Evidence for centennial-scale Lateglacial and early Holocene climatic complexity from Quoyloo Meadow,Orkney, Scotland

The influence of the North Atlantic on the margins of Europe means the region is particularly sensitive to changes in the ocean–atmospheric system. During the Last Glacial–Interglacial Transition (16–8 cal ka bp ) this system was repeatedly disrupted, leading to a series of abrupt and short-lived shifts in climate. Despite much research, the number and magnitude of these ‘centennial-scale’ events is not well understood. To address this, we expand upon investigations at Quoyloo Meadow, Orkney, Scotland, one of the best chronologically constrained palaeoclimate records in northern Britain. By coupling stable isotope and chironomid fossil analyses with existing data, this study identifies multiple phases of centennial-scale disturbance at: c. 14.0, 11.1, 10.8, 10.5, 10.45 and 10.3 cal ka bp , with the events at 14.0 and 10.3 exhibiting a particularly pronounced cold-climate signature. During the Holocene, the strongest response to climate forcing was at c. 10.3–10.0 cal ka bp , expressed as a two-stage drop in mean July temperatures, a shift in pollen spectra indicative of ‘less-stable’ climatic regimes, and a depletion in δ¹⁸O values. We interpret this as the first reliably dated incidence of the ‘10.3-ka event’ in the British Isles and consider the wider impact of this climatic reversal in other Holocene records.     

New observations on high‐pressure phases in a shock melt vein in the Villalbeto de la Peña meteorite: Insights into the shock behavior of diopside

The petrology and mineralogy of shock melt veins in the L6 ordinary chondrite host of Villalbeto de la Peña, a highly shocked, L chondrite polymict breccia, have been investigated in detail using scanning electron microscopy, transmission electron microscopy, Raman spectroscopy, and electron probe microanalysis. Entrained olivine, enstatite, diopside, and plagioclase are transformed into ringwoodite, low‐Ca majorite, high‐Ca majorite, and an assemblage of jadeite‐lingunite, respectively, in several shock melt veins and pockets. We have focused on the shock behavior of diopside in a particularly large shock melt vein (10 mm long and up to 4 mm wide) in order to provide additional insights into its high‐pressure polymorphic phase transformation mechanisms. We report the first evidence of diopside undergoing shock‐induced melting, and the occurrence of natural Ca‐majorite formed by solid‐state transformation from diopside. Magnesiowüstite has also been found as veins injected into diopside in the form of nanocrystalline grains that crystallized from a melt and also occurs interstitially between majorite‐pyrope grains in the melt‐vein matrix. In addition, we have observed compositional zoning in majorite‐pyrope grains in the matrix of the shock‐melt vein, which has not been described previously in any shocked meteorite. Collectively, all these different lines of evidence are suggestive of a major shock event with high cooling rates. The minimum peak shock conditions are difficult to constrain, because of the uncertainties in applying experimentally determined high‐pressure phase equilibria to complex natural systems. However, our results suggest that conditions between 16 and 28 GPa and 2000–2200 °C were reached.     

Sedimentological analysis of two drill cores through the crater moat‐filling breccia,Flynn Creek impact structure,Tennessee

Sedimentological (line‐logging) analysis of two drill cores, FC77‐3 and FC67‐3, situated, respectively, in the northwestern and southeastern quadrants of the Flynn Creek impact structure's crater‐moat area reveals that the ~27 m thick crater moat‐filling breccia consists of three subequal parts. These parts, which were deposited during early modification stage of this marine‐target impact structure, are distinguished on the basis of vertical trends in sorting, grain size, and counts of clasts per meter in comparison with other well‐known marine‐target impact structures, namely Lockne, Tvären, and Chesapeake Bay. The lower part is interpreted to represent mainly slump deposits, and the middle part is interpreted to represent a stage intermediate between slump and marine resurge, that is, a traction flow driven by overriding suspension flow. The upper part (size graded, and relatively well sorted and fine grained) is interpreted to represent marine resurge flow only. The upper part is capped by a relatively thin and relatively fine‐grained calcarenite to calcisiltite deposit.     

