Fracture‐related intracrystalline transformation of olivine to ringwoodite in the shocked Sixiangkou meteorite

Abstract— Magnesium‐iron olivine in the Sixiangkou L6 chondrite contains abundant fractures induced by plastic deformation during shock metamorphism. This study reports the discovery of lamellar ringwoodite that incoherently nucleated and grew along planar and irregular fractures in olivine. Magnesium‐iron interdiffusion took place between olivine matrix and crystallizing ringwoodite at high pressures and high temperatures, which resulted in higher FeO content in ringwoodite lamellae than in olivine. This suggests that a quasi‐hydrostatic high pressure lasting for several minutes should have been produced in the shock veins of the meteorite. The intracrystalline transformation of olivine to ringwoodite also has implications for phase transitions in subducting lithospheric slabs because planar and irregular fractures are commonly produced in olivine that suffered plastic deformation.     

Implications of heterogeneous flood‐frequency distributions on traditional stream‐discharge prediction techniques

Traditional flood‐frequency analysis involves the assumption of homogeneity of the flood distribution. However, floods are often generated by heterogeneous distributions composed of a mixture of two or more populations. Differences between the populations may be the result of a number of factors, including seasonal variations in the flood‐producing mechanisms, changes in weather patterns resulting from low‐frequency climate shifts and/or El Niño/La Nina oscillations, changes in channel routing owing to the dominance of within‐channel or floodplain flow, and basin variability resulting from changes in antecedent soil moisture. Not recognizing these physical processes in conventional flood‐frequency analysis probably is the main reason that many frequency distributions do not provide an acceptable fit to flood data. In this paper, we use long‐term hydroclimatic records from the Gila River basin of south‐east and central Arizona in the USA to explore the extent and significance of mixed populations. First, we discuss the probable causes of heterogeneity in the frequency distribution of annual flood and present evidence of its occurrence. Second, we investigate the implications of using various popular homogeneous distributions for predicting peak flows for basins that exhibit mixed population characteristics. Third, we demonstrate how alternative frequency models that explicitly account for floods generated by a mixture of two or more populations are both hydrologically and statistically more appropriate. We illustrate how the selection of the most plausible distribution for flood‐frequency analysis also should be based on hydrological reasoning as opposed to the sole application of the traditional statistical goodness‐of‐fit tests. Copyright © 2002 John Wiley & Sons, Ltd.     

Investigation on the effective remediation of quinoline at solid/solution interface using modified agricultural waste: an inclusive study

This research work explores the potential of modified agricultural waste for the sorption of quinoline from aqueous media. A quinoline removal efficiency of around 97 % and sorption capacities of ~20 (batch) and ~35 mg g^?1 (fixed-bed) were achieved. Pseudo-second-order kinetics and Temkin isotherm best represented the equilibrium sorption data. The sorption of quinoline is exothermic and spontaneous in nature with a slight increase in the system entropy. The quinoline sorption mechanism is controlled by H-bonding, π–π dispersive interactions, boundary layer, and intraparticle diffusion. Microwave–chemical integrated regeneration technique retrieves the sorption capacity of the exhausted sorbent with 99.15, 97.64, and 95.55 % of the original, in three sorption–regeneration cycles. Energy recovery (19.365 MJ kg^?1) from the quinoline-loaded sorbent and the potential utilization of left-over ash materials enhanced the prospective of the sorbent for the remediation of pollutants for a clean and green environment.     

Investigation of recharge dynamics and flow paths in a fractured crystalline aquifer in semi-arid India using borehole logs: implications for managed aquifer recharge

The recharge flow paths in a typical weathered hard-rock aquifer in a semi-arid area of southern India were investigated in relation to structures associated with a managed aquifer recharge (MAR) scheme. Despite the large number of MAR structures, the mechanisms of recharge in their vicinity are still unclear. The study uses a percolation tank as a tool to identify the input signal of the recharge and uses multiple measurements (piezometric time series, electrical conductivity profiles in boreholes) compared against heat-pulse flowmeter measurements and geochemical data (major ions and stable isotopes) to examine recharge flow paths. The recharge process is a combination of diffuse piston flow and preferential flow paths. Direct vertical percolation appears to be very limited, in contradiction to the conceptual model generally admitted where vertical flow through saprolite is considered as the main recharge process. The horizontal component of the flow leads to a strong geochemical stratification of the water column. The complex recharge pattern, presented in a conceptual model, leads to varied impacts on groundwater quality and availability in both time and space, inducing strong implications for water management, water quality evolution, MAR monitoring and longer-term socio-economic costs.     

