A global perspective on African climate

We describe the global climate system context in which to interpret African environmental change to support planning and implementation of policymaking action at national, regional and continental scales, and to inform the debate between proponents of mitigation v. adaptation strategies in the face of climate change. We review recent advances and current challenges in African climate research and exploit our physical understanding of variability and trends to shape our outlook on future climate change. We classify the various mechanisms that have been proposed as relevant for understanding variations in African rainfall, emphasizing a “tropospheric stabilization” mechanism that is of importance on interannual time scales as well as for the future response to warming oceans. Two patterns stand out in our analysis of twentieth century rainfall variability: a drying of the monsoon regions, related to warming of the tropical oceans, and variability related to the El Niño–Southern Oscillation. The latest generation of climate models partly captures this recent continent-wide drying trend, attributing it to the combination of anthropogenic emissions of aerosols and greenhouse gases, the relative contribution of which is difficult to quantify with the existing model archive. The same climate models fail to reach a robust agreement regarding the twenty-first century outlook for African rainfall, in a future with increasing greenhouse gases and decreasing aerosol loadings. Such uncertainty underscores current limitations in our understanding of the global climate system that it is necessary to overcome if science is to support Africa in meeting its development goals.     

Sedimentological constraints on hydrometeor-enhanced particle deposition: 1992 Eruptions of Crater Peak, Alaska

Water is a dominant component of volcanic clouds and has fundamental control on very fine particle deposition. Particle size characteristics of distal tephra-fall (100s km from source volcano) have a higher proportion of very fine particles compared to predictions based on single particle settling rates. In this study, sedimentological analyses of fallout from for the 18 August and 16–17 September 1992 eruptions of Crater Peak, Alaska, are combined with satellite observations, and cloud trajectory and microphysics modeling to investigate meteorological influences on particle sedimentation. Total grain size distributions of tephra fallout were reconstructed for both Crater Peak eruptions and indicate a predominance of fine particles < 125 μm. Polymodal analysis of the deposits has identified a particle subpopulation with mode ~ 15–18 μm involved in particle aggregation. Accounting for the magmatic water source only, calculated ice water content of the 3.7 hour old September 1992 Spurr cloud was ~ 4.5 × 10^− 2 g m^− 3 (based on an estimated cloud thickness of ~ 1000 m from trajectory modeling). Hydrometeor formation on particles in the volcanic cloud and subsequent sublimation may induce a cloud base instability that leads to rapid bulk (en masse) sedimentation of very fine particles through a mammatus-like mechanism.     

Mg-enriched erythrite from Bou Azzer,Anti-Atlas Mountains,Morocco: geochemical and spectroscopic characteristics

Mineralogy and Petrology - Supergene Mg-enriched erythrite, with an average composition (Co2.25Mg0.58Ni0.14Fe0.04Mn0.02 Zn0.02) (As1.97P&lt;0.01O8)·8H2O, accompanied by skutterudite,...     

Rates of Deglaciation during the Last Glaciation and Holocene in the Cordillera Vilcanota-Quelccaya Ice Cap Region, Southeastern Perú

Moraine chronology is combined with digital topography to model deglacial rates of paleoglacier volumes in both the Huancané Valley on the west side of the Quelccaya Ice Cap and the Upismayo Valley on the northwest side of the Cordillera Vilcanota. The fastest rates of deglaciation (39×10⁻⁵ to 114×10⁻⁵ km³ yr⁻¹ and 112×10⁻⁵ to 247×10⁻⁵ km³ yr⁻¹ for each valley, respectively) were calculated for the most recent paleoglaciers, corresponding to the last few centuries. These results are consistent with observations in the Venezuelan Andes showing high rates of deglaciation since the Little Ice Age. These rates also fall within the range of 20th century rates of deglaciation measured on the Quelccaya Ice Cap (29×10⁻⁵ to 220×10⁻⁵ km³ yr⁻¹, Brecher and Thompson, 1993; Thompson, 2000). These results imply that rates of deglaciation may fluctuate significantly over time and that high rates of deglaciation may not be exclusive to the late 20th century. Equilibrium line altitude (ELA) depressions for the ice volumes of the last glaciation modeled here were computed as 230 m for the Quelccaya Ice Cap and 170 m for the Cordillera Vilcanota. Maximum ELA depressions are lower than previously published: <500 m for the Cordillera Vilcanota and <400 m for the Quelccaya Ice Cap. These lower values could imply a topographic control over paleoglacier extent.     

