Impact of rock-water interactions and recharge on water resources quality of the Agadir-Essaouira basin,southwestern Morocco

The Agadir-Essaouira area in the occidental High Atlas Mountains of Morocco is characterized by a semi-arid climate. The scarcity and quality of water resources, exacerbated by long drought periods, constitute a major problem for a sustainable development of this region. Groundwater resources of carbonate units within Jurassic and Cretaceous aquifers are requested for drinking and irrigation purposes. In this study, we collected 84 samples from wells, boreholes, springs, and rivers. Hydrochemical and isotopic data were used to examine the mineralization and origin of water, which control groundwater quality. The chemical composition of water seems to be controlled by water-rock interactions, such as dissolution of carbonates (calcite and dolomite), weathering of gypsum, as well as ion exchange processes, which explain the observed variability. Stable isotopes results show that groundwater from the mainly marly Cretaceous aquifer are submitted to an evaporation effect, while samples from the chiefly calcareous Jurassic aquifer indicate a meteoric origin, due to a rapid infiltration of recharge runoff through the karstic outcrops. The low values of δ¹⁸O and δ²H suggest a local recharge from areas with elevations ranging from 400 to 1200 m for the Cretaceous aquifer and from 800 to 1500 m for the Jurassic units.     

Adsorption of Congo red and crystal violet dyes onto cellulose extracted from Egyptian water hyacinth

Natural Hazards - The present investigation has highlighted the utility of floating aquatic Egyptian hyacinth, which is considered as a significant reason for environmental problems in Nile River,...     

Compression Behaviour of Chlef Sand and Transition of Fines Content Using Pressure-Dependent Maximum Void Ratios of Sand

Geotechnical and Geological Engineering - This paper presents a study on Chlef sand to examine the effect of fines content (Fc), relative density (RD) and initial conditions on the compressibility...     

Effect of heat treatment on dynamic properties of selected rock types taken from the Salt Range in Pakistan

Temperature is one of the variables that influence the elasto-plastic behavior and integrity of rock outcrops. Fluctuations in temperature can trigger alteration of some of the mineral properties and impact the brittle-plastic transition. Initiation and propagation of thermally induced tension cracks tend to weaken most rock types. The principal goal of this study was to anticipate impacts of thermal stress-strain cycles on the dynamic response of representative rock units exposed in the Khewra Gorge of the Salt Range Punjab of Pakistan. Ten types of sedimentary rock units were sampled, including marl, dolomite, three types of limestone, and five different sandstones exhibiting varying characteristics in outcrop. Boulder specimens were collected from the field and transported to the laboratory to prepare 50 drill cores that could be subjected to thermal cycling between 50 and 200 °C in increments of 50 °C. Room temperature core samples were tested using an Erudite resonance frequency meter to measure their Q-factors and the resonance frequency (F_r) at an applied loading frequency of 7 KHz with 0.01 V output voltage. Results suggest that thermal cycling tends to reduce the dynamic Young’s modulus (E_d) and Q-factor. Other parameters, such as damping ratio (ξ), specific damping capacity (Ψ), and loss factor (?) appeared to increase with increasing temperature cycles, likely as a result of developing thermally induced tensile fractures. The resultant values of the null hypothesis (t-critical and t-stats) suggests that the null hypothesis can be discarded because there was no observable difference between the measured and expected values for the cores tested. The observations and data emanating from this study might be useful in designing low-level radioactive waste landfills, nuclear waste repositories, and deep underground excavations where the increased temperature could alter the mechanical behavior of the parent rock mass.     

Dependence of radon exhalation on grain size of sedimentary waste

Tailings resulted from sulphuric acid leaching process of uranium from sedimentary rocks contain high concentrations of ²²⁶Ra and its daughters, the most important of which is ²²²Rn. Movement of radon gas out of the tailings is strongly influenced by the physicochemical characteristics of these tailings especially their radium content and the grain size. So, the tailing samples were size fractionated into four sizes (>?250, 250–125, 125–74 and <?74 µm). The natural radioactivity was investigated using hyper-pure germanium detector and solid-state nuclear track detectors (CR-39) for bulk size and after size fractionation. The activity concentrations of different radionuclides in size-fractionated tailing samples have been shown to be strongly dependent on the size of the particles. In the range of >?250 and <?74 µm, the activity concentrations of ²³⁰Th, ²²⁶Ra, ²¹⁴Pb, ²¹⁴Bi, ²¹⁰Pb, ²³²Th and ⁴⁰K increased throughout with decreasing particle size, while that of ²³⁸U, ²³⁴U and ²³⁵U have an opposite effect. The results revealed an inverse relationship between the radon exhalation rate and size fractionation. Also, the results showed a good correlation between radium activity concentration and radon mass exhalation rate.     

