Trace gases and PM2.5-bound metal abundance over a tropical urban environment,South India

Pre and Post-Monsoon levels of ambient SO₂, NO₂, PM_2.5 and the trace metals Fe, Cu, etc. were measured at industrial and residential regions of the Kochi urban area in South India for a period of two years. The mean PM_2.5, SO₂ and NO₂ concentrations across all sites were 38.98?±?1.38 µg/m³, 2.78?±?0.85 µg/m³ and 11.90?±?4.68 µg/m³ respectively, which is lower than many other Indian cities. There was little difference in any on the measured species between the seasons. A few sites exceeded the NAAQS (define acronym and state standard) and most of the sites exceeded WHO (define acronym and state standard) standard for PM_2.5. The average trace metal concentrations (ng/m³) were found to be Fe (32.58)?>?Zn (31.93)?>?Ni (10.13)?>?Cr (5.48)?>?Pb (5.37)?>?Cu (3.24). The maximum concentration of trace metals except Pb were reported in industrial areas. The enrichment factor, of metals relative to crustal material, indicated anthropogenic dominance over natural sources for the trace metal concentration in Kochi’s atmosphere. This work demonstrates the importance of air quality monitoring in this area.

     

Cretaceous Environments of Afghanistan:A Synthesis Based on Selected Sections

1IntroductionThe Late Mesozoic sequences of Afghanistan are important in understanding the geodynamic evolu-tion of the northwestern part of South Asia, in par-ticular the transgressive and regressive history of the northwestern part of the Tethys connecting Iran to the west and the northern Indian Subcontinent to the east. Jurassic to Upper Cretaceous sedimentary seque-nces were initially studied by Griesbach (1885 ~1887) and Hayden (1880~1901) through several traverses in northern an…     

Integrated stratigraphy and 40Ar/39Ar chronology of the early to middle Miocene Upper Freshwater Molasse in western Bavaria (Germany)

A detailed integrated stratigraphic study (biostratigraphy and magnetostratigraphy) was carried out on five sections from the western part of the Bavarian Upper Freshwater Molasse of the North Alpine Foreland Basin (NAFB), greatly improving the chronostratigraphy of these sediments. The sections belong to the lithostratigraphic units Limnische Untere Serie (UL) and Fluviatile Untere Serie (UF) and contain 19 (mostly new) small-mammal bearing levels, significantly refining the local biostratigraphy. Radiometric ages obtained from glass shards from tuff horizons are used together with the biostratigraphic information for constructing and confirming the magnetostratigraphic correlation of the studied sections to the Astronomical Tuned Time Scale (ANTS04; Lourens et al. in Geologic Time Scale 2004, Cambridge University Press, 2004). This correlation implies that the UL lithostratigraphic unit corresponds to the latest Ottnangian and the Early Karpatian, whereas the UF corresponds to the Karpatian and the Early Badenian. This indicates that the Brackish- to Freshwater Molasse transition already occurred during the late Ottnangian. The pre-Riesian hiatus occurred in the latest Karpatian and lower Early Badenian in Eastern Bavaria and Bohemia and in the Late Karpatian and earliest Badenian in Western Bavaria. The geochemical and Ar–Ar data of volcanic ashes suggest that highly evolved silicic magmas from a single volcano or volcanic center, characterized by a uniform Nd isotopic composition, erupted repetitively over the course of at least 1.6 Myr. Three phases of eruptive activity were identified at 16.1 ± 0.2 Ma (Zahling-2), 15.6 ± 0.4 Ma (Krumbad), and 14.5 ± 0.2 Ma (Heilsberg, Hegau). The correlation of the local biostratigraphic zonation to the ANTS04 enables further the characterization of both the Ottnangian–Karpatian and Karpatian–Badenian boundaries in the NAFB by small-mammal biostratigraphy. According to these results the Ottnangian–Karpatian boundary is contemporaneous with the first appearance datum of Megacricetodon bavaricus (in the size of the type population) and the first common occurrence of Keramidomys thaleri, whereas Ligerimys florancei, Melissiodon dominans and Prodeinotherium aff. bavaricum have been already disappeared during the late Ottnangian. The Karpatian–Badenian boundary is characterized by a significant size increase of the large Megacricetodon lineage and possibly a (re-)immigration of Prodeinotherium bavaricum.     

