Stream Sediments Geochemical Exploration in the Northwestern Part of Wadi Allaqi Area, South Eastern Desert, Egypt

Geochemical stream sediments survey was conducted in the northwestern part of Wadi Allaqi area, Eastern Desert, Egypt. The area comprises Precambrian metasediments, intermediate metavolcanics, gabbro, and serpentinites, with intrusive masses of granites and quartz-porphyry and invaded by several quartz veins. The −1.0-mm size fraction is analyzed for As, Cu, S, Mo, Pb, Zn, Co, Ni, Rb, Ba, Sr, Nb, V, U, Th, Cr, Zr, La, Ce, Nd, and Y. The geochemical survey is supported by heavy minerals study in the −0.125 + 0.0625-mm fraction. The geochemical data were statistically investigated using Q-mode cluster and R-mode factor analyses as well as the enrichment factor. Factors 1 (Zr, Nb, Nd, La, and Y), 2 (V, Sr, and Zn), and 4 (Ba and Rb) are mainly controlled by the lithological characters of the rocks hosting Au-sulfide mineralizations and their accompanied hydrothermal alteration zones. In the mineralization Factor 3 (Cu, S, As, Ce, and Mo), arsenic, Cu, S, and Mo are direct indicators, while Ce is indirect one for the Au-sulfide mineralizations. The Cu–S–As–Mo association with Pb and Zn anomalies in the stream sediments draining the quartz-porphyry point to its porphyry copper mineralization. Cobalt and Ni (Factor 5) are pathfinders for the Fe- and Cu-sulfides, whereas Zn and Pb of Factor 8 are additional pathfinders for the Au-sulfide mineralizations. The southern stream sediments having high U/Th ratios with U–Mo association and draining granites traversed by pegmatites, as well as the stream sediments draining Um Garayat area and the quartz-porphyry stock with high abundance of monazite, zircon, epidote, sphene, and ilmenite, could signify sources of U and Th (Factor 7). Two watershed areas have distinct enrichment factors for arsenic suggesting unexplored extensions of Au-sulfide mineralization linked to the Allaqi shear-zone. The enrichment of the mineralization Factor 3 in the drainage system is mainly controlled by the prevailed mechanical dispersion for the hosting heavy minerals in such arid region with minor role of hydromorphic dispersion. The chemistry and mineralogy of the stream sediments are evidently allied to the drained bedrocks and their hosted mineralizations that signify a promising area for detailed exploration.     

Analytical treatment of the two-body problem with slowly varying mass

The present work is concerned with the two-body problem with varying mass in case of isotropic mass loss from both components of the binary systems. The law of mass variation used gives rise to a perturbed Keplerian problem depending on two small parameters. The problem is treated analytically in the Hamiltonian frame-work and the equations of motion are integrated using the Lie series developed and applied, separately by Delva (1984) and Hanslmeier (1984). A second order theory of the two bodies eject mass is constructed, returning the terms of the rate of change of mass up to second order in the small parameters of the problem.     

Coordination of Cd ions in the internal pore system of zeolite-X: A combined EXAFS and isotopic exchange study

The effect of prolonged contact time (up to 130 days) on the immobilization of Cd by sorption to calcium exchanged zeolite-X (CaX), under environmentally relevant conditions, was studied using both isotopic exchange and extended X-ray absorption fine structure spectroscopy (EXAFS). Sorption and isotopic exchange measurements revealed time-dependent Cd sorption and indicated the movement of Cd²⁺ ions into less accessible sites due to ageing. EXAFS suggested progressive fixation of Cd in the double six-ring (D6R) unit of the CaX structure. Proportional allocation of the apparent Cd-Si bond distance to two ‘end-members’, across all contact times, indicated that the bond distance for labile Cd was 3.41 Å and for non-labile (or fixed) Cd was 3.47 Å.     

