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991.
LAI Shaocong QIN Jiangfeng LI Yongfeng LIU Xin 《中国地球化学学报》2007,26(3):305-311
Neogene volcanic rocks in the Belog Co area, Qiangtang, northern Tibet, are represented by a typical intermediate-basic and intermediate alkaline rock association, with latite-trachyte as the main rock type. The results of chemical analysis are: SiO2=52%–62%, Al2O3>15%, Na2O/K2O>1 and MgO<3.30%. In addition, the volcanic rocks are LREE-enriched with LREE/HREE=10–13, (La/Yb)N=15–19, and show a weak negative Eu anomaly with δEu=0.71–0.89. The close relationship between Mg# and SiO2 and the co-variation of the magmatophile elements and ultra-magmatophile elements such as La/Sm-La and Cr-Tb indicate that this association of volcanic rocks is the product of comagmatic fractional crystallization. The rock association type and lower Sm/Yb values (Sm/Yb=3.23–3.97) imply that this association of volcanic rocks should have originated from partial melting of spinel lherzolite in the lithospheric mantle. On the other hand, the weak negative Eu anomaly and relative depletion in Nb, Ta and Ti reflect the features of terrigenous magma. So the Neogene Belog Co alkaline volcanic rocks should be the result of partial melting of the special crust-mantle transition zone on the Qinghai-Tibet Plateau. 相似文献
992.
Gehad M. Saleh 《中国地球化学学报》2007,26(4):333-344
The field relations, mineralogy, and major and trace elements (including REE analyses of whole-rock samples and minerals) of granites and their associated molybdenite uranium mineralized aplites in Southeastern Desert, Egypt, have been studied. The granites are leucocratic and mostly peraluminous in nature with muscovite increasing at the expense of biotite. The chemical and mineralogical characteristics of the granitic rocks indicate that their melts originated from the LILE-enriched mantle wedge by partial melting and are contaminated by crustal melts, followed by thermogravitational processes. Leucogranites with higher Na2O/K2O ratios from Um Dargag and Um Maiat crystallized under H2O-saturated equilibrium conditions in which the exsolved vapor continuously migrated away. The REE patterns of the granites studied are characterized by LREE enrichments and negative Eu anomalies. In comparison, the potassic aplites and the more sodic leucogranites are depleted in LREE, enriched in HREE and show more remarkable negative Eu anomalies. Allanite and monazite are the most important REE carriers in the granites. These minerals are strongly enriched in LREE, whereas fluorite and xenotime, which are more abundant in the aplites, are enriched in HREE. The average Lu/Ce ratio represents the fractionation trend with respect to HREE. It is 0.71 for radioactive fluorite, and it increases to 1.22 for non-radioactive fluorite. The high REE contents of molybdenite represent re-deposition of the mobilized Mo and REE. Due to the strong control of accessory minerals, the REEs are of limited use in petrogenetic modelling of highly evolved granitic systems. 相似文献
993.
YUAN Xuyin DENG Xu SHEN Zhiyong GAO Yun 《中国地球化学学报》2007,26(4):384-393
The species of Cu, Pb, Zn, Cd and Cr in sediments of the Taihu Lake, China, have been analyzed using the sequential chemical extraction method. Variations in the chemical fractions of these metals and their geographic distributions have also been studied. For all five metals, the residual fraction is highest but the exchangeable fraction is lowest among all the fractions. Compared to other metals, Cd has the highest percentage in the exchangeable fraction, and Cr is associated mainly with the residual fraction. Cu in the organic fraction and Pb in the Fe-Mn fraction are the important species, whereas the lowest percentages are found for Cd in the organic fraction, Cu in the Fe-Mn oxide fraction and Pb in the carbonate fraction. With respect to spatial differences, the total contents in the non-residual fractions of the metals in bay sediments are found to be higher than those in other sediments. The fractions of Cd, Cu and Cr showed significant variations in different regions. The fractions of Pb and Zn, however, did not show significant variations in spatial distribution, suggesting different amounts and different paths of anthropogenic input for the metals. Comparisons of the metal speciation indicated that Cd might be the most bioavailable metal, followed by Pb. 相似文献
994.
