The supergene origin of ruthenian hexaferrum in Ni‐laterites

For two decades, the nature of Fe‐rich, oxygen‐bearing, Ru–Os compounds found in the supergene environment has been debated. Ru–Os–Fe‐oxides and nano‐intergrowths of ruthenium with magnetite have been proposed. We applied FE‐SEM, EMPA, μ‐Raman spectroscopy and synchrotron tts‐μXRD to Ru–Os–Fe compounds recovered from Ni‐laterites from the Dominican Republic. The results demonstrate that a significant portion of Fe exists in a common structure with the Ru–Os alloy, that is, ruthenian hexaferrum. This mineral occurs both as nanoparticles and as micrometric patches within a matrix of Fe‐oxide(s). Our data suggest that supergene ruthenian hexaferrum with a (Ru_0.4(Os,Ir)_0.1Fe_0.5)_?1.0 stoichiometry represents the most advanced weathering product of primary laurite within Ni‐laterites from the Dominican Republic.     

Smoothing and high risk areas detection in space-time disease mapping: a comparison of P-splines,autoregressive, and moving average models

Recently, several models have been proposed for smoothing risks in disease mapping. These models consider different ways of introducing both spatial and temporal dependence as well as spatio-temporal interactions. In this work, a comparison among some autoregressive, moving average, and P-spline models is performed. Firstly, brain cancer mortality data are used to analyze the degree of smoothness introduced by these models. Secondly, two separate simulation studies (one model-based and the other model-free) are carried out to evaluate the model performance in terms of bias, variability, sensitivity, and specificity. We conclude that P-spline models seem to be a good alternative to autoregressive and moving average models when analyzing highly sparse disease mapping data.     

Spatial and temporal structure of the Denmark Strait Overflow revealed by acoustic observations

In spite of the fundamental role the Atlantic Meridional Overturning Circulation (AMOC) plays for global climate stability, no direct current measurement of the Denmark Strait Overflow, which is the densest part of the AMOC, has been available until recently that resolve the cross-stream structure at the sill for long periods. Since 1999, an array of bottom-mounted acoustic instruments measuring current velocity and bottom-to-surface acoustic travel times was deployed at the sill. Here, the optimization of the array configuration based on a numerical overflow model is discussed. The simulation proves that more than 80% of the dense water transport variability is captured by two to three acoustic current profilers (ADCPs). The results are compared with time series from ADCPs and Inverted Echo Sounders deployed from 1999 to 2003, confirming that the dense overflow plume can be reliably measured by bottom-mounted instruments and that the overflow is largely geostrophically balanced at the sill.     

Statistical and spectral analysis of the wind regime in the area of Catalonia

Summary This work presents a statistical study of the wind power potential of three stations in the Catalonia area (Spain) over the 1973–1982 period. These stations correspond to three airports (Barcelona, Palma de Mallorca and Girona), which obviously do not present a high wind power potential and are not the suitable locations for wind power utilization, but which have been chosen for the long record of data stored (10 years). The aim of this work is to provide a model of wind potential in terms of the speed and wind direction, which may be applied to other sites. The wind speed has been modelled by a Weibull distribution function and the wind direction by a normal two-dimensional function. A spectral analysis of both variables has also been carried out. The present study provides an evaluation of the local wind power in the geographic area of Catalonia.With 10 Figures     

The ICL Network on “Landslides and Cultural & Natural Heritage (LACUNHEN)”

In recent decades, the concept of cultural heritage has evolved into one that encompasses an understanding of the history of humanity, together with scientific knowledge and intellectual attitudes. This changing concept has prompted a subsequent re-evaluation of what constitutes the outstanding universal values of World Heritage sites and the operational methods for implementing the UNESCO World Heritage Convention. The scope has broadened from studying a single monument in isolation to one that values a multidimensional, multiregional, and inter-disciplinary approach and encapsulates vast spans of human history. Within this broader view, landslides and more generally slope instabilities are an important factor endangering cultural heritage sites, especially prehistoric sites, earth/rock monuments, and archaeological sites affected by environmental processes and degradation. Natural and cultural heritage sites, as well as cultural landscapes, are then tied into a common framework that the Geological Society of America has defined “Men’s legacy to Earth and Earth’s legacy to Man”. On the other hand, not too much effort has been expended in the past to develop conservation policies systematically integrating geological, geomorphological, and engineering geological aspects into daily practices. The purpose of the “LAndslides and CUltural & Natural HEritage” thematic Network (LACUNHEN) is to create a platform for scientists and practitioners who are ready to jointly contribute to safeguarding relevant endangered Natural and Cultural Heritage sites (e.g., Machu Picchu). They will share and disseminate their respective experience, demonstrating how these special “objects” require approaches, techniques, and solutions that go far beyond traditional civil engineering perspectives.     

Geomicrobiology of cores from Suruí Mangrove - Guanabara Bay - Brazil

The aim of this work was to quantify the biopolymers associated to esterase enzymes and identify bacterial respiratory activity in four cores collected in Suruí Mangrove, Guanabara Bay - RJ. Biopolymer concentration was 1000 times lower than previously reported in the literature, indicating the need for creating and establishing eutrophication indicative rates and records compatible with tropical coastal systems. The biochemical representative relationships in the cores were equivalent to those from studies on coastal marine environments made in the Northern Hemisphere. The esterase enzymes in the sediment proved efficient in the mineralization of biopolymers, even with preferentially anaerobic metabolic physiology. Despite the lack of incipient geomicrobiological studies, the results highlighted the possible application of microbiology to a better understanding of geological processes.