Mercury cycling during acid rain recovery at the forested Lesní potok catchment,Czech Republic

From 2011 to 2019, mercury (Hg) stores and fluxes were studied in the small forested catchment Lesní potok (LES) in the central Czech Republic using the watershed mass balance approach together with internal measurements. Mean input fluxes of Hg via open bulk deposition, beech throughfall and spruce throughfall during the periodwere 2.9, 3.9 and 7.6 μg m⁻² year⁻¹, respectively. These values were considerably lower than corresponding deposition Hg fluxes reported in the early years of the 21st century from catchments in Germany. Current bulk precipitation inputs at unimpacted Czech mountainous sites were lower than those in Germany. The largest Hg inputs to the catchment were via litterfall, averaging 22.6 and 17.8 μg m⁻² year⁻¹ for beech and spruce stands. The average Hg input, based on the sum of mean litterfall and throughfall deposition, was 23.0 μg m⁻² year⁻¹, compared to the estimated Hg output in runoff of 0.5 μg m⁻² year⁻¹, which is low compared to other reported values. Thus, only ~2% of Hg input is exported in stream runoff. Stream water Hg was only weakly related to dissolved organic carbon (DOC) but both concentrations were positively correlated with water temperature. The estimated total soil Hg pool averaged 47.5 mg m⁻², only 4% of which was in the O-horizon. Thus Hg in the O-horizon pool represents 72 years of deposition at the current input flux and 3800 years of export at the current runoff flux. Age-dating by ¹⁴C suggested that organic soil contains Hg from recent deposition, while mineral soil at 40–80 cm depth contained 4400-year old carbon, suggesting the soil had accumulated atmospheric Hg inputs through millennia to reach the highest soil Hg pool of the soil profile. These findings suggest that industrial era intensification of the Hg cycle is superimposed on a slower-paced Hg cycle during most of the Holocene.     

Upper Oligocene-Lower Miocene shallowing-upwardlacustrine sequences controlled by periodic and non-periodic processes(Ebro Basin, northeastern Spain)

The lacustrine facies from two sections (Candasnos and Fraga) ofthe Oligocene-Miocene Torrente de Cinca lithostratigraphic Unit in thecentral part of the Ebro Basin (Spain) have been analysed to determine theinfluence of orbital parameters in lacustrine sedimentation. The unit ispredominantly composed of limestones and marls, and represents a shallowlacustrine freshwater system. The sedimentological features of the faciesstudied demonstrate that the lower part of the Candasnos section representsoffshore lacustrine subenvironments whereas the upper part, and the whole ofthe Fraga section, characterise marginal lacustrine areas. Series of stratalthickness variations of limestone, marl, and limestone/marl couplets fromboth sections have been analysed using spectral analysis. This shows thatinformation corresponding to periodic cycles only appears in the offshorefacies, that is to say, in the lower part of Candasnos section, and disappearsin the marginal facies where non-periodic cycles exist. Furthermore, thespectral analysis of the offshore facies highlights the existence of a peak inthe power spectrum with a period of around 7 (6.8 to 7.8) that can berecognised in the field as shallowing-upward lacustrine sequences.Magnetostratigraphic data from the Candasnos section allow us to establish atime span of 2,808 years for the limestone/marl couplet from the lower partof this section, and between 19,000 and 22,000 years for the periodic cycleidentified, thus representing the climatic precession cycle. Shallowingsequences from marginal areas do not correspond with any periodiccycle.     

The ion-composition of the plasma produced by impacts of fast dust particles

The composition of the impact plasma produced by fast dust particles (v > 1 km/sec) hitting an Au or W target was measured both with a model of the HELIOS micrometeoroid experiment (low electric field at the target) and a high field detector. The plasma composition and the total plasma charge depend strongly on the impact velocity and the electric field strength at the target. Spectra of 9 different projectile-target combinations were analysed. Two types of spectra could be observed, depending on the projectile material. (1) Spectra of metals and hard dielectrics (Mohs' hardness ? 5). Particle constituents of low ionisation energy (e · u ? 7eV, e.g. Na, K, Al) dominate the spectra of these materials at impact velocities below 10 km/sec. At higher speed the relative intensities change and new ions with higher ionisation energies appear. (2) Spectra of soft dielectrics (Mohs' hardness < 3). Below 9 km/sec these materials produced less total charge than did the others. The highest masses were detected at 74 amu. The relative abundance of ions with low ionization energies such as Li, Na, K, etc. is comparatively small. Negative ions were also observed in the impact plasma. Their total number was found to be approximately 3–6% of that of the positive ions at 6 km/sec particle speed.     

