Carbonate cements in Miller field of the UK North Sea: a natural analog for mineral trapping in CO<Subscript>2</Subscript> geological storage

Miller field of the North Sea has had high concentrations of natural CO₂ for ~70 Ma. It is an ideal analog for the long-term fate of CO₂ during engineered storage, particularly for formation of carbonate minerals that permanently lock up CO₂ in solid form. The Brae Formation reservoir sandstone contains an unusually high quantity of calcite concretions; however, C and O stable isotopic signatures suggest that these are not related to the present-day CO₂ charge. Margins of the concretions are corroded, probably because of reduced pH due to CO₂ influx. Dispersed calcite cements are also present, some of which postdate the CO₂ charge and, therefore, are the products of mineral trapping. It is calculated that only a minority of the reservoired CO₂ in Miller (6–24%) has been sequestrated in carbonates, even after 70 Ma of CO₂ emplacement. Most of the CO₂ accumulation is dissolved in pore fluids. Therefore, in a reservoir similar to the Brae Formation, engineered CO₂ storage must rely on physical retention mechanisms because mineral trapping is both incomplete and slow.     

InSAR detection of residual settlement of an ocean reclamation engineering project: a case study of Hong Kong International Airport

Man-made land or islands that are reclaimed from the sea are suitable for building airports, harbors, and industry parks for material transportation because of their broad air and land spaces. However, the reclaimed foundation settlement process is of public concern, including the continuous impact of ocean processes on its stability. The majority of the buildings and facilities of Hong Kong International Airport (HKIA) are built on a reclaimed foundation. The reclaimed foundation has been in residual settlement since completion of the filling project in 1994. In this study, we use persistent scatterer interferometry (PSI) and ENVISAT (European Satellite) advanced synthetic aperture radar (ASAR) data to detect the residual settlement rates from 19 April 2006 to 9 January 2008. We use ground truth data to develop empirical correction models for correcting systematic biases in the ASAR PSI-detected settlement rates. The corrected data follow the Lorentz distribution well, implying that the residual settlement process is dominated by two modes or categories of settlement rates. The first category represents a relatively stable state and the second category represents a continuous settlement state. A ground settlement rate map of HKIA shows that an area of the Passenger Terminal Building and an area of the Southern Runway are two relatively stable areas. There are two major continuous settlement areas. One covers the airport Midfield. Another is along the coastline, implying that attention should be paid to impacts of ocean processes on the stability of airport foundations.     

Potential Application of Lateritic Soil Stabilized with Cement Kiln Dust (CKD) as Liner in Waste Containment Structures

This study evaluates the applicability of residually derived lateritic soil stabilized with cement kiln dust (CKD), a waste product from the cement manufacturing process as liner in waste repositories. Lateritic soil sample mixed with 0–16 % CKD (by dry weight of the soil) was compacted with the British Standard Light, West African Standard and British Standard Heavy compaction efforts at water contents ranging from the dry to wet of optimum moistures. Geotechnical parameters such as Atterberg limits, compaction characteristics, hydraulic conductivity, unconfined compressive strength and volumetric shrinkage strain were determined. Results indicate that the plasticity index, the maximum dry unit weight and hydraulic conductivity together with the volumetric shrinkage decreased with increased amount of CKD while the optimum moisture content and unconfined compressive strength increased with higher CKD content for all the efforts. When measured properties were compared with standard specifications adopted by most environmental regulatory agencies for the construction of barrier systems in waste containment structures, the resulting values showed substantial compliance. Besides developing an economically sustainable liner material, the present study demonstrated effective utilization of an industrial by-product otherwise considered as waste by the producers, in addition to a systematic expansion in the use of the lateritic soil for geotechnical works.     

Exploring the impact of diagenesis on (isotope) geochemical and microstructural alteration features in biogenic aragonite

For the Quaternary and Neogene, aragonitic biogenic and abiogenic carbonates are frequently exploited as archives of their environment. Conversely, pre‐Neogene aragonite is often diagenetically altered and calcite archives are studied instead. Nevertheless, the exact sequence of diagenetic processes and products is difficult to disclose from naturally altered material. Here, experiments were performed to understand biogenic aragonite alteration processes and products. Shell subsamples of the bivalve Arctica islandica were exposed to hydrothermal alteration. Thermal boundary conditions were set at 100°C, 175°C and 200°C. These comparably high temperatures were chosen to shorten experimental durations. Subsamples were exposed to different ¹⁸O‐depleted fluids for durations between two and twenty weeks. Alteration was documented using X‐ray diffraction, cathodoluminescence, fluorescence and scanning electron microscopy, as well as conventional and clumped isotope analyses. Experiments performed at 100°C show redistribution and darkening of organic matter, but lack evidence for diagenetic alteration, except in Δ₄₇ which show the effects of annealing processes. At 175°C, valves undergo significant aragonite to calcite transformation and neomorphism. The δ¹⁸O signature supports transformation via dissolution and reprecipitation, but isotopic exchange is limited by fluid migration through the subsamples. Individual growth increments in these subsamples exhibit bright orange luminescence. At 200°C, valves are fully transformed to calcite and exhibit purple‐blue luminescence with orange bands. The δ¹⁸O and Δ₄₇ signatures reveal exchange with the aqueous fluid, whereas δ¹³C remains unaltered in all experiments, indicating a carbonate‐buffered system. Clumped isotope temperatures in high‐temperature experiments show compositions in broad agreement with the measured temperature. Experimentally induced alteration patterns are comparable with individual features present in Pleistocene shells. This study represents a significant step towards sequential analysis of diagenetic features in biogenic aragonites and sheds light on reaction times and threshold limits. The limitations of a study restricted to a single test organism are acknowledged and call for refined follow‐up experiments.     

