甘露醇对石墨存在下Cs_2BO_2~ 离子热电离质谱法测定硼同位素的影响

对石墨涂样检测 Cs2 BO2 离子条件下甘露醇对硼同位素测定的影响进行了研究 ,结果表明在甘露醇存在下 11B/ 10 B比值明显高于只有石墨存在时的比值。硼 -甘露醇络合物的形成可能改变了 Cs2 BO2 -石墨方法的电离和蒸发条件。     

Crustacean zooplankton sedimentary remains from calcium-poor lakes: complex responses to threshold concentrations

Declines in lakewater calcium (Ca) concentrations are occurring in many softwater lakes of the Canadian Shield, and likely elsewhere, and there is growing interest regarding the potential impacts that reduced Ca availability may have on aquatic ecosystems. Here, we test the hypotheses that the Ca limitations of Daphnia pulex (reduced growth/survival when Ca <1.5 mg L⁻¹) identified in laboratory analyses and paleolimnological case studies can be observed among cladoceran assemblages from surface sediments along a narrow Ca gradient (1–3 mg L⁻¹), and also whether the impacts of low Ca concentrations can be distinguished from those of low lakewater pH. Significant differences among daphniid communities were observed across the 1.5 mg L⁻¹ Ca threshold; however, these differences did not extend to the broader cladoceran community and considerable variability in Ca tolerance was observed within the D. pulex species complex. Of the measured environmental variables, only pH and lake depth explained a significant amount of variation among the entire cladoceran community, although when enlarging the dataset to extend the Ca and pH ranges, Ca replaced pH as a significant explanatory variable. Our data adds support to our previous observations that, within the cladoceran community, daphniids are the most responsive to Ca decline, however responses differ within daphniid species complexes and Ca thresholds under natural conditions may be higher for some species than their laboratory-identified values.     

Seismic collapse capacity of basic inelastic structures vulnerable to the P‐delta effect

The collapse capacity of earthquake‐excited inelastic nondeteriorating SDOF systems, which are vulnerable to the destabilizing effect of gravity loads (P‐delta effect), is evaluated. In this paper, the collapse capacity of the system subjected to a ground motion is defined as spectral acceleration at its initial structural period, at which the structure becomes unstable. Characteristic structural parameters, which affect the collapse capacity, are identified. Ground motion records of the ATC 63 far‐field set characterize severe earthquake excitation. In extensive incremental dynamic analyses studies, the impact of these parameters and of aleatory uncertainties on the collapse capacity is assessed and quantified. Median and percentile collapse capacities are plotted against the initial structural period leading to collapse capacity spectra. Nonlinear regression analyses are applied to derive analytical expressions of the design collapse capacity spectra and collapse fragility curves. The ultimate objective is to provide collapse capacity spectra for easy application and yet sufficient accurate assessment of the dynamic stability of flexible multistory buildings. Copyright © 2011 John Wiley & Sons, Ltd.     

Deep jets on gas-giant planets

Three-dimensional numerical simulations of the atmospheric flow on giant planets using the primitive equations show that shallow thermal forcing confined to pressures near the cloud tops can produce deep zonal winds from the tropopause all the way down to the bottom of the atmosphere. These deep winds can attain speeds comparable to the zonal jet speeds within the shallow, forced layer; they are pumped by Coriolis acceleration acting on a deep meridional circulation driven by the shallow-layer eddies. In the forced layer, the flow reaches an approximate steady state where east-west eddy accelerations balance Coriolis accelerations acting on the meridional flow. Under Jupiter-like conditions, our simulations produce 25 to 30 zonal jets, similar to the number of jets observed on Jupiter and Saturn. The simulated jet widths correspond to the Rhines scale; this suggests that, despite the three-dimensional nature of the dynamics, the baroclinic eddies energize a quasi-two-dimensional inverse cascade modified by the β effect (where β is the gradient of the Coriolis parameter). In agreement with Jupiter, the jets can violate the barotropic and Charney-Stern stability criteria, achieving curvatures ^∂2u/∂y² of the zonal wind u with northward distance y up to 2β. The simulations exhibit a tendency toward neutral stability with respect to Arnol'd's second stability theorem in the upper troposphere, as has been suggested for Jupiter, although deviations from neutrality exist. When the temperature varies strongly with latitude near the equator, our simulations can also reproduce the stable equatorial superrotation with wind speeds greater than . Diagnostics show that barotropic eddies at low latitudes drive the equatorial superrotation. The simulations also broadly explain the distribution of jet-pumping eddies observed on Jupiter and Saturn. While idealized, these simulations therefore capture many aspects of the cloud-level flows on Jupiter and Saturn.     

