Groundwater management in northern Iraq

Groundwater is vital and the sole resource in most of the studied region of northern Iraq. It has a significant role in agriculture, water supply and health, and the elimination of poverty in rural areas. Although Iraq is currently dramatically disturbed by complex political and socio-economic problems, in its northern part, i.e. the Kurdish-inhabited region, fast urbanization and economic expansion are visible everywhere. Monitoring and water management schemes are necessary to prevent aquifer over-exploitation in the region. Artificial recharge with temporary runoff water, construction of subsurface dams and several other aquifer management and regulation measures have been designed, and some implemented, in order to improve the water situation. Recommendations, presented to the local professionals and decision-makers in water management, include creation of Water Master Plans and Water User Associations, synchronization of drilling programmes, rehabilitation of the existing well fields, opening of new well fields, and the incorporation of new spring intakes in some areas with large groundwater reserves, as well as construction of numerous small-scale schemes for initial in situ water treatment where saline groundwater is present.     

Tellurium,selenium and cobalt enrichment in Neoproterozoic black shales,Gwna Group,UK: Deep marine trace element enrichment during the Second Great Oxygenation Event

Black shales of the late Neoproterozoic Gwna Group (570–580 Ma), UK, contain enrichments of tellurium (Te), selenium (Se) and cobalt (Co) relative to average shale compositions. The Te and Co enrichments bear comparison with those of ferromanganese crusts in the modern deep ocean. Gwna Group deposition coincides with the Second Great Oxidation Event, which had a significant effect on trace element fixation globally. Selenium and Te concentrations within these black shales indicate increased continental weathering rates, high biological productivity and corresponding increases in atmospheric O₂ concentrations. Cobalt, nickel (Ni) and arsenic (As) enrichments in this succession are secondary mineralisation phases. Demand for many of the trace elements found enriched in the Gwna Group black shales make their mechanisms of accumulation, and variations through the geological record, important to understand, and suggests that new resources may be sought based on black shale protoliths from this period.     

Seismic stratigraphy, buried beach ridges and contourite drifts: the Late Quaternary history of the closed Lago Cardiel basin, Argentina (49°S)

The results of a seismic stratigraphic analysis of a closed lake basin, Lago Cardiel, in southernmost South America are reported. Very few high-resolution, continental records spanning the Late Quaternary have been obtained from this region. Seismic sequence stratigraphic analysis allows a reconstruction of lake level variations. Two major hiatuses of unknown age occurred during the early evolution of the basin with the deposition of an alluvial fan in a restricted area in the intervening time period. Following the development of a relatively shallow lake during the late Pleistocene and a short desiccation pulse around 11 220 ¹⁴C yr BP, a transgression of over 135 m occurred at the beginning of the Holocene. The transgression was associated with the formation of beach ridges preserved in the lake stratigraphy on the floor of the modern Lago Cardiel at four different elevations. The preservation of largely unreworked beach ridges indicates a stepwise rise in the lake level. There is no seismic evidence of a major lowering of the lake below modern level during the entire Holocene. Deposition since the mid-Holocene is marked by strong lateral differences in sediment accumulation with a depocentre slightly to the north of the basin midpoint and a pronounced mounded distribution. Seismic reflection geometries, as well as sedimentological characteristics indicate a lacustrine contourite drift covering an area of 80–100 km². As Lago Cardiel is under the influence of westerly winds, these most likely drove lake circulation. The identification of drowned beach ridges and of contourite drifts illustrates that high-resolution seismic stratigraphy is not only a powerful tool in reconstructing past lake level elevations for closed lake basins, but it can also provide information about the rate of lake level changes and the presence and strength of lake currents.     

