Optimization and biokinetic studies on pretreatment of sludge for enhancing biogas production

Excess sludge generation is a major problem in biological effluent treatment processes. Utilization of excess sludge for gas production is an attractive route, which could be enhanced by pretreatment methods. This study involves two sets of experiments. The first set covers mechanical pretreatment of both feed and inoculum. The second set involves alkaline and mechanical treatments of feed and only mechanical treatment of inoculum. Response surface methodology was used for experimental design, analysis and optimization. The optimized mechanical treatment volume of feed was found to be 50%. Diligent mechanical treatment of inoculum resulted in enhanced microbial activity and improved gas production. Reduction in volatile solids, proteins and carbohydrates was observed to a maximum of 63, 84 and 78.5%, respectively. Feed was subjected to alkali treatment in order to reduce mechanical energy input and to improve solubilization. Compared to mechanical treatment alone, enhanced gas production of about 15% was observed at an optimized pH of 11.8 and SRT of 21 days. A biokinetic model was formulated, simulated and validated for the degradation of organics and gas production.     

Influence of magnetic effect,anisotropy, irregularity,initial stress and heterogeneity on propagation of SH-wave in an irregular pre-stressed magnetoelastic monoclinic sandwiched layer

Monoclinic materials viz. quartz, lithium niobate and lithium tantalate are among the most abundant materials, finding numerous applications throughout the technological world. Moreover, the presence of irregularity, initial stresses, anisotropy and heterogeneity in a material medium is obvious. These facts motivate the study of magnetoelastic SH-wave propagation in an irregular monoclinic sandwiched layer between a heterogeneous isotropic layer and an isotropic half space, all under initial stress. The heterogeneity in the uppermost layer is caused due to exponential variation in rigidity, density and initial stress in terms of space variable pointing vertically downward. The dispersion relation has been obtained using first-order perturbation technique. The substantial effect of wave number, anisotropy, irregularity, width ratio of the layers, horizontal compressive/tensile initial stresses, heterogeneity and monoclinic-magnetoelastic coupling parameter associated with sandwiched layer on phase velocity of SH-wave has been studied and depicted by means of graph. Comparative study made for the case when pre-stressed irregular sandwiched layer is monoclinic-magnetoelastic to the case when it is isotropic magnetoelastic layer is one of the major highlights of the current study.     

Estimation of snow and glacial melt contribution through stable isotopes and assessment of its impact on river morphology through stream power approach in two Himalayan river basins

The impact of increased temperature on the Third Pole, as the Himalayas is referred to, and the likely cascading impacts on the general downstream hydrology have been widely noted. However, the impact on fluvial geomorphology has not received specific attention. Change in the glacial domain in terms of melt increase will change discharge and sediment flux into fluvial system, which will induce changes in fluvial processes and forms. The present work attempts to study this process-based glacio-fluvial coupling in the two neighbouring glaciated river basins in the Northwest Himalaya, viz., the Sutlej and the Yamuna river basins till the mountain front. A total of 194 samples of river, tributary and groundwater of pre- and post-monsoon seasons in the two river basins were analysed for stable isotopes. The trend of δ¹⁸O and electrical conductivity along the mainstream gives qualitative idea on the influence of headwaters in the downstream of the catchment thereby allowing inference on melt contribution. Further, two component mixing model using stable oxygen isotope of two seasons water samples showed that melt contributes about 41.1–66.8 and 6.6–10.6% at different points to the total river discharge in the Sutlej and the Tons River (the glaciated, major tributary of the Yamuna River) basins, respectively. For different scenarios of increase in melt, stream power increase in the Sutlej River basin is significant as opposed to the Tons River. River channel in the Sutlej River basin will be significantly more impacted in comparison with the Yamuna River system.     

