Kinetics of DTPA extraction of Zn,Pb, and Cd from contaminated calcareous soils amended with sewage sludge

The aim of this study was to determine the influence of sewage sludge (SLU) amendment on the desorption characteristics of zinc (Zn), lead (Pb), and cadmium (Cd) in contaminated calcareous soils. Three levels of SLU (0, 1, and 3% w/w) were added to the two calcareous contaminated soils. Samples were incubated for 30 days and equilibrated with 0.005 M DTPA for 0.25 to 240 h. The addition of SLU significantly increased the amount of DTPA-extractable Zn in soils. While the amounts of Cd, Pb, dissolved organic carbon (DOC), and pH showed a significant increase only in 3% w/w of SLU, with the exception of Cd desorption in 1% w/w of SLU, kinetics of Zn, Pb, and Cd extraction increased together with an increase in the level of applied SLU. The best models for describing desorption data were explicitly power function and Elovich. The rate constants of Zn and Pb had significant correlations with DTPA-extractable Zn and Pb, DOC and pH, which affect Zn and Pb desorption. Also, the rate constants of Cd had significant correlations with CEC that can be deemed as equivalent to the fact that Cd desorption is controlled by surface adsorption, particularly in the lower sludge application amount. These results can be used for management of sewage sludge application in contaminated calcareous soils.     

Laboratory measurements of vortex-induced sediment pickup rates

In the present study,vortices were generated in open channel flow with a cross-flow cylinder installed horizontally near the bed.Sediment pickup rates were then measured over the channel bed downstream the cylinder using a sediment lift.The experimental data show that the pickup rate increases exponentially in the presence of vortices.Two different relationships can be clearly observed between the pickup rate and the maximum root-mean-square (rms) value of the streamwise velocity fluctuation,one for the cylinder-obstructed flow and the other for the unobstructed flow.The results imply that the vortex-induced sediment pickup cannot be explained based on the traditional boundary layer theory.     

An assessment of the utilization of waste resources for the immobilization of Pb and Cu in the soil from a Korean military shooting range

Military shooting range soils contaminated by heavy metals have been subjected to remediation efforts to alleviate the detrimental effects of exposure on humans and the surrounding environment. Waste materials can be used as cost-effective soil amendments to immobilize heavy metals in contaminated soils. In this study, naturally occurring lime-based waste materials including egg shells, oyster shells, and mussel shells were assessed for their effectiveness toward heavy metal immobilization in military shooting range soil in Korea. Soil was treated in batch leaching experiments with 0, 2.5, 5, 10, and 15% of each lime-based waste material. The results showed that the lime-based waste materials effectively reduced water-soluble Pb at an application rate of 2.5% by weight of the soil. Increase in soil pH from 6.6 to 8.0 was considered to be the main chemistry of Pb immobilization, which was supported by the formation of insoluble Pb species at high pH values as confirmed by the visual MINTEQ thermodynamic model. In contrary, water-soluble Cu was increased in the lime-based waste material-treated soils when compared to the untreated soil. This was likely attributed to the formation of soluble Cu?CDOC (dissolved organic carbon) complexes as all lime-based waste materials applied increased DOC contents in the soil. Therefore, care must be taken in selecting the appropriate amendment for immobilizing metals in shooting range soils.     

Anthropogenic and natural effects on the water and sediments qualities of costal lagoons: case of the Boughrara Lagoon (Southeast Tunisia)

The Boughrara Lagoon located in southern Tunisia shows evidence of eutrophication and the deterioration of water quality. The large amount of water shown to exchange tidally between the lagoon and the open sea suggests that while water per se is important and observed eutrophication problems are not caused by a lack of water. Heavy metal concentrations in surface sediments of the lagoon indicate that the ecosystem degradation is most likely related to the discharge of untreated phosphogypsum. Excessive pumping from the local freshwater aquifer that previously supplied freshwater to the lagoon via sub-aquatique fractures is likely to be a significant factor contributing to the water and sediment quality degradation of Boughrara Lagoon.     

Dokhan volcanics of Gabal Monqul area,North Eastern Desert,Egypt: geochemistry and petrogenesis

The Dokhan volcanics are represented by a thick stratified lava flows succession of basalt, andesite, imperial porphyry, dacite, rhyodacite, rhyolite, ignimbrites, and tuffs. These lavas are interbanded with their pyroclastics in some places including banded ash flow tuffs, lithic tuffs, crystal lapilli tuffs, and agglomerates. They are typical calc–alkaline and developed within volcanic arc environment. All rocks show moderate enrichment of most large ion lithophile elements relative to high field strength elements (HFSE). The incompatible trace elements increase from basalt through andesite to rhyolite. The felsic volcanics are characterized by moderate total rare earth elements (REE) contents (162 to 392 ppm), less fractionated patterns {(Ce/Yb)_N = (1.24 to 10.93)}, and large negative Eu anomaly {(Eu/Eu*) = (0.15 to 0.92)}. The mafic volcanics have the lowest REE contents (61 to 192 ppm) and are relatively steep {(Ce/Yb)_N = (3.2 to 8.5)}, with no negative Eu anomalies {(Eu/Eu*) = (0.88 to 1)}. The rhyolite displays larger negative Eu anomaly (Eu/Eu* = 0.28) than those of other varieties, indicating that the plagioclase was an early major fractionating phase. The mineralogical and chemical variations within volcanics are consistent with their evolution by fractional crystallization of plagioclase and clinopyroxene.     