A model for the temperature-dependence of tidal dissipation in convective plumes on icy satellites: Implications for Europa and Enceladus

To explain the formation of surface features on Europa, Enceladus, and other satellites, many authors have postulated the spatial localization of tidal heating within convective plumes. However, the concept that enhanced tidal heating can occur within a convective plume has not been rigorously tested. Most models of this phenomenon adopt a tidal heating with a temperature-dependence derived for an incompressible, homogeneous (zero-dimensional) Maxwell material, but it is unclear whether this formulation is relevant to the heterogeneous situation of a warm plume surrounded by cold ice. To determine whether concentrated dissipation can occur in convective plumes, we develop a two-dimensional model to compute the volumetric dissipation rate for an idealized, vertically oriented, isolated convective plume obeying a Maxwellian viscoelastic compressible rheology. We apply the model to the Europa and Enceladus ice shells, and we investigate the consequences for partial melting and resurfacing processes on these bodies. We find that the tidal heating is strongly temperature dependent in a convective ice plume and could produce elevated temperatures and local partial melting in the ice shells of Europa and Enceladus. Our calculation provides the first quantitative verification of the hypothesis by Sotin et al. [Sotin, C., Head, J.W., Tobie, G., 2002. Geophys. Res. Lett. 29. 74-1] and others that the tidal dissipation rate is a strong function of temperature inside a convective plume. On Europa, such localized heating could help allow the formation of domes and chaos terrains by convection. On Enceladus, localized tidal heating in a thermal plume could explain the concentrated activity at the south pole and its associated heat transport of 2-7 GW.     

The Monitor project: the search for transits in the open cluster NGC 2362

We present the results of a systematic search for transiting planets in a ∼5 Myr open cluster, NGC 2362. We observed ∼1200 candidate cluster members, of which ∼475 are believed to be genuine cluster members, for a total of ∼100 h. We identify 15 light curves with reductions in flux that pass all our detection criteria, and six of the candidates have occultation depths compatible with a planetary companion. The variability in these six light curves would require very large planets to reproduce the observed transit depth. If we assume that none of our candidates are, in fact, planets then we can place upper limits on the fraction of stars with hot Jupiters (HJs) in NGC 2362. We obtain 99 per cent confidence upper limits of 0.22 and 0.70 on the fraction of stars with HJs ( f _p) for 1–3 and 3–10 d orbits, respectively, assuming all HJs have a planetary radius of 1.5 R _Jup. These upper limits represent observational constraints on the number of stars with HJs at an age ≲10 Myr, when the vast majority of stars are thought to have lost their protoplanetary discs. Finally, we extend our results to the entire Monitor project, a survey searching young, open clusters for planetary transits, and find that the survey as currently designed should be capable of placing upper limits on f _p near the observed values of f _p in the solar neighbourhood.     

Anthropogenic Impacts on a Bedrock Aquifer at the Village Scale

This study focuses on assessing groundwater potability in a highly complex and heterogeneous fractured bedrock aquifer having variable overburden cover. Eight monitoring wells were installed in a privately serviced lakeside village, and groundwater was routinely sampled over a 2‐year timeframe for concentration analysis of nitrate, fecal indicator bacteria, stable isotopes, and a total of 41 pharmaceutical compounds. While pollutant concentrations remained low throughout the study, the presence of fecal indicator bacteria and pharmaceuticals was noted at least once (but not always consistently) in most sampling intervals. An interpretation based on the integration of chemical, bacterial, and site characterization datasets suggests that: (1) the fracture network is complex and heterogeneous with limited vertical connectivity; (2) existing pathways are sufficient for the quick and widespread migration of surface contaminants to depth; (3) anthropogenic contaminants from both septic systems and agriculture are likely sourced in the surrounding uplands where overburden is thin; and (4) fecal contamination, as observed over the long term, is ubiquitous at the village scale. Groundwater quality is continually changing in this hydrogeologic environment and the determination of potability on the larger scale is not likely to be adequately captured with infrequent domestic well sampling (i.e., voluntary annual sampling by homeowners).