Adsorption of Congo red and crystal violet dyes onto cellulose extracted from Egyptian water hyacinth

Natural Hazards - The present investigation has highlighted the utility of floating aquatic Egyptian hyacinth, which is considered as a significant reason for environmental problems in Nile River,...     

Compression Behaviour of Chlef Sand and Transition of Fines Content Using Pressure-Dependent Maximum Void Ratios of Sand

Geotechnical and Geological Engineering - This paper presents a study on Chlef sand to examine the effect of fines content (Fc), relative density (RD) and initial conditions on the compressibility...     

On the distribution of rainfall over the Sultanate of Oman

Rainfall distribution over the Sultanate of Oman is analysed. Data from seven recently installed weather stations as well as supporting data from scattered sources were used. Distribution maps were drawn. NW and NE winter wind meet resulting in troughs and rainfall on the Mountains and Coastal Strips. Summer monsoon wind dominates the S. Central areas of overlap receive light showers from both summer monsoons and winter local troughs. Heavier amounts of rainfall are generally associated with high altitude.     

Effect of heat treatment on dynamic properties of selected rock types taken from the Salt Range in Pakistan

Temperature is one of the variables that influence the elasto-plastic behavior and integrity of rock outcrops. Fluctuations in temperature can trigger alteration of some of the mineral properties and impact the brittle-plastic transition. Initiation and propagation of thermally induced tension cracks tend to weaken most rock types. The principal goal of this study was to anticipate impacts of thermal stress-strain cycles on the dynamic response of representative rock units exposed in the Khewra Gorge of the Salt Range Punjab of Pakistan. Ten types of sedimentary rock units were sampled, including marl, dolomite, three types of limestone, and five different sandstones exhibiting varying characteristics in outcrop. Boulder specimens were collected from the field and transported to the laboratory to prepare 50 drill cores that could be subjected to thermal cycling between 50 and 200 °C in increments of 50 °C. Room temperature core samples were tested using an Erudite resonance frequency meter to measure their Q-factors and the resonance frequency (F_r) at an applied loading frequency of 7 KHz with 0.01 V output voltage. Results suggest that thermal cycling tends to reduce the dynamic Young’s modulus (E_d) and Q-factor. Other parameters, such as damping ratio (ξ), specific damping capacity (Ψ), and loss factor (?) appeared to increase with increasing temperature cycles, likely as a result of developing thermally induced tensile fractures. The resultant values of the null hypothesis (t-critical and t-stats) suggests that the null hypothesis can be discarded because there was no observable difference between the measured and expected values for the cores tested. The observations and data emanating from this study might be useful in designing low-level radioactive waste landfills, nuclear waste repositories, and deep underground excavations where the increased temperature could alter the mechanical behavior of the parent rock mass.     

Dependence of radon exhalation on grain size of sedimentary waste

Tailings resulted from sulphuric acid leaching process of uranium from sedimentary rocks contain high concentrations of ²²⁶Ra and its daughters, the most important of which is ²²²Rn. Movement of radon gas out of the tailings is strongly influenced by the physicochemical characteristics of these tailings especially their radium content and the grain size. So, the tailing samples were size fractionated into four sizes (>?250, 250–125, 125–74 and <?74 µm). The natural radioactivity was investigated using hyper-pure germanium detector and solid-state nuclear track detectors (CR-39) for bulk size and after size fractionation. The activity concentrations of different radionuclides in size-fractionated tailing samples have been shown to be strongly dependent on the size of the particles. In the range of >?250 and <?74 µm, the activity concentrations of ²³⁰Th, ²²⁶Ra, ²¹⁴Pb, ²¹⁴Bi, ²¹⁰Pb, ²³²Th and ⁴⁰K increased throughout with decreasing particle size, while that of ²³⁸U, ²³⁴U and ²³⁵U have an opposite effect. The results revealed an inverse relationship between the radon exhalation rate and size fractionation. Also, the results showed a good correlation between radium activity concentration and radon mass exhalation rate.     