Basin analysis study of block 10 in the Say'un-Masilah Basin, Yemen, using a 1D backstripping method

Geohistory analysis was carried out on block 10 in the Say??un-Masilah Basin. The present study is based on the analysis of the well logs of six exploration wells. In the Middle Jurassic to the Middle Eocene, Say??un-Masilah Basin exhibited a complex subsidence history over a period of about 155?Ma. Backstripped subsidence curves are constructed by removing the effects of decompaction to the water column and sediment loads. In the Middle Jurassic, slow subsidence was driven under the effect of sediment load as Kuhlan and Shuqra Formations were deposited as pre-rift deposits. The average total subsidence value of the basement during the deposition of Shuqra Formation was 276?m. The highest subsidence rates during this time are observed northeast of the study area. Rapid subsidence initiated in the Upper Jurassic driven by mechanical extension of the rift, resulting in the deposition of Madbi and Safer Formations, or the so-called Syn-rift deposits. The average tectonic subsidence value of the basements during the deposition of Madbi Formation was 368?m. The highest subsidence rates during this time are observed southwest of the study area. Mechanical extension ceased at about 145?Ma, being replaced by a phase of post-rift subsidence, resulting in more widespread uniform sedimentation, with reduced tectonic subsidence rates forming post-rift deposits represented by Nayfa Formation, Sa??ar Formation, Biyad Formation, and Mahra Group. The total subsidence value of the basement during the deposition of the post-rift sediments increases gradually due to the increase of the sediment load as the rate of deposition was high especially northeast of the area.     

Petrophysical,seismic structural and facies analysis of the Miocene reservoirs of East Morgan oil field,Gulf of Suez,Egypt

The Gulf of Suez is characterized by the presence of many hydrocarbon-bearing fields including reservoirs ranging in age from the Palaeozoic to the Tertiary. East Morgan oil field is one of the promising oil fields which are located in the southern part of the Gulf of Suez and tapping hydrocarbon deposits and potentials of the Miocene age. The purpose of this work is to evaluate the Miocene sediments of the Asl and Hawara Formations in East Morgan oil field (western sub-basin) through carrying out an integrated petrophysical, seismic structural and sequence stratigraphy study. Quantitative well logging analyses are carried out over Asl and Hawara Formations to throw light over their hydrocarbon potentiality. Good oil saturation is exhibited by the sand sections of Asl Formation, and fair to good are assigned for those of Hawara Formation in the Belayim dip province. On the other hand, a little hydrocarbon saturation is represented by both formations to the south of the study area in the Morgan accommodation zone (MAZ). The estimated petrophysical parameters of Asl reservoir throughout the study area range between 4 % and 10 % for effective porosity, 18 % and 89 % for shale volume and 2 % and 48 % for hydrocarbon saturation. Meanwhile, the ranges of 1–8 %, 20–98 % and 2–32 % are given for Hawara Formation for effective porosity, shale volume and hydrocarbon saturation, respectively. The lateral distribution maps show that the central and the western parts of the MAZ attain the best petrophysical parameters and hydrocarbon potentiality. Seismic facies analysis, structural framework and depositional history of the study area were studied through interpreting the seismic reflection data of 27 seismic profiles. A number of geo-seismic cross sections are constructed and interpreted to investigate the structural setting of the study area and clarify the main structural elements that affect the hydrocarbon bearing reservoirs. A group of simple NW–SE step-like normal faults, parallel to the Clysmic trend, is found cutting through the reservoir rocks at the bottom layers of the section (Rudeis Formation) and extending upwards to overlying layers (Zeit Formation). Some graben- and horst-shaped structures are found and usually bounded by two sets of oppositely dipping normal step-like cross faults. The seismic facies and sequence analysis revealed that the Miocene rocks are subdivided into two major third-order depositional sequences (S1 and S2), separated by two major depositional sequence boundaries (DSB1 and DSB2). The first sequence (S1, Lower–Middle Miocene rocks) is of prime interest, as it encounters the main hydrocarbon reservoirs in the study area (Asl and Hawara Formations that are equivalent to Rudeis Formation). The seismic facies of this sequence are characterized by low to moderate amplitude, discontinuous horizons and bounded by the depositional sequence boundary (DSB1) at the top. The reflection geometry at the cycle boundaries is considered as erosional truncation, toplaps and even concordant along the upper boundary of the cycle. The external form of these sediments is considered as sheet-like and wedge-shaped units. The entrapment of hydrocarbons seems to be of a combined effect of the stratigraphic and structural elements. It appears clear that both of the step-like structural fault system and the lateral variation of facies are the key parameters that control the accumulation of hydrocarbon in this area and in East Morgan field as a whole.