I. González M. M. Jordán T. Sanfeliu M. Quiroz C. de la Fuente 《Environmental Geology》2007,52(7):1243-1251
In southern Chile, with a mild and rainy climate, high levels of heavy metals have been detected in many gold placer deposits.
Many of the contaminants pose risks to human life, and consequently damage the trofic chain in this environment. The study
zones selected correspond to the handicraft gold-bearing sands of Rio Gato (Los Muermos), Carelmapu and Cucao. These are all
located in the X Region of “Los Lagos” in Chile. The type of methodology used in the characterization of the associated mineralization
consists of testing each representative sample with a grain size distribution, statistical parameter analysis and a mineralogical
analysis, using a binocular magnifying glass, a petrographic microscope, XRD and SEM/EDX. The chemical composition was defined
by means of X ray fluorescence and micro-chemical analysis. The results of the study about sediments in southern Chile are
presented. The major concentrations of heavy minerals are generally located in areas of dynamic river energy. In the samples,
more than 70% of the heavy minerals were distributed among grain sizes corresponding to thin sand with good grain selection
(meshes of 0.25–0.06 mm). The main mineral phases present in the analysed samples were gold, zircon, olivine, ilmenite, hornblende,
hypersthene, hematite, garnet, chromite, chlorite, augite, amphibolitic-epidote, etc. The main heavy metals found as a result
of the study were mercury, lead, cadmium, chrome, tellurium, indium, zinc, cobalt, copper, platinum, gold, etc., and as well
some less common elements like cerium, praseodymium, gadolinium, neodymium, samarium and lanthanum. This research work is
only a starting point for carrying out a risk probability mapping of heavy metals and the mineralogy of the Cucao, Carelmapu
and Rio Gato gold-bearing sands. 相似文献
995.
Anil Misra Lance A. Roberts Steven M. Levorson 《Geotechnical and Geological Engineering》2007,25(1):65-77
Load displacement analysis of drilled shafts can be accomplished by utilizing the “t-z” method, which models soil resistance
along the length and tip of the drilled shaft as a series of springs. For non-linear soil springs, the governing differential
equation that describes the soil-structure interaction may be discretized into a set of algebraic equations based upon finite
difference methods. This system of algebraic equations may be solved to determine the load–displacement behavior of the drilled
shaft when subjected to compression or pullout. By combining the finite difference method with Monte Carlo simulation techniques, a probabilistic load–displacement analysis can be conducted. The probabilistic analysis is advantageous
compared to standard factor of safety design because uncertainties with the shaft–soil interface and tip properties can be
independently quantified. This paper presents a reliability analysis of drilled shaft behavior by combining the finite difference
technique for analyzing non-linear load–displacement behavior with Monte Carlo simulation method. As a result we develop probabilistic relationships for drilled shaft design for both total stress (undrained)
and effective stress (drained) parameters. The results are presented in the form of factor of safety or resistance factors
suitable for serviceability design of drilled shafts. 相似文献
996.
Pasargadae complex had been the main center of Persian history during the Achaemenian period (560–330 bc), registered as one of the world heritage sites by UNESCO in 2004. This research is an attempt to recognize the natural setting
and landscape of Pasargadae during the Achaemenian period, in Iran. The method is based on the application of a multi-layer
technique. Collected data by fieldwork, especially in geology, hydrology, and hydrogeology, along with the analysis of aerial
data and satellite information provided the baseline information for preparing historic and environmental layers and have
made it possible to recognize a natural lakelet in the this area. The results show that the geometry of lakelet together with
the ancient river of Pasargadae had been the main elements that formed the character of the site; they were also important
in the locations of buildings in the Pasargadae complex. 相似文献
997.
