Morphotectonic controls of groundwater flow regime and relating environmental impacts in Northwest Sinai,Egypt

The frequent appearance of some hydro-environmental hazard features, such as waterlogging and soil salinization along the susceptible zones at Northwest Sinai area (NWSA), has put serious challenges and obstacles for a correct and efficient land use planning of this region, for several decades. Although previous studies have shown that the whole region of Northern Sinai is greatly affected by the tectonic movements associated with the Syrian Arc folding system (SAS), NWSA is barren of any obvious surficial structures. The current work aims to investigate the effect of subsurface tectonic features on the hydrogeologic regime of NWSA.Hydrogeological and remote sensing data were integrated with ground geophysical gravity and magnetic measurements, using the geographic information system. Data integration asserts the role played by buried tectonic features not only in governing the landforms of the upper water-bearing quaternary formations but also in controlling their flow regime.Two major subsurface structures were identified through interpreting the geophysical measurements. A buried dome-like structure, dominating the central part of the mapped area, coincides with the radial flow pattern observed on the water table map. At the southwestern corner of the study area, an elevated groundwater level, caused by continuous groundwater accumulation at the discharge boundary, is superimposing a subsurface block-faulted depression. The waterlogging features (saturation of the soil by groundwater and inundation of local depressions due to rising of water table) dominating the discharge lowlands of NWSA support the conclusion that a buried block-faulted structure exerts a strong influence on the thickness and groundwater flow regime of the shallow quaternary aquifer.     

Uncertainty assessment of the multilayer perceptron (MLP) neural network model with implementation of the novel hybrid MLP-FFA method for prediction of biochemical oxygen demand and dissolved oxygen: a case study of Langat River

Accurate prediction of the chemical constituents in major river systems is a necessary task for water quality management, aquatic life well-being and the overall healthcare planning of river systems. In this study, the capability of a newly proposed hybrid forecasting model based on the firefly algorithm (FFA) as a metaheuristic optimizer, integrated with the multilayer perceptron (MLP-FFA), is investigated for the prediction of monthly water quality in Langat River basin, Malaysia. The predictive ability of the MLP-FFA model is assessed against the MLP-based model. To validate the proposed MLP-FFA model, monthly water quality data over a 10-year duration (2001–2010) for two different hydrological stations (1L04 and 1L05) provided by the Irrigation and Drainage Ministry of Malaysia are used to predict the biochemical oxygen demand (BOD) and dissolved oxygen (DO). The input variables are the chemical oxygen demand (COD), total phosphate (PO₄), total solids, potassium (K), sodium (Na), chloride (Cl), electrical conductivity (EC), pH and ammonia nitrogen (NH₄-N). The proposed hybrid model is then evaluated in accordance with statistical metrics such as the correlation coefficient (r), root-mean-square error, % root-mean-square error and Willmott’s index of agreement. Analysis of the results shows that MLP-FFA outperforms the equivalent MLP model. Also, in this research, the uncertainty of a MLP neural network model is analyzed in relation to the predictive ability of the MLP model. To assess the uncertainties within the MLP model, the percentage of observed data bracketed by 95 percent predicted uncertainties (95PPU) and the band width of 95 percent confidence intervals (d-factors) are selected. The effect of input variables on BOD and DO prediction is also investigated through sensitivity analysis. The obtained values bracketed by 95PPU show about 77.7%, 72.2% of data for BOD and 72.2%, 91.6% of data for DO related to the 1L04 and 1L05 stations, respectively. The d-factors have a value of 1.648, 2.269 for BOD and 1.892, 3.480 for DO related to the 1L04 and 1L05 stations, respectively. Based on the values in both stations for the 95PPU and d-factor, it is concluded that the neural network model has an acceptably low degree of uncertainty applied for BOD and DO simulations. The findings of this study can have important implications for error assessment in artificial intelligence-based predictive models applied for water resources management and the assessment of the overall health in major river systems.     

