Factor and cluster analysis of water quality data of the groundwater wells of Kushtia, Bangladesh: Implication for arsenic enrichment and mobilization

The study area is located in the southwestern part of Bangladesh. Twenty-six groundwater samples were collected from both shallow and deep tube wells ranging in depth from 20 to 60 m. Multivariate statistical analyses including factor analysis, cluster analysis and multidimensional scaling were applied to the hydrogeochemical data. The results show that a few factors adequately represent the traits that define water chemistry. The first factor of Fe and HCO₃ is strongly influenced by bacterial Fe (III) reduction which would raise both Fe and HCO₃ concentrations in water. Na, Cl, Ca, Mg and PO₄ are grouped under the second factor representing the salinity sources of waters. The third factor, represented by As, Mn, SO₄ and K is related to As mobilization processes. Cluster analysis has been applied for the interpretation of the groundwater quality data. Initially Piper methods have been employed to obtain a first idea on the water types in the study area. Hierarchical cluster analysis was carried out for further classification of water types in the study area. Twelve components, namely, pH, Fe, Mn, As, Ca, Mg, Na, K, HCO₃, Cl, SO₄ and NO₃ have been used for this purpose. With hierarchical clustering analysis the water samples have been classified into 3 clusters. They are very high, high and moderately As-enriched groundwater as well as groundwater with elevated SO₄.     

Factors controlling mechanisms of groundwater salinization and hydrogeochemical processes in the Quaternary aquifer of the Eastern Nile Delta, Egypt

In this study, combining interpretations of conservative dissolved ions and environmental isotopes in water were used to investigate the main factors and mechanisms controlling groundwater salinization and hydrogeochemical processes in the Eastern Nile Delta, Egypt. Hydrogeochemical and isotopic study has been carried out for 61 water samples from the study area. Total dissolved solid (TDS) contents of groundwater are highly variable rising along flowpath from the south (410 mg/L) to the north (14,784 mg/L), implying significant deterioration and salinization of groundwater. Based on TDS and ionic ratios, groundwater samples were classified into three groups. In low-saline groups, water chemistry is greatly influenced by cation exchange, mineral dissolution/precipitation, anthropogenic pollutants and mixing with surface water. Whilst, in high-saline groups, water chemistry is affected by salt-water intrusion, reverse cation exchange and evaporation. The chemical constituents originating from saline water sources, reverse ion exchange and mineral dissolution are successfully differentiated using ionic delta and saturation index approaches. The δ¹⁸O–δ²H relationship plots on a typical evaporation line, suggesting potential evaporation of the recharging water prior to infiltration. Isotope evidence concludes that the groundwater have been considerably formed by mixing between depleted meteoric water recharged under different climatic conditions and recently infiltrating enriched surface water and excess of irrigation water. The δ¹⁸O data in conjunction with chloride concentrations provide firm evidence for impact of dissolution of marine-origin evaporite deposits, during past geologic periods, on groundwater salinity in the northern region. Moreover, the relation between ¹⁴C activities and Cl^? concentration confirms this hypothesis.     

Hydrogeophysical study for additional groundwater supplies in El Heiz Area, Southern part of El Bahariya Oasis, Western Desert, Egypt

El Bahariya Oasis is a part of the great groundwater reservoir of the Western Desert of Egypt. The different stratigraphic units, the water-bearing zones, aquifer potentiality conditions, and the favorable locations for drilling new wells were evaluated by carrying out 24 Schlumberger vertical electrical soundings (VESs), along with the data of some wells drilled in the near vicinity of the measuring sites. The results of the interpreted field data revealed the presence of ten distinctive subsurface geoelectric layers; a thin surface, dry loose sand and gravel, sandy clay and shale interclations, saturated coarse sand layer, shale and clay, and saturated fine sandstone and saturated coarse sandstone. The aquifer is a multilayer aquifer with different thicknesses represented by the fourth, sixth, eighth, and tenth geoelectric layers. Results also revealed that the thicknesses of the water-bearing horizons increase towards the east direction, consequently the aquifer potentiality increases. Therefore, the best production well locations are in that direction. Depth to water starts from 40 m at VES no. 14 and increases gradually toward the east to reach 66 m at VES no. 5. Hydrogeochemical analysis of two groundwater samples taken from Ein El Ezza and well no. 2 showed that groundwater in the study area is suitable for agricultural purposes but not for human consumption due to the high iron content. Recommendations concerning site selection for drilling new productive groundwater wells are given.     

Site amplification investigation in Dhaka, Bangladesh, using H/V ratio of microtremor

The degree of damage during earthquakes strongly depends on dynamic characteristics of buildings as well as amplification of seismic waves in soils. Among the other approaches, microtremor is, perhaps, the easiest and cheapest way to understand the dynamic characteristics of soil. Non-reference microtremor measurements have been carried out in 45 locations in and around the capital Dhaka city of Bangladesh. Subsoil investigations (Standard Penetration Test and Shear Wave Velocity) have also been executed in those locations. Soil model has been developed for those locations for site response analysis by means of the program SHAKE. Among those 45 locations, predominant frequency of microtremor observation varies from 0.48 to 3.65 Hz. Out of those 45, for 35 locations Transfer function obtained from the program SHAKE have higher frequency compared to microtremor H/V ratio and for one location it has lower predominant frequency. For six locations, frequencies obtained from two methods are identical. For three other locations, there are no similarities between predominant frequency obtained from microtremor and transfer function. The seismic Vulnerability Index (Kg) for 45 sites varies between 0.45 and 31.85. Ten sites have been identified as having moderate vulnerability of soil layers to deform.     