Coupling of oceanic and continental crust during Eocene eclogite-facies metamorphism: evidence from the Monte Rosa nappe,western Alps 总被引:1,自引:0,他引:1
Thomas J. Lapen Clark M. Johnson Lukas P. Baumgartner Giorgio V. Dal Piaz Susanne Skora Brian L. Beard 《Contributions to Mineralogy and Petrology》2007,153(2):139-157
High precision U–Pb geochronology of rutile from quartz–carbonate–white mica–rutile veins that are hosted within eclogite
and schist of the Monte Rosa nappe, western Alps, Italy, indicate that the Monte Rosa nappe was at eclogite-facies metamorphic
conditions at 42.6 ± 0.6 Ma. The sample area [Indren glacier, Furgg zone; Dal Piaz (2001) Geology of the Monte Rosa massif: historical review and personal comments. SMPM] consists of eclogite boudins that are exposed
inside a south-plunging overturned synform within micaceous schist. Associated with the eclogite and schist are quartz–carbonate–white
mica–rutile veins that formed in tension cracks in the eclogite and along the contact between eclogite and surrounding schist.
Intrusion of the veins at about 42.6 Ma occurred at eclogite-facies metamorphic conditions (480–570°C, >1.3–1.4 GPa) based
on textural relations, oxygen isotope thermometry, and geothermobarometry. The timing of eclogite-facies metamorphism in the
Monte Rosa nappe determined in this study is identical to that of the Gran Paradiso nappe [Meffan-Main et al. (2004) J Metamorphic Geol 22:261–281], confirming that these two units have shared the same Alpine metamorphic history. Furthermore,
the Gran Paradiso and Monte Rosa nappes underwent eclogite-facies metamorphism within the same time interval as the structurally
overlying Zermatt-Saas ophiolite [∼50–40 Ma; e.g., Amato et al. (1999) Earth Planet Sci Lett 171:425–438; Mayer et al. (1999) Eur Union Geosci 10:809 (abstract); Lapen et al. (2003) Earth Planet Sci Lett 215:57–72]. The nearly identical P–T–t histories of the Gran Paradiso, Monte Rosa, and Zermatt-Saas units suggest that these units shared a common Alpine tectonic
and metamorphic history. The close spatial and temporal associations between high pressure (HP) ophiolite and continental
crust during Alpine orogeny indicates that the HP internal basement nappes in the western Alps may have played a key role
in exhumation and preservation of the ophiolitic rocks through buoyancy-driven uplift. Coupling of oceanic and continental
crust may therefore be critical in preventing permanent loss of oceanic crust to the mantle. 相似文献
998.
Isabelle Letard Philippe Sainctavit Catherine Deudon 《Physics and Chemistry of Minerals》2007,34(2):113-120
Pyrrhotite (Fe7S8) is a natural iron sulphide that can participate in rock magnetisation. Its electronic structure is not yet surely described.
X-ray magnetic circular dichroism (XMCD) at Fe L2,3 edges on Fe7S8, coupled with multiplet calculations, shows that iron is present only as Fe2+ in this magnetic iron sulphide. It reveals a strong magnetic orbital moment. XMCD at Fe and S K edges shows the quite strong
polarization of both Fe and S in Fe7S8. 相似文献
999.
Syntectonic plutons emplaced in shallow crust often contain intermediate-to low-temperature deformation microstructures but
lack a high-temperature, subsolidus deformation fabric, although the relict magmatic fabric is preserved. The Proterozoic
Vellaturu granite emplaced at the eastern margin of the northern Nallamalai fold belt, south India during the late phase of
regional deformation has a common occurrence of intermediate-to low-temperature deformation fabric, superimposed over magmatic
fabric with an internally complex pattern. But high-T subsolidus deformation microstructure and fabric are absent in this
pluton. The main crystal plastic deformation and fluid enhanced reaction softening was concentrated along the margin of the
granite body. Resulting granite mylonites show Y-maximum c-axis fabric in completely recrystallized quartz ribbonds, dynamic recrystallization of perthites, and myrmekite indicative
of fabric development under intermediate temperature (∼ 500–400°C). The weakly-deformed interior shows myrmekite, feldspar
microfracturing and limited bulging recrystallization of quartz. The abundance of prism subgrain boundaries is indicative
of continuing deformation through low-temperature (∼ 300°C). The relative rates of cooling influenced by advective heat transfer
and deformation of the pluton seem to control the overall subsolidus fabric development. The rapid advective heat transfer
from the interior in the early stages of subsolidus cooling was followed by slow cooling through intermediate temperature
window as a well-developed phyllosilicate rich mylonitic skin around the granite body slowed down conductive heat loss. Low-T
crystal plastic deformation of quartz was effected at a late stage of cooling and deformation of the shallow crustal granite
body emplaced within the greenschist facies Nallamlai rocks. 相似文献
1000.
