A critique of the internal tracer method for estimating contaminant degradation rates

The internal tracer method for estimating contaminant degradation rates separates the attenuation effects not associated with degradation by using a codisposed recalcitrant internal tracer to normalize the degrading contaminant concentration. The remaining attenuation between the internal tracer and degrading contaminant is attributed to degradation and the degradation rate half-life is estimated from the first-order decay equation. An analytical solution of the advection- dispersion equation was used to evaluate flow-and-transport conditions that could result in incorrect estimates of contaminant degradation rate constants. Flow-and-transport characteristics that result in overestimating degradation rates were of particular interest because the internal tracer method often used to demonstrate natural attenuation can achieve remedial objectives. The analytical solution was also used to estimate the magnitude of error associated with using the internal tracer method at an example site and to explain different degradation rates estimated using tracers with different decay rate constants.     

Use of physiological responses in Mytilus trossulus as integrative bioindicators of sewage pollution

Mussels, Mytilus trossulus (average shell length 43+/-0.8 mm), were sampled from a beach in Alaska that received untreated sewage for several years, a second beach adjacent to a secondary wastewater outfall, and two nearby reference beaches. Survival time in air, byssal thread production rate, and prevalence of trematode parasites were determined for each group. Tolerances to aerial exposure was significantly lower (P<0.05) at both sewage outfall sites than at the reference sites. Mussels exposed to untreated sewage produced fewer byssal threads and had a significantly higher prevalence of encysted trematodes than mussels from the other beaches, including the secondary wastewater site. Survival in air, byssal thread production, and trematode prevalence in mussels may be useful indicators in evaluating the longterm health of beaches exposed to sewage.     

Volume contents

Volume Contents

Volume contents     

The system of the Milky Way, LMC and SMC

A simple sticky-particle numerical model has been developed in order to check whether extended structures of gas created due to the dynamical evolution of the Galaxy and the Magellanic Clouds system can be explained as remnants of a tidal interaction. Influence of dissipative nature of gaseous medium has been taken into account. The most remarkable features are: the Magellanic Stream, the common HI envelope surrounding both the LMC and SMC and the bridge extended between the Clouds. In contrast to previous works of Murai and Fujimoto (1980), Gardiner et al. (1994) and H and Rohlfs (1994) no presumptions were done on the actual galactocentric velocities of the Magellanic Clouds. The mean values of the LMC and SMC velocity vectors obtained from the Hipparcos proper motion measurements (Kroupa and Bastian, 1997) were used in order to verify whether they allow to reproduce the observed HI distribution. Numerical simulations showed that tidal forces are really significant for the evolution of extended structures such as the Magellanic Stream but this approach becomes unsufficient for the internal regions of galaxies where self-gravity and dissipative properties of the gas cannot be neglected. More precise proper motion measurements are urgently needed. This revised version was published online in August 2006 with corrections to the Cover Date.     

The capture efficiency map: the capture zone under time-varying flow

The capture zone or contributing area of a ground water extraction well can be defined as that portion of the aquifer from which the well draws its water. Accurate delineation of capture zones is important in many ground water remediation applications and in the definition of wellhead protection areas. Their mathematical delineation is often simplified by using quasi-steady-state models based on time-weighted average pumping rates and background hydraulic gradients. We present a new semianalytic approach for the definition of capture zones under transient-flow conditions. We then use this approach to evaluate the effects of time variations in the direction of the background hydraulic gradient on capture. Results are presented in the form of capture efficiency maps (CEMs). Although the area contributing to a given well is found to generally expand relative to the steady-state average capture zone when the gradient direction varies, the zone of 100% capture may expand or contract depending on site-specific conditions. We illustrate our CEM approach by applying it to the design of a plume containment system.     

Rare and vulnerable species in the mollusc communities in the mining subsidence reservoirs of an industrial area (The Katowicka Upland, Upper Silesia, Southern Poland)

Pollution of the water environment by mining waters is a problem not only in Poland, but worldwide. This study investigated the mollusc communities in seven mining subsidence reservoirs affected by coal mine output (the Katowicka Upland, Upper Silesia, Southern Poland). The objective of the survey was to determine the relationship between the molluscs and their environments and to evaluate the ecological-conservation value of freshwater habitats which support rare and vulnerable molluscs. From 1993 to 2005, 23 mollusc species were recorded. Our result confirmed an invasion by Potamopyrgus antipodarum (Gray, 1843), whose density varied from 2 to 2422 individuals/m² in the waters of the Katowicka Upland. A few rare and vulnerable species were found, e.g. Acroloxus lacustris (Linnaeus, 1758), Hippeutis complanatus (Linnaeus, 1758), Ferrissia wautieri (Mirolli, 1960), Anodonta anatina (Linnaeus, 1758), Musculium lacustre (O.F. Müller, 1774) or Pisidium casertanum (Poli, 1791). Principal component analysis showed a positive correlation between mollusc density and pH, the concentration of chlorides, the total hardness, alkalinity and total dissolved solids, and a negative correlation between the number of species and phosphates. Because of the distinctive environmental features of the mining subsidence reservoirs in Czułów, the research area has provided a refuge for wildlife.     