Trace element compositions of submicroscopic inclusions in coated diamond: A tool for understanding diamond petrogenesis

Trace element compositions of submicroscopic inclusions in both the core and the coat of five coated diamonds from the Democratic Republic of Congo (DRC, formerly Zaire) have been analyzed by Laser Ablation Inductively Coupled Mass Plasma Spectrometry (LA-ICP-MS). Both the diamond core and coat inclusions show a general 2-4-fold enrichment in incompatible elements relative to major elements. This level of enrichment is unlikely to be explained by the entrapment of silicate mantle minerals (olivine, garnet, clinopyroxene, phlogopite) alone and thus submicroscopic fluid or glass inclusions are inferred in both the diamond coat and in the gem quality diamond core. The diamond core fluids have elevated High Field Strength Element (Ti, Ta, Zr, Nb) concentrations and are enriched in U relative to inclusions in the diamond coats and relative to chondrite. The core fluids are also moderately enriched in LILE (Ba, Sr, K). Therefore, we suggest that the diamond cores contain inclusions of silicate melt. However, the Ni content and Ni/Fe ratio of the trapped fluid are very high for a silicate melt in equilibrium with mantle minerals; high Ni and Co concentrations in the diamond cores are attributed to the presence of a sulfide phase coexisting with silicate melt in the diamond core inclusions. Inclusions in the diamond coat are enriched in LILE (U, Ba, Sr, K) and La over the diamond core fluids and to chondrite. The coats have incompatible element ratios similar to natural carbonatite (coat fluid: Na/Ba ≈0.66, La/Ta≈130). The coat fluid is also moderately enriched in HFSE (Ta, Nb, Zr) when normalized to chondritic Al. LILE and La enrichment is related to the presence of a carbonatitic fluid in the diamond coat inclusions, which is mixed with a HFSE-rich hydrous silicate fluid similar to that in the core. The composition of the coat fluid is consistent with a genetic link to group 1 kimberlite.     

分支河流体系河网形态演变规律——以格尔木河流扇为例

为了探索分支河流体系河网分布规律,为创建储层建模训练图像提供知识库信息。利用Google Earth、Global Mapper、91卫图助手等现代地理信息软件,系统测量了现代格尔木河流扇表面河道分叉特征,应用Horton定律和分形方法建立了河流扇的河网形态模型。结果表明：①格尔木河流扇从顶点到入湖段共识别出26级河道,882个节点和2162个河道段,泉线上、下的河道表现出不同的河网形态;②泉线上部共发育64个节点,每级河道数目增长是上一级河道的RB=1.8900倍,每级河道平均长度是下一级河道的RL=1.0095倍,即河网形态特征参数RB=1.8900和RL=1.0095;泉线下部共发育818个节点,每级河道数目增长是上一级河道的RB=1.0279倍,每级河道平均长度是下一级河道的RL=0.9899倍,即河网形态特征参数是RB=1.0279和RL=0.9899;③河网形态特征参数受坡度影响变化较大,坡度较大则河网形态特征参数较大,坡度较小则河网形态特征参数较小。河网形态特征参数定量表征促进了分支河流体系沉积学发展,为开展陆相盆地储层建模和砂体预测提供了新的知识库信息     

High-pressure experimental growth of diamond using C–K2CO3–KCl as an analogue for Cl-bearing carbonate fluid

High-pressure, high-temperature diamond growth experiments have been conducted in the system C–K₂CO₃–KCl at 1050–1420 °C, 7.0–7.7 GPa. KCl is of interest because of the strong effect of halogens on the phase relations of carbonate-rich systems [Geophys. Res. Lett. 30 (2003) 1022] and because of the occurrence of KCl coexisting with alkali silicate–carbonate fluids in natural-coated diamond [Geochim. Cosmochim. Acta 64 (2000) 717]. We have used system C–K₂CO₃–KCl as an analogue for these mantle fluids in diamond growth experiments. The presence of KCl reduces the potassium carbonate liquidus to ≤1000 °C at 7.7 GPa, allowing it to act as a solvent catalyst for diamond growth at temperatures below the continental geotherm. This is a reduction on the minimum diamond growth temperature reported in the alkali-carbonate–C–O–H system [Lithos 60 (2002) 145]. Diamond growth using carbonate solvent catalysts is characterised by a relatively long induction period. However, the addition of KCl also reduced the period for diamond growth in carbonate to 5 min; no such induction period appears to be necessary. It is suggested that KCl destabilises carbonate, allowing greater solubility and diffusion of carbon.     

