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41.
L.D. Chrosniak L.N. Smith C.G. McDonald B.F. Jones J.M. Flinn 《Journal of Geochemical Exploration》2006,88(1-3):91
Ingestion of enhanced zinc can cause memory impairments and copper deficiencies. This study examined the effect of zinc supplementation, with and without copper, on two types of memory. Rats raised pre- and post-natally on 10 mg/kg ZnCO3 or ZnSO4 in the drinking water were tested in a fear-conditioning experiment at 11 months of age. Both zinc groups showed a maladaptive retention of fearful memories compared to controls raised on tap water. Rats raised on 10 mg/kg ZnCO3, 10 mg/kg ZnCO3 + 0.25 mg/kg CuCl2, or tap water, were tested for spatial memory ability at 3 months of age. Significant improvements in performance were found in the ZnCO3 + CuCl2 group compared to the ZnCO3 group, suggesting that some of the cognitive deficits associated with zinc supplementation may be remediated by addition of copper. 相似文献
42.
An ephemeral estuarine turbidity maximum (ETM) occurs at high water in the macrotidal Taf estuary (SW Wales, United Kingdom).
A new mechanism of ETM formation, due to resuspension and advection of material by flood tidal currents, is observed that
differs from classical mechanisms of gravitational circulation and tidal pumping. The flood tide advances across intertidal
sand flats in the main body of the estuary, progressively entraining material from the rippled sands. Resuspension creates,
a turbid front that has suspended sediment concentrations (SSC) of about 4,000 mg I−1 by the time it reaches its landward limit which is also the landward limit of salt penetration. This turbid body constitutes
the ETM. Deposition occurs at high slack water but the ETM retains SSC values up to 800 mg I−1, 1–2 orders of magnitude greater than ambient SSC values in the river and estuarine waters on either side. The ETM retreats
down the estuary during the ebb; some material is deposited thinly across emergent intertidal flats and some is flushed out
of the estuary. A new ETM is generated by the next flood tide. Both location and SSC of the ETM scale on Q/R3 where Q is tidal range and R is river discharge. The greatest expression of the ETM occurs when a spring tide coincides with
low river discharge. It does not form during high river discharge conditions and is poorly developed on neap tides. Particles
in the ETM have effective densities (120–160 kg m−3) that are 3–4 times less than those in the main part of the estuary at high water. High chlorophyll concentrations in the
ETM suggest that flocs probably originate from biological production in the estuary, including production on the intertidal
sand flats. 相似文献
43.
Vivienne Jones 《Journal of Paleolimnology》2006,36(4):439-440
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The Zambian Copperbelt forms the southeastern part of the 900-km-long Neoproterozoic Lufilian Arc and contains one of the world’s largest accumulations of sediment-hosted stratiform copper mineralization. The Nchanga deposit is one of the most significant ore systems in the Zambian Copperbelt and contains two major economic concentrations of copper and cobalt, hosted within the Lower Roan Group of the Katangan Supergroup. A Lower Orebody (copper only) and Upper Orebody (copper and cobalt) occur towards the top of arkosic units and within the base of overlying shales. The sulfide mineralogy includes pyrite, bornite, chalcopyrite, and chalcocite, although in the Lower Orebody, sulfide phases are partially or completely replaced by malachite and copper oxides. Carrollite is the major cobalt-bearing phase and is restricted to fault-propagation fold zones within a feldspathic arenite. Hydrothermal alteration minerals include dolomite, phlogophite, sericite, rutile, quartz, tourmaline, and chlorite. Quartz veins from the mine sequence show halite-saturated fluid inclusions, ranging from ~31 to 38 wt% equivalent NaCl, with homogenisation temperatures (ThTOT) ranging between 140 and 180°C. Diagenetic pyrites in the lower orebody show distinct, relatively low δ
34S, ranging from −1 to −17‰ whereas arenite- and shale-hosted copper and cobalt sulfides reveal distinctly different δ
34S from −1 to +12‰ for the Lower Orebody and +5 to +18‰ for the Upper Orebody. There is also a clear distinction between the δ
34S mean of +12.1±3.3‰ (n=65) for the Upper Orebody compared with +5.2±3.6‰ (n=23) for the Lower Orebody. The δ
13C of dolomites from units above the Upper Orebody give δ
13C values of +1.4 to +2.5‰ consistent with marine carbon. However, dolomite from the shear-zones and the alteration assemblages within the Upper Orebody show more negative δ
13C values: −2.9 to −4.0‰ and −5.6 to −8.3‰, respectively. Similarly, shear zone and Upper Orebody dolomites give a δ
18O of +11.7 to +16.9‰ compared to Lower Roan Dolomites, which show δ
18O of +22.4 to +23.0‰. Two distinct structural regimes are recognized in the Nchanga area: a weakly deformed zone consisting of basement and overlying footwall siliciclastics, and a moderate to tightly folded zone of meta-sediments of the Katangan succession. The fold geometry of the Lower Roan package is controlled by internal thrust fault-propagation folds, which detach at the top of the lowermost arkose or within the base of the overlying stratigraphy and show vergence towards the NE. Faulting and folding are considered to be synchronous, as folding predominantly occurred at the tips of propagating thrust faults, with local thrust breakthrough. The data from Nchanga suggests a strong link between ore formation and the development of structures during basin inversion as part of the Lufilian Orogeny. Sulfides tend to be concentrated within arenites or coarser-grained layers within shale units, suggesting that host-rock porosity and possibly permeability played a role in ore formation. However, sulfides are also commonly orientated along, but not deformed by, a tectonic fabric or hosted within small fractures that suggest a significant role for deformation in the development of the mineralization. The ore mineralogy, hydrothermal alteration, and stable isotope data lend support to models consistent with the thermochemical reduction of a sulfate- (and metal) enriched hydrothermal fluid, at the site of mineralization. There is no evidence at Nchanga for a contribution of bacteriogenic sulfide, produced during sedimentation or early diagenesis, to the ores.Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users.Editorial handling: H. Frimmel 相似文献
46.
