Méthodologie de l'extraction des hydrocarbures aromatiques polycycliques. Application à des sédiments de la lagune de Bizerte (Tunisie)Methodology of extraction of polycyclic aromatic hydrocarbons. Application to sediment from the Bizerte Lagoon (Tunisia)

The marine environment is very complex, with several important chemical, biological, and sedimentological interactions. Sediments constitute a reservoir for numerous pollutants, including polycyclic aromatic hydrocarbons (PAHs). PAHs are known by their mutagenic and/or carcinogenic effect. This study evaluates contamination levels in Bizerte Lagoon with respect to PAHs. The extraction efficiency of PAHs from sediment has been evaluated using Soxhlet or ultrasonic procedures, based on the recovery of an internal standard (9,10-dihydroanthracene). Several PAHs were found, including sixteen that are reported in the priority list of pollutants of the US Environmental Protection Agency (EPA). PAHs analysis was carried out by GC–FID and GC–MS for 16 samples sampled in two seasons: summer and winter. Results permit an assessment of PAHs pollution in the Bizerte Lagoon. To cite this article: N. Mzoughi et al., C. R. Geoscience 334 (2002) 893–901.     

Oxygen and carbon isotopes in Jordanian phosphorites and associated fossils

Stable isotopes have proven to be efficient tools for paleoenvironmental analysis and interpretation of paleotemperature. Oxygen and carbon isotopes were analyzed in carbonate flourapatite (francolite), oyster shells, tests of foraminifera and ostracods from the Phosphorite Unit throughout Jordan.Isotopic analysis showed δ¹⁸O to be enriched in authigenic francolite in Upper Cretaceous in NW Jordan, indicating lower temperatures, a deeper depositional environment and lower salinity than Central Jordan. In Central Jordan, the local basin of Hafira shows enrichment of δ¹⁸O indicating a deeper depositional environment than shallower highs in Mutarammil and Wadi El-Hasa. The δ¹³C shows that the depositional environment was oxic to suboxic and may have reached the suboxic to anoxic interface in the deeper environment in NW Jordan.δ¹⁸O values in tests of foraminifera and ostracods are similar to δ¹⁸O values of authigenic phosphate, which is enriched in NW Jordan, indicating lower temperature, lower salinity and a deeper environment than Central Jordan. In Central Jordan, δ¹³C shows more depletion in the Sultani section due to land derived organic carbon (food web supply) carried by terrestrial water draining to the sea.The δ¹⁸O in oyster shells show an upward enrichment in the Wadi El-Hasa section, which indicate an increase of intense upwelling, enrichment of nutrients, development of productivity and growth of oyster buildups. Meanwhile, Hafira shows enrichment of δ¹⁸O and lower temperature, in agreement with foraminifera and ostracods. The two samples of oysters from SE Jordan, although affected by diagenesis, show heavier oxygen to the north, indicating a deeper water environment and lower salinity in the same basin.     

Strong ground motion attenuation in Aswan area, Egypt

Recent and paleo seismicity indicate that moderate seismic activity is relatively large for Aswan area. This is a warning on the possibility of occurrence of earthquakes in the future too. No strong motion records are available in Aswan area for engineers to rely upon. Consequently, the seismological modeling is an alternative approach till sufficient instrumental records around Aswan become available. In the present study, we have developed new ground motion attenuation relationship for events spanning 4.0?≤? M _w?≤?7.0 and distance to the surface projection of the fault up to 100 km for Aswan based on a statistically simulated seismological model. We generated suites of ground motion time histories using stochastic technique. The ground motion attenuation relation describes the dependence of the strength of the ground motions on the earthquake magnitude and distance from the earthquake. The proposed equation for peak ground acceleration (PGA) for the bed rock is in the form of: $ {\mathbf{log}}{\text{ }}\left( {{\mathbf{PGA}}/{\mathbf{gal}}} \right){\text{ }} = {\mathbf{1}}.{\mathbf{24}} + {\mathbf{0}}.{\mathbf{358}}{M_{\mathbf{w}}} - {\text{ }}{\mathbf{log}}\left( {\mathbf{R}} \right){\text{ }}-{\text{ }}{\mathbf{0}}.{\mathbf{008}}{\text{ }}{\mathbf{R}}{\text{ }} + {\text{ }}{\mathbf{0}}.{\mathbf{22}}{\text{ }}{\mathbf{P}} $ . Where PGA is the peak ground acceleration in gal (cm/s²); M_w, its moment magnitude; R is the closest distance between the rupture projection and the site of interest; and the factor P is a dummy variable. It is observed that attenuation of strong motion in Aswan is correlated with those used before in Egypt.     

