Concentration,composition and sources of PAHs in the coastal sediments of the exclusive economic zone (EEZ) of Qatar,Arabian Gulf

Surface sediments were collected from sixteen locations in order to assess levels and sources of polycyclic aromatic hydrocarbons (PAHs) in sediments of Qatar exclusive economic zone (EEZ). Samples were analyzed for 16 parent PAHs, 18 alkyl homologs and for dibenzothiophenes. Total PAHs concentration (∑PAHs) ranged from 2.6 ng g⁻¹ to 1025 ng g⁻¹. The highest PAHs concentrations were in sediments in and adjacent to harbors. Alkylated PAHs predominated most of the sampling locations reaching up to 80% in offshore locations. Parent PAHs and parent high molecular weight PAHs dominated location adjacent to industrial activities and urban areas. The origin of PAHs sources to the sediments was elucidated using ternary plot, indices, and molecular ratios of specific compounds such as (Ant/Phe + Ant), (Flt/Flt + Pyr). PAHs inputs to most coastal sites consisted of mixture of petroleum and combustion derived sources. However, inputs to the offshore sediments were mainly of petroleum origin.     

Climate-resilient agricultural water management to alleviate negative impacts of global warming in rice production systems

Theoretical and Applied Climatology - Improving the economic productivity of limited available freshwater through producing more rice with less water is essential to sustain paddy production...     

Lithospheric extension and the opening of the Red Sea: sediment-basalt relationships in Yemen*

This paper analyses new field and radiometric age data on the timing of extension, sedimentation and magmatism related to the opening of the Red Sea. The first evidence of widespread extension is found in synsedimentary fissures in the fluviatile to shallow marine Tawilah Formation of Cretaceous to early Tertiary age. The first indication of magmatism is the eruption of alkaline basalts (43.5–21.2 Ma) on to marine and non-marine sandstones of lower to middle Tertiary age. The lack of an angular unconformity at the sediment-basalt contact, over a period of 25 Myr, corroborates a diachronous relationship between the Tawilah sandstones and the Yemen Volcanics. These data also indicate that the onset of volcanism in Yemen was in the Eocene, as is the case in Ethiopia and Saudi Arabia. A passive rifting model is supported by early extension and sedimentation followed by syn- and post-tectonic magmatism.     

Geospatial and geostatistical approach for groundwater potential zone delineation

Over the past few decades, groundwater has become an essential commodity owing to increased demand as a result of growing population, industrialization, urbanization and so on. The water supply situation is expected to become more severe in the future because of continued unsustainable water use and projected change in hydrometeorological parameters due to climate change. This study is based on the integrated approach of remote sensing, geographical information system and multicriteria decision‐making techniques to determine the most important contributing factors that affect the groundwater resources and to delineate the groundwater potential zones. Ten thematic layers, namely, geomorphology, geology, soil, topographic elevation (digital elevation model), land use/land cover, drainage density, lineament density, proximity of surface water bodies, surface temperature and post‐monsoon groundwater depth, were considered for the present study. These thematic layers were selected for groundwater prospecting based on the literature; discussion with the experts of the Central Ground Water Board, Government of India; field observations; geophysical investigation; and multivariate techniques. The thematic layers and their features were assigned suitable weights on Saaty's scale according to their relative significance for groundwater occurrence. The assigned weights of the layers and their features were normalized by using the analytic hierarchy process and eigenvector method. Finally, the selected thematic maps were integrated using a weighted linear combination method to create the final groundwater potential zone map. The final output map shows different zones of groundwater potential, namely, very good (16%), good (35%), moderate (28%) low (17%) and very low (2.1%). The groundwater potential zone map was finally validated using the discharge and groundwater depth data from 28 and 98 pumping wells, respectively, which showed good correlation. Copyright © 2014 John Wiley & Sons, Ltd.     

Adsorption of copper, nickel and lead ions from synthetic semiconductor industrial wastewater by palm shell activated carbon

Granular activated carbon produced from palm kernel shell was used as adsorbent to remove copper, nickel and lead ions from a synthesized industrial wastewater.Laboratory experimental investigation was carried out to identify the effect of pH and contact time on adsorption of lead, copper and nickel from the mixed metals solution. Equilibrium adsorption experiments at ambient room temperature were carried out and fitted to Langmuir and Freundlich models. Results showed that pH 5 was the most suitable, while the maximum adsorbent capacity was at a dosage of 1 g/L, recording a sorption capacity of 1.337 mg/g for lead, 1.581 mg/g for copper and 0.130 mg/g for nickel. The percentage metal removal approached equilibrium within 30 min for lead, 75 min for copper and nickel, with lead recording 100 %, copper 97 % and nickel 55 % removal, having a trend of Pb²⁺ > Cu²⁺ > Ni²⁺. Langmuir model had higher R² values of 0.977, 0.817 and 0.978 for copper, nickel and lead respectively, which fitted the equilibrium adsorption process more than Freundlich model for the three metals.     