Soil moisture: a residual problem underlying AGCMs

This paper critically reviews and intercompares land surface schemes (LSSs) as used in atmospheric general circulation models (AGCMs) to simulate soil moisture and its response to a warmer climate, and potential evapotranspiration approaches as used in operational soil moisture monitoring and in predicting the response of soil moisture to a warmer climate. AGCM predictions of overall soil moisture change are in broad agreement but disagree sharply in some regions. Intercomparison projects have sought to evaluate the LSSs used by AGCMs for both accuracy and consistency. These studies have found that different LSSs can produce very different simulations even when supplied with identical atmospheric forcing. As well, LSSs that produce similar surface results from present-day or control climates often diverge when forced with climatic change data. Furthermore, no single LSS has been identified that produces an adequate simulation of all of temperature, moisture, evapotranspiration and runoff. AGCM LSSs must resolve the surface energy balance (SEB) in order to compute realistic heat fluxes between with the atmospheric model. LSSs have been used with AGCMs in both on-line (fully coupled) and off-line modes. In off-line climatic change experiments, AGCM predictions of atmospheric temperature and precipitation have been used, along with model downward radiative fluxes at the surface, to drive their own uncoupled LSS. However, there are simple non-energy-balance methods for estimating evapotranspiration that have been traditionally used in agricultural and meteorological applications. These schemes compute a potential evapotranspiration (PE) based on temperature and/or net radiation inputs, with the PE modified based on the availability of soil moisture. Operational PE approaches have also been used with AGCM data in off-line climate change experiments. The advantages of this approach are that it is simpler and requires less information, although (like the off-line SEB approach) it leaves out the simulation of feedbacks between the surface and the atmosphere.Although the SEB approach is essential for LSSs that must be coupled to AGCMs, this does not necessarily make it superior to an off-line operational PE LSS when it comes to quantities such as soil moisture. The quality of current observational data is insufficient to demonstrate that either approach is better than the other. Both approaches should continue to be used and intercompared when predicting the impacts of climatic change on soil moisture.     

Pits,rifts and slumps: the summit structure of Piton de la Fournaise

A clear model of structures and associated stress fields of a volcano can provide a framework in which to study and monitor activity. We propose a volcano-tectonic model for the dynamics of the summit of Piton de la Fournaise (La Reunion Island, Indian Ocean). The summit contains two main pit crater structures (Dolomieu and Bory), two active rift zones, and a slumping eastern sector, all of which contribute to the actual fracture system. Dolomieu has developed over 100 years by sudden large collapse events and subsequent smaller drops that include terrace formation. Small intra-pit collapse scars and eruptive fissures are located along the southern floor of Dolomieu. The western pit wall of Dolomieu has a superficial inward dipping normal fault boundary connected to a deeper ring fault system. Outside Dolomieu, an oval extension zone containing sub-parallel pit-related fractures extends to a maximum distance of 225 m from the pit. At the summit the main trend for eruptive fissures is N80°, normal to the north–south rift zone. The terraced structure of Dolomieu has been reproduced by analogue models with a roof to width ratio of approximately 1, suggesting an original magma chamber depth of about 1 km. Such a chamber may continue to act as a storage location today. The east flank has a convex–concave profile and is bounded by strike-slip fractures that define a gravity slump. This zone is bound to the north by strike-slip fractures that may delineate a shear zone. The southern reciprocal shear zone is probably marked by an alignment of large scoria cones and is hidden by recent aa lavas. The slump head intersects Dolomieu pit and may slide on a hydrothermally altered layer known to be located at a depth of around 300 m. Our model has the summit activity controlled by the pit crater collapse structure, not the rifts. The rifts become important on the mid-flanks of the cone, away from pit-related fractures. On the east flank the superficial structures are controlled by the slump. We suggest that during pit subsidence intra-pit eruptions may occur. During tumescence, however, the pit system may become blocked and a flank eruption is more likely. Intrusions along the rift may cause deformation that subsequently increases the slump’s potential to deform. Conversely, slumping may influence the east flank stress distribution and locally control intrusion direction. These predictions can be tested with monitoring data to validate the model and, eventually, improve monitoring.     

Hybridization of the probability perturbation method with gradient information

Geostatistically based history-matching methods make it possible to devise history-matching strategies that will honor geologic knowledge about the reservoir. However, the performance of these methods is known to be impeded by slow convergence rates resulting from the stochastic nature of the algorithm. It is the purpose of this paper to introduce a method that integrates qualitative gradient information into the probability perturbation method to improve convergence. The potential of the proposed method is demonstrated on a synthetic history-matching example. The results indicate that inclusion of qualitative gradient information improves the performance of the probability perturbation method.     

Euv97: Improvements to Euv Irradiance Modeling in the Soft X-Rays and FUV

EUV97 is a solar EUV empirical model that incorporates revised soft X-ray fluxes from the SOLRAD-11 satellite (1976–1979) and uses Lα recently recalibrated to the UARS satellite (1991–present) SOLSTICE Lα. The soft X-ray data have been revised from the original flux values using Mewe's spectral fits to the data. The recalibrated AE-E and SME Lα datasets use UARS Lα for absolute flux values to provide two solar cycles of Lα irradiance extending back to 1977. Lα is used by EUV97 as a proxy for chromospheric EUV irradiances. The EUV97 empirical solar model takes its heritage from the EUV91 model based on a multiple linear regression technique that fits soft X-ray and EUV irradiances to 10.7 cm flux for transition region and coronal emissions or to Lα and Hei 10830 Ú EW for chromospheric emissions.