In‐plane and out‐of‐plane behavior of confined masonry walls for various toothing and openings details and prediction of their strength and stiffness

Eight half‐scale brick masonry walls were tested to study two important aspects of confined masonry (CM) walls related to its seismic behavior under in‐plane and out‐of‐plane loads. Four solid wall specimens tested to investigate the role of type of interface between the masonry and tie‐columns, such as toothing varying from none to every course. The other four specimens with openings were tested to study the effectiveness of various strengthening options around opening to mitigate their negative influence. In the set of four walls, one wall was infilled frame while the other three were CM walls of different configurations. The experimental results were further used to determine the accuracy of various existing models in predicting the in‐plane response quantities of CM walls. Confined masonry walls maintained structural integrity even when severely damaged and performed much better than infill frames. No significant effect of toothing details was noticed although toothing at every brick course was preferred for better post‐peak response. For perforated walls, provision of vertical elements along with continuous horizontal bands around openings was more effective in improving the overall response. Several empirical and semi‐empirical equations are available to estimate the lateral strength and stiffness of CM walls, but those including the contribution of longitudinal reinforcement in tie‐columns provided better predictions. The available equations along with reduction factors proposed for infills could not provide good estimates of strength and stiffness for perforated CM walls. However, recently proposed relations correlating strength/stiffness with the degree of confinement provided reasonable predictions for all wall specimens. Copyright © 2016 John Wiley & Sons, Ltd.     

Training Programme on Major Tectonics and Lithounits in the Indus and Shyok Suture Zones of Ladakh Himalaya — M. Ram Mohan, (NGRI-CSIR,Hyderabad. Email: rammohan@ngri.res.in) and Sita Bora (Kumaun University,Nainital; Email: sitabora@yahoo.com)

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Training Programme on Major Tectonics and Lithounits in the Indus and Shyok Suture Zones of Ladakh Himalaya — M. Ram Mohan, (NGRI-CSIR, Hyderabad. Email: rammohan@ngri.res.in) and Sita Bora (Kumaun University, Nainital; Email: sitabora@yahoo.com)     

Age and geochemistry of the Newania dolomite carbonatites, India: implications for the source of primary carbonatite magma

The Newania carbonatite complex of India is one of the few dolomite-dominated carbonatites of the world. Intruding into Archean basement gneisses, the rocks of the complex have undergone limited diversification and are not associated with any alkaline silicate rock. Although the magmatic nature of the complex was generally accepted, its age of emplacement had remained equivocal because of the disturbed nature of radioisotope systems. Many questions about the nature of its mantle source and mode of origin had remained unanswered because of lack of geochemical and isotopic data. Here, we present results of our effort to date the complex using ¹⁴⁷Sm–¹⁴³Nd, ²⁰⁷Pb–²⁰⁶Pb and ⁴⁰Ar–³⁹Ar dating techniques. We also present mineral chemistry, major and trace element geochemistry and Sr–Nd isotopic ratio data for these carbonatites. Our age data reveal that the complex was emplaced at ~1,473 Ma and parts of it were affected by a thermal event at ~904 Ma. The older ²⁰⁷Pb–²⁰⁶Pb ages reported here (~2.4 Ga) and by one earlier study (~2.3 Ga; Schleicher et al. Chem Geol 140:261–273, 1997) are deemed to be a result of heterogeneous incorporation of crustal Pb during the post-emplacement thermal event. The thermal event had little effect on many magmatic signatures of these rocks, such as its dolomite–magnesite–ankerite–Cr-rich magnetite–magnesio-arfvedsonite–pyrochlore assemblage, mantle like δ¹³C and δ¹⁸O and typical carbonatitic trace element patterns. Newania carbonatites show fractional crystallization trend from high-Mg to high-Fe through high-Ca compositions. The least fractionated dolomite carbonatites of the complex possess very high Mg# (≥80) and have similar major element oxide contents as that of primary carbonatite melts experimentally produced from peridotitic sources. In addition, lower rare earth element (and higher Sr) contents than a typical calcio-carbonatite and mantle like Nb/Ta ratios indicate that the primary magma for the complex was a magnesio-carbonatite melt and that it was derived from a carbonate bearing mantle. The Sr–Nd isotopic data suggest that the primary magma originated from a metasomatized lithospheric mantle. Trace element modelling confirms such an inference and suggests that the source was a phlogopite bearing mantle, located within the garnet stability zone.     