Performance improvement of a passive solar still in a water desalination

Using a solar energy in water desalination system is regarded as one of the most effective ways to resolve the problem of freshwater shortages in this world. Experimental and theoretical approaches were carried out to design and test multistage solar still. The experimental tests were conducted for five months in the city of Kirkuk, north of Iraq, at 43.39° longitudinal and 35.17° latitude. The performance requirement of the design is dependent on many factors such as circumstances, work and designation variables. Designating variables, mainly length, width, height and volume of each stage besides the number of all stages, are determined via theoretical analysis approach. The results obtained by both approaches have shown that there is a 10% deviation in still water productivity. Also, the results indicated that the minimum and maximum daily average of still water productivity is 1.7 and 3.8 kg. MATLAB software was employed to model and simulate the experimental processes of evaporation and condensation. The simulation model results were found to agree well with the experiments carried out in many other papers and studies. The test results reported that the system produces about 5 kg of clean water per day with 87% distillation efficiency and 26% of the overall efficiency due to heat losses in the system. Such system is not only promising, but can offer a new technology that can particularly be used in remote and rural areas. The theoretical calculations were compared with the experimental results, and there is a good agreement between the two .     

Genetic responses to metal contamination in two clams: Ruditapes decussatus and Ruditapes philippinarum

Coastal ecosystems are subjected to a wide variety of disturbances, including those due to xenobiotics of agricultural and industrial origin. These pollutants as heavy metals can modify the genetic diversity of populations by favouring or counter-selecting certain alleles or genotypes by differential mortality. In the present study, two genetic markers (phosphoglucomutase and glucosephosphate isomerase) and a protein marker (metallothionein) were monitored in order to determine the impact of heavy metals in different clam populations. Analysis of the genetic structure of the clam populations examined reveals that those inhabiting environments contaminated by heavy metals exhibit a higher allelic diversity and possess alleles at PGM loci that could be selected by the presence of heavy metals. The evaluation of metallothionein levels using a specific polyclonal antibody developed in the Pacific oyster (Crassostrea gigas) demonstrated the existence of a relationship between metallothionein concentrations and the level of metal pollution for clam populations sampled from different sites. An inter-specific difference was also detected between Ruditapes decussatus and Ruditapes philippinarum living in sympatry at the same site, suggesting a differential response of these two species upon exposure to an identical heavy metal concentration.     

Development of calcrete of the Late Cretaceous carbonate platform,northern Jordan,and its tectonic implications

A calcrete horizon, 3–10 m thick, is found exposed in northern Jordan in three localities, Rumman, Marsa’, and Wasfi At Tal forest (WTF). It is situated at the base of the dominantly limestone, Late Cenomanian Hummar Formation, separating it from the underlying marly Fuheis Formation. The calcrete horizon exhibits all the diagnostic features characteristic of calcrete, such as diagenetic pisoids; a mottled or clotted texture; circumgranular cracks around grains in a nodular texture; pendant or microstalactitic cement; meniscus cement; plant roots or rhizogenic structures, both longitudinal and transverse; exfoliation on boulder and cobbles; alagally laminated hard pans; and abundant dissolution of cracks and vugs. Consequently, it represents a subaerial erosional unconformity and type 1 sequence boundary (SB) that was not previously noticed. The Hummar Formation is considered as a third-order sequence with the SB at the base of the calcrete horizon, while the calcrete horizon itself forms the lowstand system tracts (LST). The transgressive systems tracts (TST) involve the lower two third of the Hummar Formation ending with peloidal grainstone representing the maximum flooding surface (MFSs). The rest of the formation is the falling highstand systems tracts (HST). The next SB is not seen due to a thick soil-covered gap. The calcrete horizon formed due to the formation of a paleohigh, in the study area, associated with the compression produced by the initial subduction of the Afro-Arabian Plate under the Eurasian Plate during the Late Cenomanian, slightly earlier than the previously known Turonian subduction and compression.     