Automated AF-demagnetization on the 2G-Enterprises through-bore,cryogenic magnetometer

Since the early sixties, alternating field demagnetization (AFD) has been a standard laboratory technique for demagnetizing rocks to expose the multicomponent structure of their natural remanent magnetization (NRM). In the majority of AFD implementations, however, the procedure remains as labour-intensive as ever. The implementation that we have developed at the Australian Geological Survey Organisation, automates the procedure for AFD based on the static method, and results in significant productivity and efficiency gains without compromising data quality. A properly formulated procedure for static AFD may be the only method of retrieving higher-coercivity components of natural remanence in samples prone to developing gyroremanence at higher alternating fields (AFs). Our AFD environment comprises: a 2G-Enterprises through-bore, cryogenic magnetometer; 2G AF-coils and control equipment; and personal computer software, developed by us, to control all procedural aspects for a complete AFD of a sample including, importantly, a counteracting procedure to neutralize the effects of gyroremanence build-up at higher AFs. With our system, AFD of 8 samples/day, each of 20+ steps, requires only 20 min of user attention compared with a full day for conventional systems.     

Metropolitan growth and labor markets in Mexico

The objective of this paper is to examine the main changes in the metropolitan labor markets associated with economic restructuring in Mexico during the late 1980s and beginning of the 1990s. The analysis refers particularly to the four largest metropoles of the country, Mexico City, Guadalajara, Monterrey and Puebla, looking for common characteristics in their emergent employment structures now strongly differentiated in terms of rewards, stability in employment relations and conditions of access to jobs. The analysis reveals that largest metropolitan areas have been the most profoundly affected by the economic restructuring resulting from globalization, through a rapid de-industrialization and the expansion of the tertiary sector. Metropolitan labor markets in Mexico, at the time that show signs of social polarization in the formal sector, put in evidence a general process of precarization – less labor stability, replacement of permanent by part-time jobs, and increasing subcontracting –, segmentation of the labor force, and an increasing informal conditions of economic activities with small businesses and unskilled, temporarly and poorly paid jobs. The labor force segmentation and its more precarious and casual conditions are mostly explained by the impact of recent neoliberal policies, and recurrent economic crisis during the 1980s and 1990s which highly contributes to social inequality.     

Phase center modeling for LEO GPS receiver antennas and its impact on precise orbit determination

Most satellites in a low-Earth orbit (LEO) with demanding requirements on precise orbit determination (POD) are equipped with on-board receivers to collect the observations from Global Navigation Satellite systems (GNSS), such as the Global Positioning System (GPS). Limiting factors for LEO POD are nowadays mainly encountered with the modeling of the carrier phase observations, where a precise knowledge of the phase center location of the GNSS antennas is a prerequisite for high-precision orbit analyses. Since 5 November 2006 (GPS week 1400), absolute instead of relative values for the phase center location of GNSS receiver and transmitter antennas are adopted in the processing standards of the International GNSS Service (IGS). The absolute phase center modeling is based on robot calibrations for a number of terrestrial receiver antennas, whereas compatible antenna models were subsequently derived for the remaining terrestrial receiver antennas by conversion (from relative corrections), and for the GNSS transmitter antennas by estimation. However, consistent receiver antenna models for space missions such as GRACE and TerraSAR-X, which are equipped with non-geodetic receiver antennas, are only available since a short time from robot calibrations. We use GPS data of the aforementioned LEOs of the year 2007 together with the absolute antenna modeling to assess the presently achieved accuracy from state-of-the-art reduced-dynamic LEO POD strategies for absolute and relative navigation. Near-field multipath and cross-talk with active GPS occultation antennas turn out to be important and significant sources for systematic carrier phase measurement errors that are encountered in the actual spacecraft environments. We assess different methodologies for the in-flight determination of empirical phase pattern corrections for LEO receiver antennas and discuss their impact on POD. By means of independent K-band measurements, we show that zero-difference GRACE orbits can be significantly improved from about 10 to 6 mm K-band standard deviation when taking empirical phase corrections into account, and assess the impact of the corrections on precise baseline estimates and further applications such as gravity field recovery from kinematic LEO positions.