夏季副高与海温的相互关系及副高预测

通过分析夏季西太平洋副高与前期12月至后期11月的赤道太平洋和北太平洋海温的相关系数分布图,综合比较副高面积指数、西伸脊点和脊线位置与海温的相关关系,讨论副高对海温的反馈作用以及海温与夏季副高的物理联系模型,为副高预测提供依据.     

Site classification of Turkish national strong-motion stations

Since 1973, the General Directorate of Disaster Affairs of Turkey has deployed several strong-motion accelerographs at selected sites. Within the framework of the project entitled Compilation of National Strong Ground Motion Database in Accordance with International Standards, site conditions were investigated within the upper 30-m depth by surface seismic and standard penetration tests. Preliminary characterization of the sites is made by making use of both geophysical and geotechnical criteria of NEHRP Provisions and Eurocode-8 site classification systems. The liquefaction susceptibility of those sites which comprise saturated cohesionless deposits is also determined. Mean shear-wave velocity, mean penetration resistance, site class, and liquefaction susceptibility of each site are tabulated. The Turkish strong-motion database supplemented by detailed information on site conditions is a valuable source of information particularly for those studies that put emphasis on the relationship between site conditions and strong-motion parameters.     

The influence of carbonate textures and rock composition on durability cycles and geomechanical aspects of carbonate rocks

Acta Geotechnica - One of the most important geotechnical parameters in studying the engineering behavior of a rock mass is slake durability. The major goal of this research is to test how a series...     

New data on the Late Cenozoic basaltic volcanism in Syria,applied to its origin

New data on geology and 21 K–Ar dates of the Late Oligocene–Quaternary basalts in Syria, combined with analysis of the new and previous data are used to reconstruct the volcanic history and relations between it and tectonic events. Volcanism began at the end of Oligocene (26–24 Ma) and was concentrated in the Late Oligocene–Early Miocene along a N-trending band, which stretches from the Jebel Arab (Harrat Ash Shaam) up to Kurd Dagh and southern Turkey. Activity waned in the Middle Miocene (17–12 Ma), but was resumed in the same band in the Tortonian and increased in the Messinian and Early Pliocene (6.3–4 Ma), when volcanism spread to the Shin Plateau and its coastal extension. After a brief hiatus ～ 4–3.5 Ma, volcanism became still more intensive and spread from the N-trending band to the east into the northern margin of the Mesopotamian Foredeep and to the west into the Dead Sea Transform zone. Additional eruptions continued into the Holocene.Volcanism lasted > 25 million years in the Jebel Arab Highland and > 15 million years in the Aleppo Plateau. The long duration of volcanism in the same parts of the moving Arabian plate and absence of records of one-way migration of the activity mean that the magmatic sources moved together with the plate, i.e., they were situated within the lithosphere mantle. Coincidence of the tectonic and volcanic stages of the Arabian plate development proves that volcanic activity depended on the geodynamic situation, caused by the plate motion. Situated within the lithosphere, magmatic sources within this transverse band were possibly caused by thermal and deforming influences of the asthenospheric lateral flow, moved laterally from the Ethiopia–Afar deep superplume.     

Optimal design of rain gauge network in the Middle Yarra River catchment,Australia

Rainfall data are a fundamental input for effective planning, designing and operating of water resources projects. A well‐designed rain gauge network is capable of providing accurate estimates of necessary areal average and/or point rainfall estimates at any desired ungauged location in a catchment. Increasing network density with additional rain gauge stations has been the main underlying criterion in the past to reduce error and uncertainty in rainfall estimates. However, installing and operation of additional stations in a network involves large cost and manpower. Hence, the objective of this study is to design an optimal rain gauge network in the Middle Yarra River catchment in Victoria, Australia. The optimal positioning of additional stations as well as optimally relocating of existing redundant stations using the kriging‐based geostatistical approach was undertaken in this study. Reduction of kriging error was considered as an indicator for optimal spatial positioning of the stations. Daily rainfall records of 1997 (an El Niño year) and 2010 (a La Niña year) were used for the analysis. Ordinary kriging was applied for rainfall data interpolation to estimate the kriging error for the network. The results indicate that significant reduction in the kriging error can be achieved by the optimal spatial positioning of the additional as well as redundant stations. Thus, the obtained optimal rain gauge network is expected to be appropriate for providing high quality rainfall estimates over the catchment. The concept proposed in this study for optimal rain gauge network design through combined use of additional and redundant stations together is equally applicable to any other catchment. © 2014 The Authors. Hydrological Processes published by John Wiley & Sons Ltd.