Facies analysis and geochemistry of the Euphrates Formation in Central Iraq

The Euphrates Formation (Lower Miocene) in the Central Iraq consists mainly of shallow marine carbonates. Two hundred ten samples were collected from 21 wells (1E to 21ED) at Bahar Najaf area, and 18 samples were collected at Wadi Asadi in Baghdadi area, from Euphrates Formation. Four microfacies are identified, namely mudstone, wackestone, packstone, and rare grainstone with ten submicrofacies. The allochems in the Euphrates Formation are dominated by bioclasts. Peloids, ooids, and intraclasts are less abundant. The common fossils in the Euphrates Formation are miliolids, algae, ostracods, Miogypsina, and abundant shells of pelecypods and gastropods. Calcite and dolomite are the predominant mineral components of the Euphrates Formation. The carbonates of the Euphrates Formation have been affected by a variety of diagenetic processes such as micritization, dissolution, neomorphism, cementation, stylolitization, dolomitization, dedolomitization, and silicification. The Euphrates Formation was deposited in open to restricted platforms which indicated lagoonal environment with warm and restricted open circulation. In fact, prevalence and abundance of micrite provide an evidence of a shallow marine of low-energy environment and, in some places, may be approaching to be stagnant environment. The average of CaO in Najaf area (51.5 %) is slightly lower than that in Baghdadi area (53.3 %), which was reflected in calcite content found being 91 % in Najaf and 94 % in Baghdadi. Dolomite and gypsum appeared as minor minerals beside calcite, so low concentration of MgO (0.83 % in Najaf; 0.63 in Baghdadi) and SO₃ (0.55 % in Najaf; 0.53 % in Baghdadi) was reflected information of small amounts of dolomite (2 % in Najaf; 1.6 % in Baghdadi) and gypsum (0.7 % in Najaf and 0.6 in Baghdadi) in the Euphrates Formation. The insoluble residue in Najaf area (4.37 %) is relatively higher than that in Baghdadi area (1.9 %), indicating that the Euphrates Formation in Najaf Area has deposited in an environment closer to the shoreline. Concentrations of the trace elements Sr, Mn, and Fe which support the conclusion that reminds the Euphrates Formation had been deposited in a shallow marine environment of quiet energy, with the likelihood that the shoreline was the nearest to Najaf rather than to Baghdadi.     

Study of the 26 December 2011 Aswan earthquake,Aswan area,South of Egypt

The source process and parameters for a moderate earthquake of magnitude Ml 4.1 that occurred on the Kalabsha fault at the Aswan area are analyzed. The derived focal mechanisms of this event and other two aftershocks using polarities of P, SV, and SH waves show strike-slip fault with minor vertical movement of normal type. The solutions give two nodal planes trending ENE–WSW and NNW–SSE in close agreement with the surface traces of the faults crossing the area. The movement is right lateral along the first plane while left lateral along the second one. The rupture process characterization of this event has been investigated by using the empirical Green’s function deconvolution method. By inversion only for the P wave part of the records of these three events (main and other two aftershocks), the source time function for the master events and the azimuthally variations in the (RSTF) pulse amplitude are retrieved for estimating the rupture directivities. The estimated rupture direction is combined with the P-wave focal mechanisms for the three events to identify the fault plane solution for these earthquakes. Based on the width, amplitudes, and numbers of the isolated source time functions, a complex bi-lateral rupture of the studied earthquake is delineated. The source parameters of the master event is calculated and the derived corner frequencies f _o for P-wave spectra show a value of 6.6 Hz; the seismic moment (M _o ) is 4.2?×?10²² Nm; the average displacement (U) is 0.5 m; fault radius (r) 40 m; the average value of the stress drops (Δσ) is 0.6 Mpa, and the moment magnitude (M _w ) is 4.4.     

Microbial community of cyanobacteria mats in the intertidal zone of oil-polluted coast of Saudi Arabia

Cyanobacterial mats are found at various locations along the coast of the Eastern Province of Saudi Arabia. Those mats were affected by severe oil pollution following 1991 oil spill. In this study, samples from Abu Ali Island were collected at three selected sampling sites across the intertidal zone (Lower, Middle, and Upper) in order to understand the effect of extreme environmental conditions of high salinity, temperature and desiccation on distribution of cyanobacteria along the oil polluted intertidal zone. Our investigation of composition of cyanobacteria and diatoms was carried out using light microscopy, and Denaturant Gradient Gel Electrophoresis (DGGE) technique. Light microscopy identification revealed dominant cyanobacteria to be affiliated with genera Phormidium, Microcoleus, and Schizothrix, and to a lesser extent with Oscillatoria, Halothece, and various diatom species. The analysis of DGGE of PCR-amplified 16S rRNA fragments showed that the diversity of cyanobacteria decreases as we proceed from the lower to the upper intertidal zone. Accordingly, the tidal regime, salinity, elevated ambient air temperature, and desiccation periods have a great influence on the distribution of cyanobacterial community in the oil polluted intertidal zone of Abu Ali Island.