Allen P. Nutman Vickie C. Bennett Clark R. L. Friend Kenji Horie Hiroshi Hidaka 《Contributions to Mineralogy and Petrology》2007,154(4):385-408
The Eoarchaean (>3,600 Ma) Itsaq Gneiss Complex of southern West Greenland is dominated by polyphase orthogneisses with a
complex Archaean tectonothermal history. Some of the orthogneisses have c. 3,850 Ma zircons, and they vary from rare single
phase metatonalites to more common complexly banded migmatites. This is due to heterogeneous strain, in situ anatexis and
granitic veining superimposed during younger tectonothermal events. In the single-phase tonalites with c. 3,850 Ma zircon,
oscillatory-zoned prismatic zircon is all 3,850 Ma old, but shows patchy ancient loss of radiogenic Pb. SHRIMP spot analyses
and laser ablation ICP-MS depth profiling show that thin (usually < 10 μm) younger (3,660–3,590 Ma and Neoarchaean) shells
of lower Th/U metamorphic zircon are present on these 3,850 Ma zircons. Several samples with this simple zircon population
occur on islands near Akilia. In contrast, migmatites usually contain more complex zircon populations, with often more than
one generation of igneous zircon present. Additional zircon dating of banded gneisses across the Complex shows that samples
with c. 3,850 Ma igneous zircon are not just a phenomenon restricted to Akilia and adjacent islands. For example, migmatites
from Itilleq (c. 65 km from Akilia) contain variable amounts of oscillatory-zoned 3,850 Ma and 3,650 Ma zircon, interpreted,
respectively, as the rock age and the time of crustal melting under Eoarchaean metamorphism. With only 110–140 ppm Zr in the
tonalites and likely magmatic temperatures of >850°C, zircon solubility–melt composition relationships show that they were
only one-third saturated in zircon. Any zircon entrained in the precursor magmas would thus have been highly soluble. Combined
with the cathodoluminesence imaging, this demonstrates that the c. 3,850 Ma oscillatory zoned zircon crystallised out of the
melt and hence gives a magmatic age. Thus the rare well-preserved tonalites and palaeosome in migmatites testify that c. 3,850 Ma
quartzo–feldspathic rocks are a widespread (but probably minor) component in the Itsaq Gneiss Complex. C. 3,850 Ma zircon
with negative Eu anomalies (showing growth in felsic systems) also occurs as detrital grains in rare c. 3,800 Ma metaquartzites
and as inherited grains in some 3,660 Ma granites (sensu stricto). These demonstrate that still more c. 3,850 Ma rocks were present, but were recycled into Eoarchaean sediments and crustally
derived granites. The major and trace element characteristics (e.g. LREE enrichment, HREE depletion, low MgO) of the best-preserved
c. 3,850 Ma rocks are typical of Archaean TTG suites, and thus argue for crust formation processes involving important contributions
from melting of hydrated mafic crust to the earliest Archaean. Five c. 3,850 Ma tonalites were selected as the best preserved
on the basis of field criteria and zircon petrology. Four of these samples have overlapping initial ɛNd (3,850 Ma) values from +2.9 to +3.6± 0.5, with the fourth having a slightly lower value of +0.6. These data provide additional
evidence for a markedly LREE-depleted early terrestrial mantle reservoir. The role of c. 3,850 Ma crust should be considered
in interpreting isotope signatures of the younger (3,800–3,600 Ma) rocks of the Itsaq Gneiss Complex.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献