Red Sea faulting and salt diapirism as a potential geotechnical hazard in Jazan,southwest Saudi Arabia: inferences from gravity data

Natural Hazards - The main objective of this study is to detect the subsurface extension of salt diapirs and structural deformations in the city of Jazan and its suburbs using gravity data. Salt...     

Mineralogy and geochemistry of fine-grained Dahab stream sediments,Southeastern Sinai,Egypt: emphasis on the intergrowths of Fe–Ti oxides

Acta Geochimica - Mineralogical and geochemical characteristics of stream sediments collected from 30 stations in the Dahab-Wadi Kid area (southeastern Sinai, Egypt) are presented. The studied...     

Discovery of lamproites near Vattikod Area, NW margin of the Cuddapah basin, Eastern Dharwar craton, southern India

A cluster of lamproite dykes are located 1 km west of Vattikod village at the NW margin of the Cuddapah basin, Eastern Dharwar craton, southern India, during the pursuit for locating primary diamond source rocks by adapting multifarious applications. These exotic rocks are emplaced along WNW-ESE to NW-SE trending fractures in the granitic rocks belonging to the Peninsular Gneissic Complex. Ten out of twelve lamproites occur near Vattikod village and one each is located in the vicinity of Marepalli and Gundrapalli villages respectively. These lamproites, though highly altered, contain microphenocrysts of altered olivine, clinopyroxene, phlogopite, leucite and sanidine and translucent to opaque, amoeboid shaped patches of glass set in a groundmass rich in carbonate, phlogopite, serpentine, and chlorite. This new cluster of lamproites constitutes a part of the recently discovered Ramadugu lamproite field. The Vattikod and Ramadugu lamproites, together with those from Krishna lamproite field and the Cuddapah basin, constitute, a wide spectrum of ultrapotassic magmatism emplaced in and around the Palaeo-Mesoproterozoic Cuddapah basin in southern India.     

Electrochemical studies of sulphides,I. The electrocatalytic activity of galena,pyrite and cobalt sulphide for oxygen reduction in relation to xanthate adsorption and flotation

The electrocatalytic activity of galena, pyrite and Co₃S₄ for oxygen reduction has been studied by potentiostatic methods. Open circuit potentials of the sulphide electrodes have also been measured as a function of pH in nitrogen, air and oxygen atmospheres and also in the presence of H₂O₂ and ethyl xanthate. The adsorption of xanthate on sulphides was followed by observing bubble attachment to the electrodes.The catalytic activity for oxygen (or H₂O₂) reduction (the cathodic currents), the electrode potentials and the xanthate adsorption as shown by bubble attachment within certain pH limits, all varied as $\text{Co}{}_3\text{S}{}_4\text{> pyrite (≈ PbS in H}{}_2\text{O}{}_2\text{) ? PbS}$ indicating considerable dependence of the redox processes in flotation on the d - electron character of the sulphides.In the absence of oxygen, xanthate is probably bonded to the water structure of the surface through hydrogen-bonding, thus keeping the surface hydrophilic. Such adsorption reduces the electrode potential and inhibits oxygen reduction.     

Hydrothermal alteration and evolution of Zr-Th-U-REE mineralization in the microgranite of Wadi Ras Abda,North Eastern Desert,Egypt

Ras Abda plutonic suite, North Eastern Desert of Egypt, consists predominantly of Neoproterozoic calc-alkaline older granites. Minor exposures of pink microgranite are occurring along Wadi Ras Abda within the older granites. Previous studies on this area demonstrated that the microgranite is altered in some parts and contains anomalous concentrations of rare metal elements (Zr, Th, and U). These altered and mineralized zones are re-assessed using field observations, chemical analysis, and by the application of various transmitted light and electron microscopic techniques. The rare metals exist as mineral segregation grew freely into open cavities of the microgranite and concordant with the NNE strike-slip fault movement. The mineralized zones contain an assemblage of secondary magnetite, zircon, uranothorite, columbite-(Mn), fergusonite-(Y), and allanite-(Ce). The extreme abundance of zircon in the mineralized zone, along with other evidence, indicates a hydrothermal origin of this zircon together with associated rare metals. The geochemical investigation and mass balance calculations revealed extreme enrichment of Zr, Th, U, Y, Nb, Ta, and REE. Post-magmatic hydrothermal alterations resulted in such pronounced chemical and mineralogical heterogeneity. The hydrothermal fluids are thought to be oxidizing, alkaline and of medium temperature (>?250 °C). The average contents of the elements Zr (1606 ppm), Th (1639 ppm), U (306 ppm), Nb (955 ppm), and REE (1710 ppm) in the mineralized microgranite reach sub-economic levels and could be a potential source of these elements.