Structural elements and incremental strain history of the basement rocks of Um Had area, central Eastern Desert, Egypt

The Um Had area, central Eastern Desert, Egypt shows a regional stretching in the NW–SE and a contraction in the NE–SW direction. Major NW–SE folds, small recumbent folds, and local thrusts and reverse faults were recognized. Complicated relation between folds and boudinage was identified. This stretching amount ranges from 1.282 to 1.309. Earlier coaxial and later non-coaxial strains were inferred. The change from axial to non-coaxial stress regime was gradual and the latter was associated with minor clockwise and anticlockwise rotation of structural elements. During the non-coaxial strain, strain fringes were formed as a consequence of the high circulation of fluids in low temperature and high pressure conditions. Superimposed strain fringes indicating right- and left-lateral senses of movement were recognized. At least three generations of fringes were recognized, implying three stages of non-coaxial stretching. Each generation has about 15 increments which show irregular strain gradient and intensity over the different increments. Eastwards, the strain increments became mature and westwards, the finite strain increases. The strongest finite strain was found in a narrow belt delimiting the basement rocks on the west and underlying the Phanerozoic sediments. Chocolate-tablet structure was recorded and indicates later multidirectional tension. Not all Nubia Sandstone exposures are overlying the basement rocks and some are separated by NW–SE normal faults. Major NW–SE normal faults are cutting basement rocks of different ages.     

Generation and expulsion of oils from Permian coals of the Sydney Basin,Australia

Organic geochemical and petrological assessment of coals/coaly shales and fine grained sediments, coupled with organic geochemical analyses of oil samples, all from Permo–Triassic sections of the Southern Sydney Basin (Australia), have enabled identification of the source for the widely distributed oil shows and oil seeps in this region. The Permian coals have higher hydrogen indices, higher liptinite contents, and much higher total organic matter extract yields than the fine grained sediments. A variety of source specific parameters obtained from n-alkanes, regular isoprenoids, terpanes, steranes and diasteranes indicate that the oil shows and seeps were generated and expelled predominantly from higher plant derived organic matter deposited in oxic environments. The source and maturity related biomarkers and aromatic hydrocarbon distributions of the oils are similar to those of the coals. The oil-coal relationship also is demonstrated by similarities in the carbon isotopic composition of the total oils, coal extracts, and their individual n-alkanes. Extracts from the Permo–Triassic fine grained sediments, on the other hand, have organic geochemical signatures indicative of mixed terrestrial and prokaryotic organic matter deposited in suboxic environments, which are significantly different from both the oils and coal extracts. The molecular signatures indicating the presence of prokaryotic organic matter in some of the coal extracts and oils may be due to thin sections of possibly calcareous lithologies interbedded within the coal measures. The genetic relationship between the oils and coals provides new evidence for the generation and expulsion of oils from the Permian coals and raises the possibility for commercial oil accumulations in the Permian and Early Triassic sandstones, potentially in the deeper offshore part of the Sydney Basin.     

Comparative analysis of real-time precise point positioning zenith total delay estimates

The continuous evolution of global navigation satellite systems (GNSS) meteorology has led to an increased use of associated observations for operational modern low-latency numerical weather prediction (NWP) models, which assimilate GNSS-derived zenith total delay (ZTD) estimates. The development of NWP models with faster assimilation cycles, e.g., 1-h assimilation cycle in the rapid update cycle NWP model, has increased the interest of the meteorological community toward sub-hour ZTD estimates. The suitability of real-time ZTD estimates obtained from three different precise point positioning software packages has been assessed by comparing them with the state-of-the-art IGS final troposphere product as well as collocated radiosonde (RS) observations. The ZTD estimates obtained by BNC2.7 show a mean bias of 0.21 cm, and those obtained by the G-Nut/Tefnut software library show a mean bias of 1.09 cm to the IGS final troposphere product. In comparison with the RS-based ZTD, the BNC2.7 solutions show mean biases between 1 and 2 cm, whereas the G-Nut/Tefnut solutions show mean biases between 2 and 3 cm with the RS-based ZTD, and the ambiguity float and ambiguity fixed solutions obtained by PPP-Wizard have mean biases between 6 and 7 cm with the references. The large biases in the time series from PPP-Wizard are due to the fact that this software has been developed for kinematic applications and hence does not apply receiver antenna eccentricity and phase center offset (PCO) corrections on the observations. Application of the eccentricity and PCO corrections to the a priori coordinates has resulted in a 66 % reduction of bias in the PPP-Wizard solutions. The biases are found to be stable over the whole period of the comparison, which are criteria (rather than the magnitude of the bias) for the suitability of ZTD estimates for use in NWP nowcasting. A millimeter-level impact on the ZTD estimates has also been observed in relation to ambiguity resolution. As a result of a comparison with the established user requirements for NWP nowcasting, it was found that both the G-Nut/Tefnut solutions and one of the BNC2.7 solutions meet the threshold requirements, whereas one of the BNC2.7 solution and both the PPP-Wizard solutions currently exceed this threshold.