Early solar system processes recorded in the matrices of two highly pristine CR3 carbonaceous chondrites, MET 00426 and QUE 99177

The mineralogy and bulk compositions of the matrices of the CR chondrites MET 00426 and QUE 99177 have been studied using a combination of SEM, EPMA, and TEM techniques. The matrices of these two chondrites are texturally, chemically, and mineralogically similar and are characterized by significant FeO-enrichments with respect to other CR chondrite matrices, nearly flat refractory lithophile patterns, variable volatile element patterns, and a simple mineral assemblage dominated by amorphous silicate material and Fe,Ni sulfides. Fine-grained, crystalline silicate phases such as olivine and pyroxene appear to be extremely rare in the matrices of both meteorites. Instead, the mineralogy of matrices and fine-grained rims of both meteorites consists of abundant amorphous FeO-rich silicate material, containing nanoparticles of Fe,Ni sulfides (troilite, pyrrhotite, and pentlandite). Secondary alteration minerals that are characteristic of other CR chondrites (e.g., Renazzo and Al Rais), such as phyllosilicates, magnetite, and calcite are also rare. The texture and mineralogy of the matrices of MET 00426 and QUE 99177 share many features with matrices in the primitive carbonaceous chondrites ALH A77307 (CO3.0) and Acfer 094 (unique). These observations show that MET 00426 and QUE 99177 are very low petrologic type 3 chondrites that have escaped the effects of aqueous alteration, unlike other CR chondrites, which are typically classified as petrologic type 2. We suggest that these meteorites represent additional samples of highly primitive, but extremely rare carbonaceous chondrites of petrologic type 3.00, according to the classification scheme of Grossman and Brearley (2005). The highly pristine nature of MET 00426 and QUE 99177 provides important additional insights into the origins of fine-grained materials in carbonaceous chondrites. Based on our new observations, we infer that the amorphous silicate material and nanosulfide particles that dominate the matrices of these meteorites formed in the solar nebula by rapid condensation of material following high-temperature events, such as those that formed chondrules.     

Strain localization as a key to reconciling experimentally derived flow-law data with dynamic models of continental collision

Published strength profiles predict strength discontinuities within and/or at the base of continental crust during compression. We use finite element models to investigate the effect of strength discontinuities on continental collision dynamics. The style of deformation in model crust during continued subduction of underlying mantle lithosphere is controlled by: (1) experimental flow-law data; (2) the crustal geotherm; (3) strain localization by erosion; (4) strain-softening and other localization effects. In the absence of erosion and other factors causing strain localization, numerical models with typical geothermal gradients and frictional/ductile rheologies predict diffuse crustal deformation with whole-scale detachment of crust from mantle lithosphere. This prediction is at odds with earlier model studies that only considered frictional crustal rheologies and showed asymmetric, focused crustal deformation. Without localization, model deformation is not consistent with that observed in small collisional orogens such as the Swiss Alps. This suggests that strain localization by a combination of erosion and rheological effects such as strain softening must play a major role in focusing deformation, and that strength profiles derived under constant strain rates and uniform material properties cannot be used to infer crustal strength during collision dynamics.     

<Superscript>10</Superscript>Be, <Superscript>18</Superscript>O and radiogenic isotopic constraints on the origin of adakitic signatures: a case study from Solander and Little Solander Islands,New Zealand