Status of sedimentation in King Talal Dam,case study from Jordan

This paper focuses on characterizing the current status of physical and chemical characteristics of King Talal Dam (KTD) sediments. The quality of sediments was investigated based on several international sediment quality guidelines. The volume of sediment and sedimentation rate in (KTD) was also estimated. Five types of granulometric textural facies were observed for the sediments of KTD reservoir bed, with an average grain size distribution of gravel (1.38%), sand (32.38%), silt (32.35%) and clay (32.38%). The fraction of <63 micron showed that the total mean size was 8.0 micron. Other sediment parameters in KTD were 7.0% for total organic matter (TOM), 7.3 for pH, 35.9% for CaCO₃ and 100.5 meq/100 g for cation exchange capacity, with dominant mineralogical constituents of quartz, calcite, dolomite, clay minerals and minor feldspar. The total concentrations of F, Cl, NO₂, NO₃, PO₄ and SO₄ in sediment samples were lower inward for KTD. The vast majority of trace metals in sediments were generally within the standard limits recommended for soils. TOM and grain size of sediment are major factors governing the trace metal concentrations. The calculated geoaccumulation index (I _geo) and enrichment factor of metals in bottom sediments showed that the metals were in the following order: Cd > Pb > Zn > Co > Cr > Ni > Fe > Cu > Sr > Mn and Cd > Zn > Pb > Co > Cr > Ni > Cu > Sr > Mn, respectively. Based on the sonic survey of KTD reservoir, the annual sedimentation rate was about 0.4061 MCM/year, in which about 18.66% of the reservoir initial storage capacity was lost to sediments and a projected lifespan of about 198 years.     

Determining shallow aquifer vulnerability by the DRASTIC model and hydrochemistry in granitic terrain,southern India

Shallow aquifer vulnerability has been assessed using GIS-based DRASTIC model by incorporating the major geological and hydrogeological factors that affect and control the groundwater contamination in a granitic terrain. It provides a relative indication of aquifer vulnerability to the contamination. Further, it has been cross-verified with hydrochemical signatures such as total dissolved solids (TDS), \(\hbox {Cl}^{-},\, \hbox {HCO}_{3}^{-},\, \hbox {SO}_{4}^{2-}\) and \(\hbox {Cl}^{-}/\hbox {HCO}_{3}^{-}\) molar ratios. The results show four zones of aquifer vulnerability (i.e., negligible, low, moderate and high) based on the variation of DRASTIC Vulnerability Index (DVI) between 39 and 132. About 57% area in the central part is found moderately and highly contaminated due to the 80 functional tannery disposals and is more prone to groundwater aquifer vulnerability. The high range values of TDS (2304–39,100 mg/l); \(\hbox {Na}^{+}\)(239– 6,046 mg/l) and \(\hbox {Cl}^{-}\) (532–13,652 mg/l) are well correlated with the observed high vulnerable zones. The values of \(\hbox {Cl}^{-}/\hbox {HCO}_{3}^{-}\) (molar ratios: 1.4–106.8) in the high vulnerable zone obviously indicate deterioration of the aquifer due to contamination. Further cumulative probability distributions of these parameters indicate several threshold values which are able to demarcate the diverse vulnerability zones in granitic terrain.     

Wrench structural deformation in Ras Al Hilal-Al Athrun area, NE Libya: a new contribution in Northern Al Jabal Al Akhdar Belt

Al Jabal Al Akhdar is a NE/SW- to ENE/WSW-trending mobile part in Northern Cyrenaica province and is considered a large sedimentary belt in northeast Libya. Ras Al Hilal-Al Athrun area is situated in the northern part of this belt and is covered by Upper Cretaceous–Tertiary sedimentary successions with small outcrops of Quaternary deposits. Unmappable and very restricted thin layers of Palaeocene rocks are also encountered, but still under debate whether they are formed in situ or represent allochthonous remnants of Palaeocene age. The Upper Cretaceous rocks form low-lying to unmappable exposures and occupy the core of a major WSW-plunging anticline. To the west, south, and southeast, they are flanked by high-relief Eocene, Oligocene, and Lower Miocene rocks. Detailed structural analyses indicated structural inversion during Late Cretaceous–Miocene times in response to a right lateral compressional shear. The structural pattern is themed by the development of an E–W major shear zone that confines inside a system of wrench tectonics proceeded elsewhere by transpression. The deformation within this system revealed three phases of consistent ductile and brittle structures (D₁, D₂, and D₃) conformable with three main tectonic stages during Late Cretaceous, Eocene, and Oligocene–Early Miocene times. Quaternary deposits, however, showed at a local scale some of brittle structures accommodated with such deformation and thus reflect the continuity of wrenching post-the Miocene. D₁ deformation is manifested, in Late Cretaceous, via pure wrenching to convergent wrenching and formation of common E- to ENE-plunging folds. These folds are minor, tight, overturned, upright, and recumbent. They are accompanied with WNW–ESE to E–W dextral and N–S sinistral strike-slip faults, reverse to thrust faults and pop-up or flower structures. D₂ deformation initiated at the end of Lutetian (Middle Eocene) by wrenching and elsewhere transpression then enhanced by the development of minor ENE–WSW to E–W asymmetric, close, and, rarely, recumbent folds as well as rejuvenation of the Late Cretaceous strike-slip faults and formation of minor NNW–SSE normal faults. At the end of Eocene, D₂ led to localization of the movement within E–W major shear zone, formation of the early stage of the WSW-plunging Ras Al Hilal major anticline, preservation of the contemporaneity (at a major scale) between the synthetic WNW–ESE to E–W and ENE–WSW strike-slip faults and antithetic N–S strike-slip faults, and continuity of the NW–SE normal faults. D₃ deformation is continued, during the Oligocene-Early Miocene, with the appearance of a spectacular feature of the major anticline and reactivation along the E–W shear zone and the preexisting faults. Estimating stress directions assumed an acted principal horizontal stress from the NNW (N33°W) direction.     