Contact Partial Melting of Granitic Country Rock, Melt Segregation, and Re-injection as Dikes into Ferrar Dolerite Sills, McMurdo Dry Valleys, Antarctica

Numerous, interconnected, granitic dikes (<30 cm in widthand hundeds of meters in length) cut Ferrar dolerite sills ofthe McMurdo Dry Valleys, Antarctica. The source of the graniticdikes is partial melting of granitic country rock, which tookplace in the crust at a depth of about 2–3 km adjacentto contacts with dolerite sills. Sustained flow of doleriticmagma through the sill generated a partial melting front thatpropagated into the granitic country rock. Granitic partialmelts segregated and collected at the contact in a melt-rich,nearly crystal-free reservoir adjacent to the initial doleritechilled margin. This dolerite chilled margin was subsequentlyfractured open in the fashion of a trapdoor by the graniticmelt, evacuating the reservoir to form an extensive complexof granitic dikes within the dolerite sills. At the time ofdike injection the dolerite was nearly solidified. Unusuallycomplete exposures allow the full physical and chemical processesof partial melting, segregation, and dike formation to be examinedin great detail. The compositions of the granitic dikes andthe textures of partially melted granitic wall rock suggestthat partial melting was characterized by disequilibrium mineraldissolution of dominantly quartz and alkali feldspar ratherthan by equilibrium melting. It is also unlikely that meltingoccurred under water-saturated conditions. The protolith granitecontains only 7 vol.% biotite and estimated contact temperaturesof 900–950°C suggest that melting was possible ina dry system. Granite partial melting, under closed conditions,extended tens of meters away from the dolerite sill, yet meltsegregation occurred only over less than one-half a meter fromthe dolerite chilled margin where the degree of partial meltingwas of the order of 50 vol.%. This segregation distance is consistentwith calculated length scales expected in a compaction-drivenprocess. We suggest that the driving force for compaction wasdifferential stress generated by a combination of volume expansionas a result of granite partial melting, contraction during doleritesolidification, and relaxation of the overpressure driving doleriteemplacement. On a purely chemical basis, the extent of meltsegregation necessary under fractional and batch melting tomatch the Rb concentrations between melt and parent rock isa maximum of 48 and 83 vol.% melt, respectively. KEY WORDS: Antarctica; dike injection; disequilibrium; granite partial melting; silicic melt segregation     

Understanding the relative impacts of natural processes and human activities on the hydrology of the Central Rift Valley lakes,East Africa

Significant changes have been observed in the hydrology of Central Rift Valley (CRV) lakes in Ethiopia, East Africa as a result of both natural processes and human activities during the past three decades. This study applied an integrated approach (remote sensing, hydrologic modelling, and statistical analysis) to understand the relative effects of natural processes and human activities over a sparsely gauged CRV basin. Lake storage estimates were calculated from a hydrologic model constructed without inputs from human impacts such as water abstraction and compared with satellite‐based (observed) lake storage measurements to characterize the magnitude of human‐induced impacts. A non‐parametric Mann–Kendall test was used to detect the presence of climatic trends (e.g. a decreasing or increasing trends in precipitation), while the Standard Precipitation Index (SPI) analysis was used to assess the long‐term, inter‐annual climate variability within the basin. Results indicate human activities (e.g. abstraction) significantly contributed to the changes in the hydrology of the lakes, while no statistically significant climatic trend was seen in the basin, however inter‐annual natural climate variability, extreme dryness, and prolonged drought has negatively affected the lakes. The relative contributions of natural and human‐induced impacts on the lakes were quantified and evaluated by comparing hydrographs of the CRV lakes. Lake Abiyata has lost ~6.5 m in total lake height between 1985 and 2006, 70% (~4.5 m) of the loss has been attributed to human‐induced causes, whereas the remaining 30% is related to natural climate variability. The relative impact analysis utilized in this study could potentially be used to better plan and create effective water‐management practices in the basin and demonstrates the utility of this integrated methodology for similar studies assessing the relative natural and human‐induced impacts on lakes in data sparse areas. Copyright © 2015 John Wiley & Sons, Ltd.     