Subduction-related Quaternary volcanic rocks from Solander and Little Solander Islands, south of mainland New Zealand, are porphyritic trachyandesites and andesites (58.20–62.19 wt% SiO₂) with phenocrysts of amphibole, plagioclase and biotite. The Solander and Little Solander rocks are incompatible element enriched (e.g. Sr ~931–2,270 ppm, Ba ~619–798 ppm, Th ~8.7–21.4 ppm and La ~24.3–97.2 ppm) with MORB-like Sr and Nd isotopic signatures. Isotopically similar quench-textured enclaves reflect mixing with intermediate (basaltic-andesite) magmas. The Solander rocks have geochemical affinities with adakites (e.g. high Sr/Y and low Y), whose origin is often attributed to partial melting of subducted oceanic crust. Solander sits on isotopically distinct continental crust, thus excluding partial melting of the lower crust in the genesis of the magmas. Furthermore, the incompatible element enrichments of the Solander rocks are inconsistent with partial melting of newly underplated mafic lower crust; reproduction of their major element compositions would require unrealistically high degrees of partial melting. A similar argument precludes partial melting of the subducting oceanic crust and the inability to match the observed trace element patterns in the presence of residual garnet or plagioclase. Alternatively, an enriched end member of depleted MORB mantle source is inferred from Sr, Nd and Pb isotopic compositions, trace element enrichments and εHf ? 0 CHUR in detrital zircons, sourced from the volcanics. ¹⁰Be and Sr, Nd and Pb isotopic systematics are inconsistent with significant sediment involvement in the source region. The trace element enrichments and MORB-like Sr and Nd isotopic characteristics of the Solander rocks require a strong fractionation mechanism to impart the high incompatible element concentrations and subduction-related (e.g. high LILE/HFSE) geochemical signatures of the Solander magmas. Trace element modelling shows that this can be achieved by very low degrees of melting of a peridotitic source enriched by the addition of a slab-derived melt. Subsequent open-system fractionation, involving a key role for mafic magma recharge, resulted in the evolved andesitic adakites.     

Coupling between subtropical cloud feedback and the local hydrological cycle in a climate model

In HadGEM2-A, AMIP experiments forced with observed sea surface temperatures respond to uniform and patterned +4 K SST perturbations with strong positive cloud feedbacks in the subtropical stratocumulus/trade cumulus transition regions. Over the subtropical Northeast Pacific at 137°W/26°N, the boundary layer cloud fraction reduces considerably in the AMIP +4 K patterned SST experiment. The near-surface wind speed and the air-sea temperature difference reduces, while the near-surface relative humidity increases. These changes limit the local increase in surface evaporation to just 3 W/m² or 0.6 %/K. Previous studies have suggested that increases in surface evaporation may be required to maintain maritime boundary layer cloud in a warmer climate. This suggests that the supply of water vapour from surface evaporation may not be increasing enough to maintain the low level cloud fraction in the warmer climate in HadGEM2-A. Sensitivity tests which force the surface evaporation to increase substantially in the +4 K patterned SST experiment result in smaller changes in boundary layer cloud and a weaker cloud feedback in HadGEM2-A, supporting this idea. Although global mean surface evaporation in climate models increases robustly with global temperature (and the resulting increase in atmospheric radiative cooling), local values may increase much less, having a significant impact on cloud feedback. These results suggest a coupling between cloud feedback and the hydrological cycle via changes in the patterns of surface evaporation. A better understanding of both the factors controlling local changes in surface evaporation and the sensitivity of clouds to such changes may be required to understand the reasons for inter-model differences in subtropical cloud feedback.     

The onset of metamorphism in ordinary and carbonaceous chondrites

Abstract— Ordinary and carbonaceous chondrites of the lowest petrologic types were surveyed by X‐ray mapping techniques. A variety of metamorphic effects were noted and subjected to detailed analysis using electron microprobe, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and cathodoluminescence (CL) methods. The distribution of Cr in FeO‐rich olivine systematically changes as metamorphism increases between type 3.0 and type 3.2. Igneous zoning patterns are replaced by complex ones and Cr‐rich coatings develop on all grains. Cr distributions in olivine are controlled by the exsolution of a Cr‐rich phase, probably chromite. Cr in olivine may have been partly present as tetrahedrally coordinated Cr³⁺. Separation of chromite is nearly complete by petrologic type 3.2. The abundance of chondrules showing an inhomogeneous distribution of alkalis in mesostasis also increases with petrologic type. TEM shows this to be the result of crystallization of albite. Residual glass compositions systematically change during metamorphism, becoming increasingly rich in K. Glass in type I chondrules also gains alkalis during metamorphism. Both types of chondrules were open to an exchange of alkalis with opaque matrix and other chondrules. The matrix in the least metamorphosed chondrites is rich in S and Na. The S is lost from the matrix at the earliest stages of metamorphism due to coalescence of minute grains. Progressive heating also results in the loss of sulfides from chondrule rims and increases sulfide abundances in coarse matrix assemblages as well as inside chondrules. Alkalis initially leave the matrix and enter chondrules during early metamorphism. Feldspar subsequently nucleates in the matrix and Na re‐enters from chondrules. These metamorphic trends can be used to refine classification schemes for chondrites. Cr distributions in olivine are a highly effective tool for assigning petrologic types to the most primitive meteorites and can be used to subdivide types 3.0 and 3.1 into types 3.00 through 3.15. On this basis, the most primitive ordinary chondrite known is Semarkona, although even this meteorite has experienced a small amount of metamorphism. Allan Hills (ALH) A77307 is the least metamorphosed CO chondrite and shares many properties with the ungrouped carbonaceous chondrite Acfer 094. Analytical problems are significant for glasses in type II chondrules, as Na is easily lost during microprobe analysis. As a result, existing schemes for chondrule classification that are based on the alkali content of glasses need to be revised.