A new record and a new ichnospecies of Arachnostega from the Middle Miocene of Egypt

The ichnogenus Arachnostega Bertling, 1992 is recorded for the first time from a bioeroded, coral-rich, Middle Miocene limestone bed in the middle Siwa Escarpment Member (Marmarica Formation) at Siwa Oasis, northern Western Desert of Egypt. These burrowing traces are preserved on the surface of a few internal moulds of bivalves and gastropods. Until now, the ichnogenus Arachnostega included a single ichnospecies, A. gastrochaenae Bertling, 1992. In the material studied herein, two ichnospecies are identified, described, illustrated and compared with other, similar traces. One of these is a new ichnospecies of Arachnostega; this is here named A. siwaensis ichnosp. nov. It is distinguished from A. gastrochaenae in the possession of tunnels that usually branch in a V-pattern; intervals of ramification are longest in the main branch and decrease in second- and third-order branches. Arachnostega traces were produced in a warm, low-energy, shallow-marine (<10?m water depth) environment. Polychaetes are the most likely producers of marine Arachnostega, which are commonly occurred in the same studied bed. This new occurrence is significant in extending the known stratigraphical and geographical ranges of Arachnostega into the Middle Miocene of Egypt.     

Geochemistry and mineralogy of arsenic in (natural) anaerobic groundwaters

Here new data from field bioremediation experiments and geochemical modeling are reported to illustrate the principal geochemical behavior of As in anaerobic groundwaters. In the field bioremediation experiments, groundwater in Holocene alluvial aquifers in Bangladesh was amended with labile water-soluble organic C (molasses) and MgSO₄ to stimulate metabolism of indigenous SO₄-reducing bacteria (SRB). In the USA, the groundwater was contaminated by Zn, Cd and SO₄, and contained <10 μg/L As under oxidized conditions, and a mixture of sucrose and methanol were injected to stimulate SRB metabolism. In Bangladesh, groundwater was under moderately reducing conditions and contained ∼10 mg/L Fe and ∼100 μg/L As. In the USA experiment, groundwater rapidly became anaerobic, and dissolved Fe and As increased dramatically (As > 1000 μg/L) under geochemical conditions consistent with bacterial Fe-reducing conditions. With time, groundwater became more reducing and biogenic SO₄ reduction began, and Cd and Zn were virtually completely removed due to precipitation of sphalerite (ZnS) and other metal sulfide mineral(s). Following precipitation of chalcophile elements Zn and Cd, the concentrations of Fe and As both began to decrease in groundwater, presumably due to formation of As-bearing FeS/FeS₂. By the end of the six-month experiment, dissolved As had returned to below background levels. In the initial Bangladesh experiment, As decreased to virtually zero once biogenic SO₄ reduction commenced but increased to pre-experiment level once SO₄ reduction ended. In the ongoing experiment, both SO₄ and Fe(II) were amended to groundwater to evaluate if FeS/FeS₂ formation causes longer-lived As removal. Because As-bearing pyrite is the common product of SRB metabolism in Holocene alluvial aquifers in both the USA and Southeast Asia, it was endeavored to derive thermodynamic data for arsenian pyrite to better predict geochemical processes in naturally reducing groundwaters. Including the new data for arsenian pyrite into Geochemist’s Workbench, its stability field completely dominates in reducing Eh–pH space and “displaces” other As-sulfides (orpiment, realgar) that have been implied to be important in previous modeling exercises and reported in rare field conditions.     

Comparison of dissolved and particulate arsenic distributions in shallow aquifers of Chakdaha, India, and Araihazar, Bangladesh

Background  

The origin of the spatial variability of dissolved As concentrations in shallow aquifers of the Bengal Basin remains poorly understood. To address this, we compare here transects of simultaneously-collected groundwater and aquifer solids perpendicular to the banks of the Hooghly River in Chakdaha, India, and the Old Brahmaputra River in Araihazar, Bangladesh.     

GIS-based impact assessment of land-use changes on groundwater quality: study from a rapidly urbanizing region of South India

This study attempts to assess the influence of changing land-use patterns on the groundwater quality of the hard rock aquifer system in the Maheshwaram watershed, near Hyderabad, India. The study area is a rapidly urbanizing region with land development progressing at a fast pace. To study the impact of this rapid urbanization and overall land-use transition, a groundwater quality index (GQI) was prepared within a geographical information system (GIS). The GQI integrates the different water quality parameters to give a final index value that can be used for spatio-temporal comparisons. The land-use transitions were closely monitored from 2003 to 2008 using multispectral satellite images. The land-use pattern has changed drastically with an increase in the built-up area at the expense of other land uses. The analysis reveals a rapid deterioration of groundwater quality related mainly to the increase in built-up land with unsewered sanitation and poultry farms. Seasonal variability of the groundwater quality was also assessed. Mean GQI decreased from 84.16 to 83.26 over a period of 5 years from 2003 to 2008, while seasonal variability of water quality increased. GQI and Seasonal Variability of water quality were integrated in GIS to yield a groundwater sustainability map, in terms of water quality. Zones of sustainable and unsustainable groundwater use were demarcated for better decision making related to municipal land allotment in this rapidly urbanizing region.