Identification of a sulfide derivative with a bicyclic hydrocarbon skeleton related to squalene. Part II: synthesis of a S-spiro-like dithiolane triterpenoid

A sulfide with a bicyclic squalene hydrocarbon skeleton present in sediments from various depositional settings and of different geological age has been identified by synthesis of a reference compound. In contrast to previous expectations [cf. Schouten, S., Sinninghe Damsté, J.S., de Leeuw, J.W., 1995. A novel triterpenoid carbon skeleton in immature sulphur-rich sediments. Geochimica et Cosmochimica Acta 59, 953–958; Gug, S., Schaeffer, P., Adam, P., Klein, S., Motsch, E., Albrecht, P., 2009. Identification of a sulfide derivative with a bicyclic hydrocarbon skeleton related to squalene. Part I: Synthesis of a dithiane triterpenoid. Organic Geochemistry 40, 876–884.], this sulfide bears two “S-spiro type“ thiolane moities, but not the two thiochromane moieties originally envisaged. The synthesis resulted in the formation of a complex isomeric mixture of compounds, all co-eluting in gas chromatography (GC) in the form of one broad peak, as is the case with the geochemical compound. The spiro-type sulfide was formed by intramolecular sulfurization of a polyunsaturated bicyclic squalene derivative of unknown biological origin. The presence of this sulfide in a number of Triassic to Miocene marine sediments from various and contrasting depositional settings (upwelling environments, shallow continental platforms, lagoonal sub-basins, hypersaline environments), all characterized by strongly anoxic conditions, but with or without photic zone anoxia, indicates that the microorganisms biosynthesizing the precursor bicyclic squalene occupy diverse ecological niches.     

Early Holocene brackish closed basin conditions in Georgian Bay, Ontario, Canada: microfossil (thecamoebian and pollen) evidence

Microfossils have been critical in unravelling the complex postglacial history of Georgian Bay. Thecamoebians (testate amoebae/rhizopods) record paleolimnological conditions, and pollen stratigraphy allows correlation across the basin, where sedimentation has been spatially and temporally discontinuous. Because parts of Georgian Bay have been non-depositional or erosional since the end of the Nipissing transgression (~5,000 (5,800 cal) BP), early Holocene features are exposed on the lakebed. Among these are shoreline features, such as submerged beaches and relict channels, associated with low-level Lake Hough that was driven far below the level of basin overflow. Cores taken throughout Georgian Bay record the existence of closed basin conditions that persisted several centuries around 7,500 (8,300 cal) BP, corresponding to the late Lake Hough lowstand. Evidence for hydrologic closure includes a low-diversity centropyxid-dominated thecamoebian fauna around the boundary between pollen subzones 2a and 2b in the Flowerpot Beach core, Flowerpot and Killarney basins, and in Severn Sound. This low-diversity centropyxid-dominated fauna is interpreted as recording the development of slightly brackish conditions as a result of a hydrologic deficit associated with relatively arid conditions in the Great Lakes basin during the early Holocene pine zone (~8,800–7,200 (9,900–8,050 cal) BP). The rest of the Holocene record in Georgian Bay (where it is preserved) is more diverse and dominated by difflugiid thecamoebians: predominantly Difflugia oblonga prior to human settlement, and Cucurbitella tricuspis since high-density human occupation and agriculture (and resulting eutrophication) began with the Wendat First Nations people around Severn Sound about 750 years ago. The implication that water budget fluctuations leading to discernible variations in lake level and water chemistry occurred in the relatively recent geologic past is significant to studies of global climate change and resource management in the Great Lakes, one of the world’s largest freshwater resources.