Nanophase iron carbides in fine‐grained rims in CM2 carbonaceous chondrites: Formation of organic material by Fischer–Tropsch catalysis in the solar nebula

Transmission electron microscope studies of fine‐grained rims in three CM2 carbonaceous chondrites, Y‐791198, Murchison, and ALH 81002, have revealed the presence of widespread nanoparticles with a distinctive core–shell structure, invariably associated with carbonaceous material. These nanoparticles vary in size from ~20 nm up to 50 nm in diameter and consist of a core of Fe,Ni carbide surrounded by a continuous layer of polycrystalline magnetite. These magnetite shells are 5–7 nm in thickness irrespective of the diameter of the core Fe,Ni carbide grains. A narrow layer of amorphous carbon a few nanometers in thickness is present separating the carbide core from the magnetite shell in all the nanoparticles observed. The Fe,Ni carbide phases that constitute the core are consistent with both haxonite and cohenite, based on electron diffraction data, energy dispersive X‐ray analysis, and electron energy loss spectroscopy. Z‐contrast scanning transmission electron microscopy shows that these core–shell magnetite‐carbide nanoparticles can occur as individual isolated grains, but more commonly occur in clusters of multiple particles. In addition, energy‐filtered transmission electron microscopy (EFTEM) images show that in all cases, the nanoparticles are embedded within regions of carbonaceous material or are coated with carbonaceous material. The observed nanostructures of the carbides and their association with carbonaceous material can be interpreted as being indicative of Fischer–Tropsch‐type (FTT) reactions catalyzed by nanophase Fe,Ni metal grains that were carburized during the catalysis reaction. The most likely environment for these FTT reactions appears to be the solar nebula consistent with the high thermal stability of haxonite and cohenite, compared with other carbides and the evidence of localized catalytic graphitization of the carbonaceous material. However, the possibility that such reactions occurred within the CM parent body cannot be excluded, although this scenario seems unlikely, because the kinetics of the reaction would be extremely slow at the temperatures inferred for CM asteroidal parent bodies. In addition, carbides are unlikely to be stable under the oxidizing conditions of alteration experienced by CM chondrites. Instead, it is most probable that the magnetite rims on all the carbide particles are the product of parent body oxidation of Fe,Ni carbides, but this oxidation was incomplete, because of the buildup of an impermeable layer of amorphous carbon at the interface between the magnetite and the carbide phase that arrested the reaction before it went to completion. These observations suggest that although FTT catalysis reactions may not have been the major mechanism of organic material formation within the solar nebula, they nevertheless contributed to the inventory of complex insoluble organic matter that is present in carbonaceous chondrites.     

Revision of the Carboniferous cystoporate bryozoan Fistulipora incrustans (Phillips, 1836), with remarks on the type species of Fistulipora M'Coy, 1849

The type species of the Palaeozoic cystoporate bryozoan genus Fistulipora M'Coy, 1849 is redescribed. Fistulipora minor M'Coy, 1849 is the type species, and was the first species described under the genus Fistulipora. Quantitative assessment of type and figured specimens of Calamopora incrustans Phillips, 1836 and F. minor has shown them to fall within the range of morphological variation exhibited by abundant comparative material collected at several horizons and they are referable to one morphologically variable taxon. F. minor is the junior subjective synonym of C. incrustans and the form can be quoted as F. minor M'Coy, 1849 = C. incrustans Phillips, 1836 with a valid name of F. incrustans (Phillips, 1836). However, this does not alter the name of the type species, which is F. minor M'Coy, 1849. The type specimen of Berenicea megastoma M'Coy, 1844 has also been examined, and this form is also conspecific with F. minor M'Coy, 1849 = C. incrustans Phillips, 1836. Examination of the type specimen of F. major M'Coy (1849) has shown it to be referable to the tabulate coral genus Chaetetes. A lectotype and paralectotypes are designated for F. minor and the status of the type specimens of F. incrustans is clarified.     

Tectono-sedimentary evolution of Jurassic–Cretaceous diapiric structures: Miravete anticline,Maestrat Basin,Spain