Tingting Yao Craig Calvert Tom Jones Glen Bishop Yuan Ma Lincoln Foreman 《Mathematical Geology》2006,38(1):51-62
Spectral simulation has gained application in building geologic models due to the advantage of better honoring the spatial continuity of petrophysical properties, such as reservoir porosity and shale volume. Distinct from sequential simulation methods, spectral simulation is a global algorithm in the sense that a global density spectrum is calculated once and the inverse Fourier transform is performed on the Fourier coefficient also only once to generate a simulation realization. The generated realizations honor the spatial continuity structure globally over the whole field instead of only within a search neighborhood, as with sequential simulation algorithms. However, the disadvantage of global spectral simulation is that it traditionally cannot account for the local information such as the local continuity trends, which are often observed in reservoirs and hence are important to be accounted for in geologic models. This disadvantage has limited wider application of spectral simulation in building geologic models. In this paper, we present ways of conditioning geologic models to the relevant local information. To account for the local continuity trends, we first scale different frequency components of the original model with local-amplitude spectrum ratios that are specific to the local trend. The sum of these scaled frequency components renders a new model that displays the desired local continuity trend. The implementation details of this new method are discussed and examples are provided to illustrate the algorithm. 相似文献
47.
Adrian Lawrence Marianne Stuart Colin Cheney Neil Jones Richard Moss 《Hydrogeology Journal》2006,14(8):1470-1482
Contaminant migration behaviour in the unsaturated zone of a fractured porous aquifer is discussed in the context of a study site in Cheshire, UK. The site is situated on gently dipping sandstones, adjacent to a linear lagoon historically used to dispose of industrial wastes containing chlorinated solvents. Two cores of more than 100 m length were recovered and measurements of chlorinated hydrocarbons (CHCs), inorganic chemistry, lithology, fracturing and aquifer properties were made. The results show that selecting an appropriate vertical sampling density is crucial both to providing an understanding of contaminant pathways and distinguishing whether CHCs are present in the aqueous or non-aqueous phase. The spacing of such sampling should be on a similar scale to the heterogeneity that controls water and contaminant movement. For some sections of the Permo-Triassic aquifer, significant changes in lithology and permeability occur over vertical distances of less than 1 m and samples need to be collected at this interval, otherwise considerable resolution is lost, potentially leading to erroneous interpretation of data. At this site, although CHC concentrations were high, the consistent ratio of the two main components of the plume (tetrachloroethene and trichloroethene) provided evidence of movement in the aqueous phase rather than in dense non-aqueous phase liquid (DNAPL). 相似文献
48.
49.
Christopher D.K Herd Lars E BorgJohn H Jones James J Papike 《Geochimica et cosmochimica acta》2002,66(11):2025-2036
The oxygen fugacity of the Dar al Gani 476 martian basalt is determined to be quartz-fayalite-magnetite (QFM) −2.3 ± 0.4 through analysis of olivine, low-Ca pyroxene, and Cr-spinel and is in good agreement with revised results from Fe-Ti oxides that yield QFM −2.5 ± 0.7. This estimate falls within the range of oxygen fugacity for the other martian basalts, QFM −3 to QFM −1. Oxygen fugacity in martian basalts correlates with 87Sr/86Sr, 143Nd/144Nd, and La/Yb ratios, indicating that the mantle source of the basalts is reduced and that assimilation of crust-like material controls the oxygen fugacity. This allows constraints to be placed on the oxidation state of the martian mantle and on the nature of assimilated crustal material. The assimilated material may be the product of early and extensive hydrothermal alteration of the martian crust, or it may be amphibole- or phlogopite-bearing basaltic rock within the crust. In either case, water may play a significant role in the oxidation of basaltic magmas on Mars, although it may be secondary to assimilation of ferric iron-rich material. 相似文献
50.
Adrian Williams 《中国科学D辑(英文版)》2002,45(1):109-114
The paper describes Western Australian examples and causes of land degradation. It outlines shortcomings in the methodologies used to rehabilitate these areas. From this a protocol is suggested for an ‘holistic’ approach to land rehabilitation. 相似文献