Morphometric and geological conditions for sediment accumulation in the Udava River,Outer Carpathians,Slovakia

The accumulation of sediment in river channels is a phenomenon that is not only influenced by the channel morphology, but also by the physical and geographical characteristics and the endogenous and exogenous processes taking place in the catchment. This paper presents an analysis of the impact the changes in lithological conditions have on the morphological and morphometric parameters of the Udava River channel and their relation to the channel accumulation forms representative of the river’s longitudinal profile as well as of its planform. Results document when accumulation forms occur and what is their spatial distribution within the longitudinal and cross-sectional river profiles. More resistant structures created sections with a lower degree of sedimentation, while in depression segments the degree of sedimentation was higher. With the increase in longitudinal slope, the impact of channel width on the average channel bar size increased. Also a difference in the accumulation was observed between the left and right bank which could be possibly explained by the impact of Coriolis force.     

Trapping and adsorption of CO2 in amorphous ice: A FTIR study

The interaction of carbon dioxide and amorphous water ice at 95 K is studied using transmission infrared spectroscopy. Samples are prepared in two ways: co-deposition of the gases admitted simultaneously or sequential deposition, in which amorphous water ice (ASW) is grown first and CO₂ vapor is added subsequently. In either case, a fraction of the CO₂ molecules is found to interact with water in a way that gives rise to shifts and splittings in the infrared bands with respect to those of a pure CO₂ solid. In co-deposition experiments, a larger amount of carbon dioxide is trapped within the amorphous water than in sequential deposition samples, where a substantial proportion of molecules appears to be trapped in macropores of the ASW. The specific surface area of sequential samples is evaluated and compared to previous literature results. When the sequential samples are heated to 140 K, beyond the onset temperature at which water ice undergoes a phase transition, the CO₂ molecules at the pores relocate inside the bulk in a structure similar to that found in co-deposited samples, as deduced by changes in the shape of the CO₂ infrared bands.     

Groundwater flow regime under natural conditions as inferred from past evidence and contemporary field observations in a semi-arid basin: Cuenca de la Independencia, Guanajuato, México

This study was carried out in the Cuenca de la Independencia, a semi-arid basin in Central Mexico. The objective is to describe the main features of a groundwater flow regime under natural conditions, based on groundwater discharge manifestations. Information obtained from paleoecological, paleontological, archaeological and historical data suggests that, prior to heavy development (starting in the 1950s), the hydrogeologic regime was characterized by a larger groundwater availability in a more humid and colder climate. Manifestations associated to groundwater discharges are springs, lagoons, wetlands, saline soils, chalcedony deposits, phreatophytes, thermalism, and artesianism. The different types of manifestations and their position in the basin indicate the influence of groundwater flow systems hierarchically nested, forming concentric zones at ground level. The groundwater flow regime corresponds to a classical gravity-induced flow system with generation of local, intermediate and regional patterns. Integrating several types of data to establish the flow geometry and its dynamics has proven a useful tool to increase understanding of the original groundwater regimes. This approach can also be applied in other over-exploited semi-arid basins.     

On the use of logistic regression for stellar classification

We are totally immersed in the Big Data era and reliable algorithms and methods for data classification are instrumental for astronomical research. Random Forest and Support Vector Machines algorithms have become popular over the last few years and they are widely used for different stellar classification problems. In this article, we explore an alternative supervised classification method scarcely exploited in astronomy, Logistic Regression, that has been applied successfully in other scientific areas, particularly biostatistics. We have applied this method in order to derive membership probabilities for potential T Tauri star candidates from ultraviolet-infrared colour-colour diagrams.     

On the Dynamic Disconnection of Rising Omega Loops

The tilt-angle variation of solar bipolar magnetic regions (BMRs) in space and time is a probable indicator of large-scale properties of magnetic field distribution, the dynamo and other different processes affecting the rising of magnetic flux tubes. We analyze the tilt-angle distribution and evolution of clearly oriented BMRs using sunspot position and area measurements from the Greenwich Photo-Heliographic Results (GPHR) supplemented by high-quality full-disk sunspot drawings made in the Haynald Observatory in Hungary. Our work is made on the basis of the 14th sunspot cycle and we compare our results with present theories of magnetic flux evolution in the convective zone. Our results support the assumption that the scatter of tilt angles of BMRs around Joy`s law is determined by the convective turbulence. Furthermore, we find that regular BMRs grouped by age generally do not show the phenomenon of toroidal relaxation towards the east–west direction. We interpret this by the disconnection of -loops from the bottom of the convection zone.