Extended statistical entropy analysis for the evaluation of nitrogen budgets in Austria

Extended statistical entropy analysis (eSEA) is used to evaluate the nitrogen (N) budgets of two Austrian catchments, the Wulka and the Ybbs, and of entire Austria. The eSEA quantifies the extent of N dispersion in the environment. The results from the eSEA are compared to the corresponding N use efficiencies (NUEs). Application of the eSEA reveals that the Ybbs catchment, compared to the Wulka catchment leads to a greater extent of N dispersion, primarily as a result of increased losses of N compounds to the atmosphere and in leachates to the groundwater. The NUE in the Wulka catchment, at 63 %, is substantially higher than that in the Ybbs catchment, at 43 %, and confirms a more efficient N use in Wulka. Furthermore, it is shown that the adoption of a healthy, balanced diet, as defined by the German Nutrition Society, changes the N budget of Austria in a way that significantly reduces the dispersion of N. Decreased N losses to the atmosphere and to the groundwater are primarily responsible for this result. The national NUE of Austria responds only moderately to the adoption of such a diet increasing from 48 to 53 % and leads to statistically insignificant results if the uncertainty of the input data is taken into account. This study demonstrates the effectiveness of eSEA for the evaluation of N budgets in agricultural regions and suggests that statistical entropy can serve as a reliable agri-environmental indicator to support decisions regarding nutrient management.     

Enhancement of deltamethrin degradation by soil bioaugmentation with two different strains of Serratia marcescens

Deltamethrin is one of the most commonly used pyrethroid in agricultural practice in different geographic regions of the world. It is detected in many environments, especially in soil and water, and can exhibit toxic effect to human and other organisms. In this study, we describe two bacterial strains DeI-1 and DeI-2, isolated from soil, and both identified as Serratia marcescens based on profile of the fatty acid methyl esters, biochemical test, and 16S RNA gene analysis, which were shown to efficiently degrade deltamethrin. Degradation of deltamethrin in mineral salt medium (50 mg l^?1) proceeded by strains DeI-1 or DeI-2 reached the values of 88.3 or 82.8 % after 10 days, and DT50 was 2.8 or 4.0 days, respectively. Bioaugmentation of deltamethrin-contaminated non-sterile soils (100 mg kg^?1) with strains DeI-1 or DeI-2 (3 × 10⁶ cells g^?1 of soil) enhanced the disappearance rate of pyrethroid, and its DT50 was reduced by 44.9, 33.1, 44.4, and 58.2 days or 39.1, 25.8, 35.6, and 46.0 days in sandy, sandy loam, silty loam, and silty soils, respectively, in comparison with non-sterile soils with only indigenous microflora. The three-way ANOVA indicated that DT50 of deltamethrin was significantly (P < 0.01) affected by soil type, microflora presence, and inoculum, and the interaction between these factors. Generally, the lower content of clay and organic carbon in soil, the higher degradation rate of deltamethrin was observed. Obtained results show that both strains of S. marcescens may possess potential to be used in bioremediation of deltamethrin-contaminated soils.     

Photometric and spectrophotometric observations of Nova Delphini 1967

Photographic, photovisual and photoelectric (V) observations of Nova Delphini 1967 were made from August 8 to October 31 (Table I, Figure 1). Simultaneously spectrophotometric measurements of the continuum were made on objective prism exposures extending to November 26, and spectrophotometric gradients derived (Tables II and III; Figures 3, 4, and 5). The continuum of Nova near its flat maximum is close to that of an early-type star in contrast to late-type absorptionline spectrum.     

The formation of Ganymede's grooved terrain: Numerical modeling of extensional necking instabilities

Ganymede's grooved terrain likely formed during an epoch of global expansion, when unstable extension of the lithosphere resulted in the development of periodic necking instabilities. Linear, infinitesimal-strain models of extensional necking support this model of groove formation, finding that the fastest growing modes of an instability have wavelengths and growth rates consistent with Ganymede's grooves. However, several questions remain unanswered, including how nonlinearities affect instability growth at large strains, and what role instabilities play in tectonically resurfacing preexisting terrain. To address these questions we numerically model the extension of an icy lithosphere to examine the growth of periodic necking instabilities over a broad range of strain rates and temperature gradients. We explored thermal gradients up to 45 K km⁻¹ and found that, at infinitesimal strain, maximum growth rates occur at high temperature gradients (45 K km⁻¹) and moderate strain rates (10⁻¹³ s⁻¹). Dominant wavelengths range from 1.8 to 16.4 km (post extension). Our infinitesimal growth rates are qualitatively consistent with, but an order of magnitude lower than, previous linearized calculations. When strain exceeds ∼10% growth rates decrease, limiting the total amount of amplification that can result from unstable extension. This fall-off in growth occurs at lower groove amplitudes for high-temperature-gradient, thin-lithosphere simulations than for low-temperature-gradient, thick-lithosphere simulations. At large strains, this shifts the ideal conditions for producing large amplitude grooves from high temperature gradients to more moderate temperature gradients (15 K km⁻¹). We find that the formation of periodic necking instabilities can modify preexisting terrain, replacing semi-random topography up to 100 m in amplitude with periodic ridges and troughs, assisting the tectonic resurfacing process. Despite this success, the small topographic amplification produced by our model presents a formidable challenge to the necking instability mechanism for groove formation. Success of the necking instability mechanism may require rheological weakening or strain localization by faulting, effects not included in our analysis.     