Limitations of Monitoring Wells for the Detection and Quantification of Petroleum Products in Soils and Aquifers

Theoretical analysis and laboratory column experiments were carried out to investigate the conditions required for petroleum products (oil) to flow into a well installed through a sandy porous medium contaminated with the oil. The results indicated that oil would flow into a well only after a layer of "free oil" is formed in the adjacent porous medium. Because significant quantities of oil could be stored in the porous medium under the influence of capillary suction prior to the formation of the zone of free oil, the presence of oil in a well would indicate an advanced stage of oil contamination of the subsurface. While monitoring wells could be used to delineate the extent of the free-oil plume and the plume of dissolved petroleum constituents, they are not useful for delineating the extent of capillary held oil.
The experimental results also indicated that the ratio of the oil-layer thickness in the well to that in the porous medium is not a constant as is sometimes assumed in practice. Further, estimates of the oil thickness in the medium based on the oil thickness in wells and on capillary properties measured in the laboratory were sensitive to the values of the parameters used in these estimates. The measured thickness of the oil layer in a monitoring well alone may not yield reliable estimates of the amount of oil in the subsurface, and assuming that the oil-thickness ratio is a constant can lead to inadequate site assessments and inappropriate remedial plans.     

Stability of the periodic solutions of the restricted three-body problem representing analytic continuations of Keplerian rectilinear periodic motions

The periodic solutions of the restricted three-body problem representing analytic continuations of Keplerian rectilinear periodic motions are well known (Kurcheeva, 1973). Here the stability of these solutions are examined by applying Poncaré's characteristic equation for periodic solutions. It is found that the isoperiodic solutions are stable and all other solutions are unstable.     

Numerical simulation of physical and dynamical characteristics associated with the severe thunderstorm on April 5, 2015 at Kushtia and Jhenaidah

The paper deals with the study of the physical and dynamical characteristics of a severe thunderstorm, which had occurred on April 5, 2015, at about 2100 UTC in the southwestern Bangladesh with location around 23.3–23.7N and 89.0–89.4E within the upazilas (sub-districts) of Kumarkhali and Shailkupa under the districts of Kushtia and Jhenaidah, respectively. The thunderstorm was associated with numerous hails of large size. More than 5000 birds which used to live in the bird sanctuary at Shailkupa and 22,011 birds in Chhaglapara Bird Sanctuary of Kumarkhali died as they were hit by the hails. Large hails also damaged crops, houses and forests over the thunderstorm hit areas. The evolution of the thunderstorm is studied by the WRF model, which is initialized using the National Centers for Environmental Prediction Final reanalysis data of 0000 UTC of April 5, 2015. The simulated results provide a basis to study the physical and dynamical characteristics of the thunderstorm, which are generally not identified by the meteorological observations which are too sparse. The model has captured a micro-low over Kumarkhali and its neighborhood, which favored the occurrence of the severe thunderstorm. The model simulated rainfall is about 26 mm near the place of occurrence, which matches well with the area where the reflectivity of hydrometeor is maximum. The convective available potential energy is found to be 1600 J kg^?1 at 1730 UTC near the place of occurrence of the thunderstorm; this indicates high atmospheric instability over the thunderstorm location for the formation of the thunderstorm. The vertical velocity, convergence, cloud water mixing ratio and the ice water mixing ratio and their vertical extensions are found to be satisfactory and responsible for the occurrence of large hails associated with the thunderstorm.     

Evaluation of the fishery status for King Soldier Bream Argyrops spinifer in Pakistan using the software CEDA and ASPIC

Catch and effort data were analyzed to estimate the maximum sustainable yield(MSY) of King Soldier Bream, Argyrops spinifer(Forssk?l, 1775, Family: Sparidae), and to evaluate the present status of the fish stocks exploited in Pakistani waters. The catch and effort data for the 25-years period 1985–2009 were analyzed using two computer software packages, CEDA(catch and effort data analysis) and ASPIC(a surplus production model incorporating covariates). The maximum catch of 3 458 t was observed in 1988 and the minimum catch of 1 324 t in 2005, while the average annual catch of A. spinifer over the 25 years was 2 500 t. The surplus production models of Fox, Schaefer, and Pella Tomlinson under three error assumptions of normal, log-normal and gamma are in the CEDA package and the two surplus models of Fox and logistic are in the ASPIC package. In CEDA, the MSY was estimated by applying the initial proportion(IP) of 0.8, because the starting catch was approximately 80% of the maximum catch. Except for gamma, because gamma showed maximization failures, the estimated results of MSY using CEDA with the Fox surplus production model and two error assumptions, were 1 692.08 t(R 2 =0.572) and 1 694.09 t( R 2 =0.606), respectively, and from the Schaefer and the Pella Tomlinson models with two error assumptions were 2 390.95 t( R 2 =0.563), and 2 380.06 t( R 2 =0.605), respectively. The MSY estimated by the Fox model was conservatively compared to the Schaefer and Pella Tomlinson models. The MSY values from Schaefer and Pella Tomlinson models were the same. The computed values of MSY using the ASPIC computer software program with the two surplus production models of Fox and logistic were 1 498 t(R 2 =0.917), and 2 488 t( R 2 =0.897) respectively. The estimated values of MSY using CEDA were about 1 700–2 400 t and the values from ASPIC were 1 500–2 500 t. The estimates output by the CEDA and the ASPIC packages indicate that the stock is overfished, and needs some effective management to reduce the fishing effort of the species in Pakistani waters.     