A new record and a new ichnospecies of Arachnostega from the Middle Miocene of Egypt

The ichnogenus Arachnostega Bertling, 1992 is recorded for the first time from a bioeroded, coral-rich, Middle Miocene limestone bed in the middle Siwa Escarpment Member (Marmarica Formation) at Siwa Oasis, northern Western Desert of Egypt. These burrowing traces are preserved on the surface of a few internal moulds of bivalves and gastropods. Until now, the ichnogenus Arachnostega included a single ichnospecies, A. gastrochaenae Bertling, 1992. In the material studied herein, two ichnospecies are identified, described, illustrated and compared with other, similar traces. One of these is a new ichnospecies of Arachnostega; this is here named A. siwaensis ichnosp. nov. It is distinguished from A. gastrochaenae in the possession of tunnels that usually branch in a V-pattern; intervals of ramification are longest in the main branch and decrease in second- and third-order branches. Arachnostega traces were produced in a warm, low-energy, shallow-marine (<10?m water depth) environment. Polychaetes are the most likely producers of marine Arachnostega, which are commonly occurred in the same studied bed. This new occurrence is significant in extending the known stratigraphical and geographical ranges of Arachnostega into the Middle Miocene of Egypt.     

GIS-based impact assessment of land-use changes on groundwater quality: study from a rapidly urbanizing region of South India

This study attempts to assess the influence of changing land-use patterns on the groundwater quality of the hard rock aquifer system in the Maheshwaram watershed, near Hyderabad, India. The study area is a rapidly urbanizing region with land development progressing at a fast pace. To study the impact of this rapid urbanization and overall land-use transition, a groundwater quality index (GQI) was prepared within a geographical information system (GIS). The GQI integrates the different water quality parameters to give a final index value that can be used for spatio-temporal comparisons. The land-use transitions were closely monitored from 2003 to 2008 using multispectral satellite images. The land-use pattern has changed drastically with an increase in the built-up area at the expense of other land uses. The analysis reveals a rapid deterioration of groundwater quality related mainly to the increase in built-up land with unsewered sanitation and poultry farms. Seasonal variability of the groundwater quality was also assessed. Mean GQI decreased from 84.16 to 83.26 over a period of 5 years from 2003 to 2008, while seasonal variability of water quality increased. GQI and Seasonal Variability of water quality were integrated in GIS to yield a groundwater sustainability map, in terms of water quality. Zones of sustainable and unsustainable groundwater use were demarcated for better decision making related to municipal land allotment in this rapidly urbanizing region.     

Hydrochemistry and Classification of Groundwater Resources of Ishwardi Municipal Area,Pabna District,Bangladesh

The chemical property of groundwater depends largely on the mineralogical composition of the rocks through which the water has moved and the rate of movement and these characteristics of surface water depend on organic and inorganic reactions, industrial effluents, rainfall and temperature etc. The underground water tends to contain more dissolved materials than those in surface water because of their more intimate and longer contact with organic materials of soil and rock particles. The groundwater of the studied area is dominant of alkaline earth’s (Ca²⁺ and Mg²⁺) and weak acids (HCO₃ ⁻) which may be classified as Magnesium-Bicarbonate and Calcium Carbonate types. Genetically, the groundwater of the area belongs to both “Normal Chloride” “Normal Sulphate” and “Normal Carbonate” to “Super Carbonate” group. Based on EC, SAR and RC, the groundwater of the area varies from good–excellent quality for irrigation purposes with low alkali hazard and medium salinity hazard.     

Evolution of isotopic compositions in groundwater of the area between the Gulf of Oman and the Arabian Gulf

The stable isotopes of oxygen and hydrogen have been implemented to assess the recharge mechanisms in an area in the UAE bounded to the northwestern part of the Gulf of Oman and the southeastern part of the Arabian Gulf. The conversion of stable isotopes to deuterium excess was utilized as a supportive tool to understand the process of groundwater recharge. The concluding results of this study showed that the origin of moisture is the Mediterranean Sea. The precipitation is the main source of recharge, in which the precipitation having undergone evaporation before recharge occurs. The comparison between regression line for data collected in 1996 and regression line for samples collected in 2006 suggests that the precipitation water which recharged the groundwater, was diluted with groundwater and this dilution is observed from decreasing of the deuterium excess of collected groundwater samples with increasing isotopes of oxygen. The dilution of groundwater with the recharge water suggests modern-day recharge as it is seen from high deuterium excess that exceeded the deuterium excess of LMWL and was close to MMWL.     

A practical co-simulation approach for multiscale analysis of geotechnical systems

The particulate nature of granular soils can be accurately simulated at a microscale level. However, due to the huge spatial extent of geotechnical systems, a model fully constructed at such a scale is almost impossible with current computing technologies. Hence, continuum-based approaches are considered as the practical scale for modeling the majority of problems. Combining both scales enables benefiting from the advantages of both techniques while trying to overcome their drawbacks. Although a significant number of publications have addressed coupling both scales, only a few provide information regarding implementing the proposed procedures. In this study, an efficient co-simulation framework for conducting multiscale analysis is introduced. The framework is based on integrating existing continuum and micromechanical modeling software packages and therefore benefitting from already existing codes. A computational simulation of a rigid pile in contact with granular soil demonstrating the capabilities of such technique is presented. The near-field zone surrounding the pile is modeled using DEM whereas FEM is utilized to model far-field zones that are not affected by the presence of the pile. Results of conducted simulations resemble those obtained from experimental results. The proposed approach appears to be a very effective and promising tool to model boundary value problems of geotechnical systems.