Integration of extensive fieldwork, remote sensing mapping and 3D models from high-quality drone photographs relates tectonics and sedimentation to define the Jurassic–early Albian diapiric evolution of the N–S Miravete anticline, the NW-SE Castel de Cabra anticline and the NW-SE Cañada Vellida ridge in the Maestrat Basin (Iberian Ranges, Spain). The pre shortening diapiric structures are defined by well-exposed and unambiguous halokinetic geometries such as hooks and flaps, salt walls and collapse normal faults. These were developed on Triassic salt-bearing deposits, previously misinterpreted because they were hidden and overprinted by the Alpine shortening. The Miravete anticline grew during the Jurassic and Early Cretaceous and was rejuvenated during Cenozoic shortening. Its evolution is separated into four halokinetic stages, including the latest Alpine compression. Regionally, the well-exposed Castel de Cabra salt anticline and Cañada Vellida salt wall confirm the widespread Jurassic and Early Cretaceous diapiric evolution of the Maestrat Basin. The NE flank of the Cañada Vellida salt wall is characterized by hook patterns and by a 500-m-long thin Upper Jurassic carbonates defining an upturned flap, inferred as the roof of the salt wall before NE-directed salt extrusion. A regional E-W cross section through the Ababuj, Miravete and Cañada-Benatanduz anticlines shows typical geometries of salt-related rift basins, partly decoupled from basement faults. These structures could form a broader diapiric region still to be investigated. In this section, the Camarillas and Fortanete minibasins displayed well-developed bowl geometries at the onset of shortening. The most active period of diapiric growth in the Maestrat Basin occurred during the Early Cretaceous, which is also recorded in the Eastern Betics, Asturias and Basque-Cantabrian basins. This period coincides with the peak of eastward drift of the Iberian microplate, with speeds of 20 mm/year. The transtensional regime is interpreted to have played a role in diapiric development.     

Pteropods in Southern Ocean ecosystems

To date, little research has been carried out on pelagic gastropod molluscs (pteropods) in Southern Ocean ecosystems. However, recent predictions are that, due to acidification resulting from a business as usual approach to CO₂ emissions (IS92a), Southern Ocean surface waters may begin to become uninhabitable for aragonite shelled thecosome pteropods by 2050. To gain insight into the potential impact that this would have on Southern Ocean ecosystems, we have here synthesized available data on pteropod distributions and densities, assessed current knowledge of pteropod ecology, and highlighted knowledge gaps and directions for future research on this zooplankton group.Six species of pteropod are typical of the Southern Ocean south of the Sub-Tropical Convergence, including the four Thecosomes Limacina helicina antarctica, Limacina retroversa australis, Clio pyramidata, and Clio piatkowskii, and two Gymnosomes Clione limacina antarctica and Spongiobranchaea australis. Limacina retroversa australis dominated pteropod densities north of the Polar Front (PF), averaging 60 ind m⁻³ (max = 800 ind m⁻³) and 11% of total zooplankton at the Prince Edward Islands. South of the PF L. helicina antarctica predominated, averaging 165 ind m⁻³ (max = 2681 ind m⁻³) and up to >35% of total zooplankton at South Georgia, and up to 1397 ind m⁻³ and 63% of total zooplankton in the Ross Sea. Combined pteropods contributed <5% to total zooplankton in the Lazarev Sea, but 15% (max = 93%) to macrozooplankton in the East Antarctic. In addition to regional density distributions we have synthesized data on vertical distributions, seasonal cycles, and inter-annual density variation.Trophically, gymnosome are specialist predators on thecosomes, while thecosomes are considered predominantly herbivorous, capturing food with a mucous web. The ingestion rates of L. retroversa australis are in the upper range for sub-Antarctic mesozooplankton (31.2-4196.9 ng pig ind⁻¹ d⁻¹), while those of L. helicina antarctica and C. pyramidata are in the upper range for all Southern Ocean zooplankton, in the latter species reaching 27,757 ng pig ind⁻¹ d⁻¹ and >40% of community grazing impact. Further research is required to quantify diet selectivity, the effect of phytoplankton composition on growth and reproductive success, and the role of carnivory in thecosomes.Life histories are a significant knowledge gap for Southern Ocean pteropods, a single study having been completed for L. retroversa australis, making population studies a priority for this group. Pteropods appear to be important in biogeochemical cycling, thecosome shells contributing >50% to carbonate flux in the deep ocean south of the PF. Pteropods may also contribute significantly to organic carbon flux through the production of fast sinking faecal pellets and mucous flocs, and rapid sinking of dead animals ballasted by their aragonite shells. Quantification of these contributions requires data on mucous web production rates, egestion rates, assimilation efficiencies, metabolic rates, and faecal pellet morphology for application to sediment trap studies.Based on the available data, pteropods are regionally significant components of the Southern Ocean pelagic ecosystem. However, there is an urgent need for focused research on this group in order to quantify how a decline in pteropod densities may impact on Southern Ocean ecosystems.     