Thermal metamorphism of the Arunachal Himalaya, India: Raman thermometry and thermochronological constraints on the tectono-thermal evolution

Determination of the peak thermal condition is vital in order to understand tectono-thermal evolution of the Himalayan belt. The Lesser Himalayan Sequence (LHS) in the Western Arunachal Pradesh, being rich in carbonaceous material (CM), facilitates the determination of peak metamorphic temperature based on Raman spectroscopy of carbonaceous material (RSCM). In this study, we have used RSCM method of Beyssac et al. (J Metamorph Geol 20:859–871, 2002a) and Rahl et al. (Earth Planet Sci Lett 240:339–354, 2005) to estimate the thermal history of LHS and Siwalik foreland from the western Arunachal Pradesh. The study indicates that the temperature of 700–800 °C in the Greater Himalayan Sequence (GHS) decreases to 650–700 °C in the main central thrust zone (MCTZ) and decreases further to <200 °C in the Mio-Pliocene sequence of Siwaliks. The work demonstrates greater reliability of Rahl et al.’s (Earth Planet Sci Lett 240:339–354, 2005) RSCM method for temperatures >600 and <340 °C. We show that the higher and lower zones of Bomdila Gneiss (BG) experienced temperature of ~600 °C and exhumed at different stages along the Bomdila Thrust (BT) and Upper Main Boundary Thrust (U.MBT). Pyrolysis analysis of the CM together with the Fission Track ages from upper Siwaliks corroborates the RSCM thermometry estimate of ~240 °C. The results indicate that the Permian sequence north of Lower MBT was deposited at greater depths (>12 km) than the upper Siwalik sediments to its south at depths <8 km before they were exhumed. The ⁴⁰Ar/³⁹Ar ages suggest that the upper zones of Se La evolved ~13–15 Ma. The middle zone exhumed at ~11 Ma and lower zone close to ~8 Ma indicating erosional unroofing of the MCT sheet. The footwall of MCTZ cooled between 6 and 8 Ma. Analyses of P–T path imply that LHS between MCT and U.MBT zone falls within the kyanite stability field with near isobaric condition. At higher structural level, the temperatures increase gradually with P–T conditions in the sillimanite stability field. The near isothermal (700–800 °C) condition in the GHS, isobaric condition in the MCTZ together with T–t path evidence of GHS that experienced relatively longer duration of near peak temperatures and rapid cooling towards MCTZ, compares the evolution of GHS and inverted metamorphic gradient closely to channel flow predictions.     

Numerical simulation of fault reactivation phenomenon

Two-dimensional finite element method was used for evaluating the effect of orthogonal compression on precursor faults. The tendency of reactivation of precursor faults as thrust or normal was analyzed involving the positions and angles of precursor faults with the stresses, strains and displacements. Twelve cases were taken up with different combinations of precursor fault angles (high, >45° and low, <45°) and fault positions for analysis. Different positions and angles of precursor faults are correlated with stresses, strains, and displacements and are discussed in detail. It is hoped that this would help in understanding the past and the present geodynamics of the earth’s crust.     

The role of magnetic buoyancy in a Babcock-Leighton type solar dynamo

We study the effects of incorporating magnetic buoyancy in a model of the solar dynamo&amp;#x2014;which draws inspiration from the Babcock-Leighton idea of surface processes generating the poloidal field. We present our main results here.     

Propagation of weak discontinuities in a vibrationally-excited gas flow

Propagation of weak discontinuities headed by wavefronts of arbitrary shape in three dimensions are studied in vibrationally relaxing gas flow. The transport equations representing the rate of change of discontinuities in the normal derivatives of the flow variables are obtained, and it is found that the nonlinearity in the governing equations does not contribute anything to the vibrationally relaxing gas. An explicit criterion for the growth and decay of weak discontinuities along bi-characteristic curves in the characteristic manifold of the governing differential equations is given. A special case of interest is also discussed.