Natural and human-induced sinkhole hazards in Saudi Arabia: distribution,investigation, causes and impacts

Approximately 60 % of the 2,150,000 km² area of Saudi Arabia is underlain by soluble sediments (carbonate and evaporite rock formations, salt diapirs, sabkha deposits). Despite its hyper-arid climate, a wide variety of recent sinkholes have been reported in numerous areas, involving significant property losses. Human activities, most notably groundwater extraction, have induced unstable conditions on pre-existing cavities. This work provides an overview of the sinkhole hazard in Saudi Arabia, a scarcely explored topic. It identifies the main karst formations and the distribution of the most problematic sinkhole areas, illustrated through several case studies covering the wide spectrum of subsidence mechanisms. Some of the main investigation methods are presented through selected examples, including remote sensing, trenching and geophysics. Based on the available data, the main causal factors are identified and further actions that should be undertaken to better assess and manage the risk are discussed.     

Magmatism at continental passive margins inferred from Ambient‐Noise Phase‐velocity in the Gulf of Aden

Non‐volcanic continental passive margins have traditionally been considered to be tectonically and magmatically inactive once continental breakup has occurred and seafloor spreading has commenced. We use ambient‐noise tomography to constrain Rayleigh‐wave phase‐velocity maps beneath the eastern Gulf of Aden (eastern Yemen and southern Oman). In the crust, we image low velocities beneath the Jiza‐Qamar (Yemen) and Ashawq‐Salalah (Oman) basins, likely caused by the presence of partial melt associated with magmatic plumbing systems beneath the rifted margin. Our results provide strong evidence that magma intrusion persists after breakup, modifying the composition and thermal structure of the continental margin. The coincidence between zones of crustal intrusion and steep gradients in lithospheric thinning, as well as with transform faults, suggests that magmatism post‐breakup may be driven by small‐scale convection and enhanced by edge‐driven flow at the juxtaposition of lithosphere of varying thickness and thermal age.     

Utilization of low quality water of mountain reservoirs: a case study from Al Jabal Al Akhdar,Oman

Al Jabal al Akhdar (Green Mountain) in arid northern Oman has freshwater resources that had supported small communities for hundreds of years. Jabal Akhdar receives more rainfall (300-400 mm) when compared to the desert plains. In the last few years, this region had undergone enormous changes due to rapid development. The resident and transient populations have increased and their activities exert severe stress on the water resources. There are 24 retention reservoirs in the area, but most are eutrophic and the nutrient loading is due to input of animal fecal matter via surface run-off. As expected, these waters contaminated with coliform bacteria and some have pathogenic Escherichia coli. Drinking water needs of all the villages met by groundwater extraction. Because of poor quality, the surface water in the reservoirs is under-utilized. A low-cost low-maintenance treatment system designed, constructed and operated in one village to clean the reservoir water for non-drinking human use. The treatment unit improved the water quality parameters. A survey among the adult male population of the village showed their eagerness to adopt this system and use the treated reservoir water for uses other than agriculture. Establishment of these treatment units in other villages should reduce the pressures on groundwater extraction.     

Mesoscale analysis of failure in quasi‐brittle materials: comparison between lattice model and acoustic emission data

The purpose of this paper is to analyse the development and the evolution of the fracture process zone during fracture and damage in quasi‐brittle materials. A model taking into account the material details at the mesoscale is used to describe the failure process at the scale of the heterogeneities. This model is used to compute histograms of the relative distances between damaged points. These numerical results are compared with experimental data, where the damage evolution is monitored using acoustic emissions. Histograms of the relative distances between damage events in the numerical calculations and acoustic events in the experiments exhibit good agreement. It is shown that the mesoscale model provides relevant information from the point of view of both global responses and the local failure process. © 2015 The Authors. International Journal for Numerical and Analytical Methods in Geomechanics published by John Wiley & Sons Ltd.