High resolution facies architecture and digital outcrop modeling of the Sandakan formation sandstone reservoir,Borneo:Implications for reservoir characterization and flow simulation

Advances in photogrammetry have eased the acquisition of high-resolution digital information from outcrops, enabling faster, non-destructive data capturing and improved reservoir modeling. Geocellular models for flow dynamics with in the virtual outcrop in siliciclastic deposits at different sets of sandstone facies architecture remain, however, a challenge. Digital maps of bedding, lithological contrast, spatial-temporal variations of bedding and permeability characteristics make it more easy to understand flow tortuosity in a particular architecture. An ability to precisely model these properties can improve reservoir characterization and flow modeling at different scales. Here we demonstrate the construction of realistic 2 D sandstone facies based models for a pragmatic simulation of flow dynamics using a combination of digital point clouds dataset acquired from LiDAR and field investigation of the Sandakan Formation, Sabah, Borneo.Additionally, we present methods for enhancing the accuracy of outcrop digital datasets for producing high resolution flow simulation. A well-exposed outcrop from the Sandakan Formation, Sabah, northwest Borneo having a lateral extent of 750 m was chosen in order to implement our research approach. Sandstone facies and its connectivity are well constrained by outcrop observations, data from air-permeability measurements, bilinear interpolation of permeability, grid construction and water vector analysis for flow dynamics.These proportions were then enumerated in terms of static digital outcrop model(DOM) and facies model based on sandstone facies bedding characteristics. Flow simulation of water vector analysis through each of the four sandstone facies types show persistent spatial correlation of permeability that align with either cross-bedded orientation or straight with more dispersion high quality sandstone(porosity 21.25%-41.2%and permeability 1265.20-5986.25 mD) and moderate quality sandstone(porosity 10.44%-28.75% and permeability 21.44-1023.33 mD). Whereas, in more heterolithic sandstone(wavy-to flaser-bedded and bioturbated sandstone), lateral variations in permeability show spatially non-correlated patterns over centimeters to tens of meters with mostly of low quality sandstone(porosity 3.4%-12.31% and permeability < 1 mD to 3.21 mD). These variations reflect the lateral juxtaposition in flow dynamics. It has also been resulted that the vertical connectivity and heterogeneities in terms of flow are mostly pragmatic due to the interconnected sandstone rather than the quality of sandstone.     

Multi-criteria decision-making analysis in selecting suitable plotting positions for IDF curves of storm events

Selecting suitable distributions for rainfall data is usually subjective and complex since it requires decision-makers to consider results from various measures of goodness-of-fit indices. In this study, the VIKOR method in multi-criteria decision-making analysis is modified to select the most suitable plotting positions to represent extreme storm intensities in order to build the intensity–duration–frequency (IDF) curves of storm events. This is done by considering the rankings provided by all goodness-of-fit indices used to obtain a compromise solution. Nine plotting positions are considered: Weibull (W), Adamowski (A), Gringorten (G), Hazen (H) and Gumbel (EV I) and two known plotting positions for generalized extreme value (GEV) distribution using Pearson’s skewness and another two using L-skewness. The IDF curves obtained are compared to a reference IDF curves which was found using the GEV distribution. The mean and median for three goodness-of-fit indices, the coefficient of variation of root mean square error, CV_RMSE, the mean percentage of difference, Δ, and the coefficient of determination, R ², are taken as the criteria for selection process. The results show that six plotting positions, A, H, W, G and the two plotting positions with L-skewness, are equally superior compared to the other three plotting positions.