Compositions and microstructures of CB sulfides: Implications for the thermal history of the CB chondrite parent body

We studied textures and compositions of sulfide inclusions in unzoned Fe,Ni metal particles within CBa Gujba, CBa Weatherford, CBb HH 237, and CBb QUE 94411 in order to constrain formation conditions and secondary thermal histories on the CB parent body. Unzoned metal particles in all four chondrites have very similar metal and sulfide compositions. Metal particles contain different types of sulfides, which we categorize as: homogeneous low‐Cr sulfides composed of troilite, troilite‐containing exsolved daubreelite lamellae, arcuate sulfides that occur along metal grain boundaries, and shock‐melted sulfides composed of a mixture of troilite and Fe, Ni metal. Our model for formation proposes that the unzoned metal particles were initially metal droplets that formed from splashing by a partially molten impacting body. Sulfide inclusions later formed as a result of precipitation of excess S from solid metal at low temperatures, either during single stage cooling or during a reheating event by impacts. Sulfides containing exsolution lamellae record temperatures of ?600 °C, and irregular Fe‐FeS intergrowth textures suggest localized shock melting, both of which are indicative of heterogeneous heating by impact processes on the CB parent body. Our study shows that CBa and CBb chondrites formed in a similar environment, and also experienced similar secondary impact processing.     

Distribution and spatial variation of hydrothermal faunal assemblages at Lucky Strike (Mid-Atlantic Ridge) revealed by high-resolution video image analysis

Whilst the fauna inhabiting hydrothermal vent structures in the Atlantic Ocean is reasonably well known, less is understood about the spatial distributions of the fauna in relation to abiotic and biotic factors. In this study, a major active hydrothermal edifice (Eiffel Tower, at 1690 m depth) on the Lucky Strike vent field (Mid-Atlantic Ridge (MAR)) was investigated. Video transects were carried out by ROV Victor 6000 and complete image coverage was acquired. Four distinct assemblages, ranging from dense larger-sized Bathymodiolus mussel beds to smaller-sized mussel clumps and alvinocaridid shrimps, and two types of substrata were defined based on high definition photographs and video imagery. To evaluate spatial variation, faunal distribution was mapped in three dimensions. A high degree of patchiness characterizes this 11 m high sulfide structure. The differences observed in assemblage and substratum distribution were related to habitat characteristics (fluid exits, depth and structure orientation). Gradients in community structure were observed, which coincided with an increasing distance from the fluid exits. A biological zonation model for the Eiffel Tower edifice was created in which faunal composition and distribution can be visually explained by the presence/absence of fluid exits.     

Phase center modeling for LEO GPS receiver antennas and its impact on precise orbit determination

Most satellites in a low-Earth orbit (LEO) with demanding requirements on precise orbit determination (POD) are equipped with on-board receivers to collect the observations from Global Navigation Satellite systems (GNSS), such as the Global Positioning System (GPS). Limiting factors for LEO POD are nowadays mainly encountered with the modeling of the carrier phase observations, where a precise knowledge of the phase center location of the GNSS antennas is a prerequisite for high-precision orbit analyses. Since 5 November 2006 (GPS week 1400), absolute instead of relative values for the phase center location of GNSS receiver and transmitter antennas are adopted in the processing standards of the International GNSS Service (IGS). The absolute phase center modeling is based on robot calibrations for a number of terrestrial receiver antennas, whereas compatible antenna models were subsequently derived for the remaining terrestrial receiver antennas by conversion (from relative corrections), and for the GNSS transmitter antennas by estimation. However, consistent receiver antenna models for space missions such as GRACE and TerraSAR-X, which are equipped with non-geodetic receiver antennas, are only available since a short time from robot calibrations. We use GPS data of the aforementioned LEOs of the year 2007 together with the absolute antenna modeling to assess the presently achieved accuracy from state-of-the-art reduced-dynamic LEO POD strategies for absolute and relative navigation. Near-field multipath and cross-talk with active GPS occultation antennas turn out to be important and significant sources for systematic carrier phase measurement errors that are encountered in the actual spacecraft environments. We assess different methodologies for the in-flight determination of empirical phase pattern corrections for LEO receiver antennas and discuss their impact on POD. By means of independent K-band measurements, we show that zero-difference GRACE orbits can be significantly improved from about 10 to 6 mm K-band standard deviation when taking empirical phase corrections into account, and assess the impact of the corrections on precise baseline estimates and further applications such as gravity field recovery from kinematic LEO positions.