Groundwater dating with 3H and SF6 in relation to mixing patterns,transport modelling and hydrochemistry

A comprehensive study of a sandy aquifer of deltaic origin in southern Poland included water chemistry, isotopes, dissolved trace gases and transport modelling. Tritium, sulphur hexafluoride (SF₆) and freons (F‐11, F‐12 and F‐113) showed the presence of modern waters in the recharge areas and shallow confined parts of the aquifer. The presence of older Holocene waters farther from the recharge areas was indicated by lack of ³H, SF₆ contents ≤0·02 fmol l⁻¹ and relatively low ¹⁴C values. The discharge from the system is by upward seepage in the valley of a major river. Pre‐Holocene waters of a cooler climate, identified on the basis of δ¹⁸O, δ²H, ¹⁴C, Ne and Ar data, were found in some distant wells. Concentrations of N₂, Ne and Ar determined by gas chromatography were used for calculating the noble gas temperatures, air excess needed for correction of SF₆, and nitrogen content released by denitrification process. The time series of ³H content available for some wells supplied quantitative information on age distributions and the total mean ages of flow through the unsaturated and saturated zones. The derived ³H age distributions turned out to be very wide, with mean values in the range of about 30 to 160 years. For each well with determined ³H age, the SF₆ data showed either a lower age range or the possibility of a lower age as expected due to shorter travel times of SF₆ through the unsaturated zone, which most probably also resulted in different types of age distributions of these tracers. Freons appeared to be of little use for individual age determinations. A quantitative estimation of two‐component mixing from SF₆ ³H relations is not possible unless the travel time of ³H through the unsaturated zone is comparable to that of SF₆. The ratio of integrals of the response function over the age range with tracer and the whole response function yields the ratio of water with tracer to total flow of water. That ratio is a tracer‐dependent function of time. Transport modelling of SF₆ tracer done with MT3D code yielded initially large discrepancies between calculated and measured tracer concentrations. Some discrepancies remained even after calibration of the transport model with SF₆. Simulation of tritium contents with a calibrated transport model yielded reasonable agreement with measured contents in some wells and indicated a need for further investigations, particularly in the eastern part of the aquifer. The existence of distinct hydrochemical zones is consistent with the tracer data; young waters with measurable ³H and SF₆ contents are aerobic and of HCO₃ Ca or HCO₃ SO₄ Ca types. Slightly elevated Na and Cl contents, as well as the highest concentrations of SO₄ and NO₃ within this zone are due to anthropogenic influences. Anaerobic conditions prevail in the far field, under the confining cover, where pre‐bomb era Holocene waters dominate. In that zone, dissolved oxygen, NO₃ and U contents are reduced, and Fe, Mn and NH₄ contents increase. In the third zone, early Holocene and glacial waters occur. They are of HCO₃ Ca Na or HCO₃ Na types, with TDS values higher than 1 g l⁻¹ and Na content higher than 200 mg l⁻¹, due to either small admixtures of ascending or diffusing older water or freshening of marine sediments, a process that is probably occurring till the present time. Copyright © 2005 John Wiley & Sons, Ltd.     

Physics of accretion in the millisecond pulsar XTE J1751 − 305

We have undertaken an extensive study of X-ray data from the accreting millisecond pulsar XTE J1751 − 305 observed by RXTE and XMM–Newton during its 2002 outburst. In all aspects this source is similar to the prototypical millisecond pulsar SAX J1808.4 − 3658, except for the higher peak luminosity of 13 per cent of Eddington, and the optical depth of the hard X-ray source, which is larger by a factor ∼2. Its broad-band X-ray spectrum can be modelled by three components. We interpret the two soft components as thermal emission from a colder  ( kT ∼ 0.6 keV)  accretion disc and a hotter (∼1 keV) spot on the neutron star surface. We interpret the hard component as thermal Comptonization in plasma of temperature ∼40 keV and optical depth ∼1.5 in a slab geometry. The plasma is heated by the accretion shock as the material collimated by the magnetic field impacts on to the surface. The seed photons for Comptonization are provided by the hotspot, not by the disc. The Compton reflection is weak and the disc is probably truncated into an optically thin flow above the magnetospheric radius. Rotation of the emission region with the star creates an almost sinusoidal pulse profile with an rms amplitude of 3.3 per cent. The energy-dependent soft phase lags can be modelled by two pulsating components shifted in phase, which is naturally explained by a different character of emission of the optically thick spot and optically thin shock combined with the action of the Doppler boosting. The observed variability amplitude constrains the hotspot to lie within 3°–4° of the rotational pole. We estimate the inner radius of the optically thick accreting disc to be about 40 km. In that case, the absence of emission from the antipodal spot, which can be blocked by the accretion disc, gives the inclination of the system as ≳70°.     

Propagation of magnetoacoustic-gravity waves in a horizontally-stratified medium: IV. kinematics

A model magneto-atmosphere is used to discuss the behavior of the group velocity for magnetoacoustic-gravity (MAG) waves as a function of their angular frequency. The qualitative frequency/time history of a signal generated by a source differs significantly from the case where the magnetic field is zero, for which a clear distinction may be made between the acoustic and gravity components of the signal.