the mesoporous character. The instrumental neutron activation analysis (INAA), a nondestructive method, gives the elemental composition of the adsorbent. Based on the value of the coefficient of determination, the adsorption kinetics of copper in aqueous solution using marl as adsorbent follows the pseudo-second-order model. And according to the value of the coefficient of determination obtained for the two models, the intraparticle diffusion and liquid film diffusion control the process of adsorption of copper onto marl with low predominance for the second model of diffusion in the first stage of adsorption. The linear and the non-linear treatments of the two-parameter isotherm models (Langmuir, Freundlish, Temkin) show that the fitting best model of isotherm is the empirical Freundlish isotherm. For the three-parameter isotherm models (Toth, Sips, and Redlish-Peterson), the Sips model is the more accurate fitting model than the two other isotherms in the non-linear approach. Some error analysis functions are used to choose the best results.     

A nanoscopic hydro-thermo-mechanical model for nuclear waste shale/clay repositories

Shales or highly compacted engineered clay layers are being used as buffers in deep surface nuclear waste repositories. Due to the complex natural structure and fabric of clay and non-clay minerals associated with high in situ stresses, high temperatures, and the practical difficulties in the replication of the field stress and temperature conditions in the lab testing facilities, swell potential from the macro and micro investigations does not provide reliable and universally applicable results. In this study, a comprehensive molecular-level simulation-based volume change constitutive model has been developed for clay minerals incorporating the effects of cation exchange capacity, density, water content, in situ stress state, temperature, exchangeable-cations type and proportion, pore fluids, and the dissolved salts. The molecular simulations were performed using molecular mechanics, molecular dynamics, and Monte Carlo simulation techniques. Comparing the model predictions with the results of the lab tests, the model has been proven to be quite precise in the prediction of the swell potential of these strata under various overburden pressures and temperatures. There is several fold increase in swelling of clay samples at 80 °C as compared to the equivalent specimen tested at 25 °C. The effect of higher temperature is lesser at lower initial water content (higher density) while at higher water content (lower density) the structure has been found to be more vulnerable at higher temperatures. About 100 times higher confining pressure results in the same swell at 80 °C as in its counterpart specimen at 25 °C, the corresponding swell increase factor in case of 50 °C specimens is about 45. A sharp increase in swelling with a drop in in situ pressure emphasizes the probability of higher swell as a result of an accidental reduction in in situ pressure such as the higher concentration of nuclear reactions. In this study, the cohesive energy density (CED) was found to be highly sensitive to various volume change variables, such as water content, density, CEC, type, and percentage of exchangeable and non-exchangeable cations. Contrary to all the previous models, CED-based model developed in this study is universal in nature and can be adopted for any case with minimal basic material input parameters. The good agreement found between the predicted and real values for the swell potential of the undisturbed samples suggests that the model presented here can effectively be used for the assessment of the swelling potential of shale/clay deposits to be used as buffers to the nuclear waste storage.     

Assessment of physico-chemical and microbiological surface water quality using multivariate statistical techniques: a case study of the Wadi El-Bey River,Tunisia

Located in the northeastern part of Tunisia, Wadi El Bey drains the watershed through farmland, industrial, and urban areas of the region. It serves to discharge treated wastewater of different types. In this work, the variations of the water quality of Wadi El Bey were studied and evaluated, during 2 years (2012–2013), using multivariate statistical techniques such as principal component analysis (PCA) and cluster analysis (CA). In addition, the similarities or dissimilarities among the sampling points were as well analyzed to identify spatial and temporal variations. The results obtained based on the cluster analysis, led to identify three similar water quality zones: relatively polluted (LP), moderately polluted (MP), and highly polluted (HP). The inorganic and organic parameters, temperature, conductivity, dissolved oxygen, chemical oxygen demand, salmonella, and enterococcus, seemed to be the most significant parameters of water quality. Three factors were identified as responsible for the data structure, explaining 60.95% of the total variance. The first factor is the physical and non-organic chemical parameters explaining 23.48% of the total variance. The second and third factors are, respectively, the microbiological (21.26%) and organic-nutrient (16.2%).This study shows that multivariate statistical methods can help the water managers to understand the factors affecting the water quality.     

Characterization of some bacterial strains isolated from the Egyptian eastern and northern coastlines with antimicrobial activity of Bacillus zhangzhouensis OMER4

Marine microorganisms were considered to be important sources of marine bioactive compounds. The major objective of the study was to isolate and characterize bacteria with antimicrobial activities from the various marine environment of Egypt. In this respect, thirty-five bacterial isolates were recovered from sediment samples collected from different spots along the Egyptian Red Sea coastline and Alexandria coastline during the summer season of 2017 and 2018. According to the morphological, phys...     