Geology and Genesis of Barite Deposits of Lasbela and Khuzdar Districts, Balochistan, Pakistan

Abstract: Geology and genesis of the sediment-hosted barite deposits in the Lasbela and Khuzdar districts of Balochistan, Pakistan have been studied and described. Hot solutions generated in rifting environments during the initial stage of separation of the continental crustal block related to the Gondwanaland fragmentation subsequently reposed in Jurassic rocks, most probably played an important role on barite formation.
Paragenetic relationships indicate that the period of barite mineralization was distinctly later than that of zinc-lead sulphide mineralization in the Lasbela and Khuzdar districts. The barite deposits occur on top and in peripheral to the zinc-lead sulphides. The earliest barite mineralization took place in the clastic rock sequence of the lower Spingwar Formation as cross cutting veins. Younger mineralization as stratabound-replacement type occurred within the platform limestones of Loralai Formation, just above the Spingwar Formation. The youngest mineralization as stratiform is hosted within black shales, mudstones and argillaceous limestones of Anjira Formation at the top of Loralai Formation. In the light of the evidences gathered from field and laboratory investigations a genetic model has been deduced.     

Electronic waste: present status and future perspectives of sustainable management practices in Malaysia

The ever-increasing and rapidly growing volume of waste electrical and electronic equipment has become a serious threat to the environment in many countries. The inevitability of e-waste management and the development of a holistic system to deal with it has become an indispensable socio-economic and environmental issue for the sustainable development of Malaysia. However, no comprehensive research has yet been carried out, and only a few works in a discreet manner have been begun. In view of the above, and as a small endeavor towards achieving the country’s Vision 2020, this study explores the present status and future perspectives of the management of waste electrical and electronic equipment in Malaysia. This article presents an overview of e-waste management practices around the world, including the generation of e-waste, the implementation of management strategies, and collection and recovery activities in Malaysia. It also presents the corresponding responses adopted so far with respect to legislation and other infrastructural development. Finally, through the use of structured and semi-structured interviews, it reveals the barriers and challenges, as well as future perspectives and sustainability issues related to the e-waste management system in this fast developing country.     

Study of Aerosol Direct and Indirect Effects and Auto-conversion Processes over the West African Monsoon Region Using a Regional Climate Model

This study assesses the direct and indirect effects of natural and anthropogenic aerosols(e.g., black carbon and sulfate)over West and Central Africa during the West African monsoon(WAM) period(June–July–August). We investigate the impacts of aerosols on the amount of cloudiness, the influences on the precipitation efficiency of clouds, and the associated radiative forcing(direct and indirect). Our study includes the implementation of three new formulations of auto-conversion parameterization [namely, the Beheng(BH), Tripoli and Cotton(TC) and Liu and Daum(R6) schemes] in Reg CM4.4.1,besides the default model's auto-conversion scheme(Kessler). Among the new schemes, BH reduces the precipitation wet bias by more than 50% over West Africa and achieves a bias reduction of around 25% over Central Africa. Results from detailed sensitivity experiments suggest a significant path forward in terms of addressing the long-standing issue of the characteristic wet bias in Reg CM. In terms of aerosol-induced radiative forcing, the impact of the various schemes is found to vary considerably(ranging from-5 to-25 W m~(-2)).