Urban heat island and its effect on the cooling and heating demands in urban and suburban areas of Hong Kong

This study investigates the urban heat island characteristics of four major areas of Hong Kong. The areas of study include a densely populated and well-developed commercial area (i.e., Tsim Sha Tsui) and three suburban areas (i.e., Cheung Chau, Lau Fau Shan and Sha Tin) with differing degrees of development. The weather station data of respective areas were acquired from the Hong Kong Observatory. The urban heat island intensity, determined as the air-temperature difference between the selected urban/suburban area and the reference rural area (i.e., Ta Kuw Ling) with thin population and lush vegetation, was used for the analysis. Results showed stronger heat island effect during winter and nighttime than during summer and daytime. An investigation of the cooling and heating degree days indicate that all areas have observed higher number of cooling degree days. However, the cooling degree days were the maximum while heating degree days were the minimum in the urban area (i.e., Tsim Sha Tsui). Clearly, the minimum heating degree days and the maximum cooling degree days in the urban area were a direct consequence of urban heat island. The 10-year (i.e., from 1995 to 2005) average shows that Cheung Chau experienced the least number of cooling degree days while Lau Fau Shan experienced the highest number of heating degree days. Seemingly, the area of Cheung Chau offers better thermal comfort conditions with the minimum number of cooling and heating degree days.     

Mobility of arsenic and trace element inventories in sediment cores from Masuda City,southwestern Japan

The vertical distribution of arsenic and other trace and major elements has been studied in four sediment cores from Masuda City, Nagashima and Okite in the Shimane Prefecture of southwestern Japan. The sediment cores were also subjected to leaching techniques and ¹⁴C dating. The stratigraphic sequences in the cores consist of silt and sandy silt at top, passing downward into gray to black clays. Elevated values of As, Pb, Zn, Cu, Ni, Cr, and V are present in several horizons while abundances of these elements tend to be higher in the black and gray clays, probably due to adsorption onto clay sediments. Higher concentrations of Fe and total sulfur (TS) occur in black clays. The correlations of the trace metals with iron suggest their adsorption onto Fe (oxy)hydroxides, whereas correlations with sulfur in some cores indicate that they were precipitated as Fe-sulfides. Age determinations suggest that clay horizons at ∼5 m depth were deposited at around 5,000 and 6,000 years BP (¹⁴C ages) during the transgressive phase of sea level change. The results of the leaching techniques in the core samples show that higher amounts of As were extracted with deionized water. Even at neutral pH, As can be released from sediments to groundwater, and therefore groundwater pollution is a concern in Masuda City and the surrounding area.     

Natural zeolites enhance groundwater quality: evidences from Deccan basalts in India

The zeolite minerals characterized with hydrated aluminosilicates, negative ionic charge and 3D framework structure are well known for purifying the groundwater occurring in basaltic aquifer systems. However, the filtering mechanism at in situ field conditions is a complex process, which is rarely studied, and hence, it needs to be demonstrated. This paper explores the mechanism of hydrochemical processes and evolution of natural zeolites associated with basaltic rock to enhance groundwater quality. We present the hydrochemical findings and evolution processes derived from 46 groundwater samples (N_t = 46) belong to zeolitic (N_z = 25) and non-zeolitic (N_nz = 21) zones of a micro-watershed (4.4 km²) beset over basaltic terrain, Deccan Volcanic Province (DVP), India. The groundwater samples collected for one hydrological cycle (pre- and post-monsoons) are examined for major ion chemistry to determine the aqueous solution mechanism and ion-exchange process occurred in zeolitic and non-zeolitic zones. Further, the hydrochemical parameters are appraised by means of dominancy of ions, rock–water interactions, silicate weathering, chloro-alkaline indices, cation-exchange bivariate plots and the mechanism controlling groundwater chemistry. The results show that: 1) the purifying efficiency of zeolites for total ionic strength is observed as 63.85 and 68.58% during pre- and post-monsoons, respectively, 2) the significant reduction (36.51%) in total hardness attributed to the positive trend of chloro-alkaline indices depicting the ion-exchange phenomenon between Na⁺ and K⁺ (alkalies) and Ca²⁺ and Mg²⁺ (alkali-earth) elements in the zeolitic zone, 3) Gibbs plot shows the rock–water interaction as the predominant mechanism controlling groundwater chemistry in the zeolitic zone, and 4) the groundwater quality parameters from zeolitic zone are found within the permissible limit of WHO drinking water standards.