Chronology of the high-pressure metamorphism of Norwegian garnet peridotites/pyroxenites

Eclogite facies mineral assemblages are variably preserved in mafic and ultramafic rocks within the Western Gneiss Region (WGR) of Norway. Mineralogical and microstructural data indicate that some Mg–Cr-rich, Alpine-type peridotites have had a complex metamorphic history. The metamorphic evolution of these rocks has been described in terms of a seven-stage evolutionary model; each stage is characterized by a specific mineral assemblage. Stages II and III both comprise garnet-bearing mineral assemblages. Garnet-bearing assemblages are also present in Fe–Ti-rich peridotites which commonly occur as layers in mafic complexes. Sm–Nd isotopic results are reported for mineral and whole rock samples from both of these types of peridotites and related rocks. The partitioning of Sm and Nd between coexisting garnet and clinopyroxene is used to assess chemical equilibrium. One sample of Mg–Cr-type peridotite shows non-disturbed partitioning of Sm and Nd between Stage II garnet and clinopyroxene pairs and yields a garnet–clinopyroxene–whole-rock date of 1703 ± 29 Ma (I= 0.51069, MSWD = 0.04). This is the best estimate for the age of the Stage II high-P assemblage. Other Stage II garnet–clinopyroxene pairs reflect later disturbance of the Sm–Nd system and yield dates in the range 1303 to 1040 Ma. These dates may not have any geological significance. Stage III garnet–clinopyroxene pairs typically have equilibrated Sm–Nd partitioning and two samples yield dates of 437 ± 58 and 511 ± 18 Ma. This suggests that equilibration of the Stage III high-P assemblage is related to the Caledonian orogeny and is more or less contemporaneous with high-P metamorphism of ‘country-rock’eclogites in the surrounding gneisses. The Sm–Nd mineral data for the Fe–Ti-rich garnet peridotites and for a superferrian eclogite, which occurs as a dyke within the Gurskebotn Mg–Cr-type peridotite, are consistent with a Palaeozoic high-P metamorphism. Finally a synoptic P–T–t path is proposed for the Mg–Cr-type peridotites which is consistent with the petrological and geochronological data.     

Seepage of groundwater nitrate from a riparian agroecosystem into the Wye River estuary

Intensive research in Chesapeake Bay has indicated that reductions in nitrogen inputs to the bay will be necessary to restore water quality to levels needed for resurgence of bay living resources. Fall-line water quality monitoring efferts have characterized diffuse-source nitrogen inputs from a large percentage of the bay drainage basin, but relatively little information exists regarding rates of nitrogen delivery to tidal waters from coastal plain regions. Extensive nitrate contamination of shallow groundwater due to agricultural activities, coupled with the dominant role of subsurface flow in discharge from Coastal Plain regions of the drainage basin, creates the potential for high rates of nitrogen delivery to tidal waters via groundwater seepage. This study utilized intensive hydrologic and water chemistry monitoring from April 1992 through September 1994 to determine the spatial characteristics of the groundwater-estuarine interface, as well as the rates of subsurface nitrogen transport from an agricultural field into nearshore waters of the Wye River, a subestuary of Chesapeake Bay. The hydrogeologic characteristics of the study site resulted in groundwater discharge to the Wye River occurring almost exclusively within 15 m of the shoreline. Calculated groundwater discharge rates were found to vary widely in the short term due to tidal fluctuations but in the long term were driven by seasonal changes in groundwater recharge rates. The zone of groundwater discharge contracted shoreward during summer months of low discharge, and expanded to a maximum width of approximately 15 m during high discharge periods in late winter. Average discharge rates were more than five times higher in winter versus summer months. Groundwater nitrate concentrations entering the discharge zone were relatively stable throughout the study period, with little evidence of denitrification or nitrate uptake by riparian vegetation. Consequently, nitrogen discharge patterns reflected the strong seasonality in groundwater discharge. Annual nitrate-N discharge was approximately 1.2 kg m^?1 of shoreline, indicating drainage basin rates of nitrogen delivery to tidal waters of approximately 60 kg ha^?1.     

Comparative study of different wavelets for developing parsimonious Volterra model for rainfall-runoff simulation

Although the Volterra models are non-parsimonious ones, they are being used because they can mimic dynamics of complex systems. However, applying and identification of the Volterra models using data may result in overfitting problem and uncertainty. In this investigation we evaluate capability of different wavelet forms for decomposing and compressing the Volterra kernels in order to overcome this problem by reducing the number of the model coefficients to be estimated and generating smooth kernels. A simulation study on a rainfall?runoff process over the Cache River watershed showed that the method performance is successful due to multi-resolution capacity of the wavelet analysis and high capability of the Volterra model. The results also revealed that db2 and sym2 wavelets have the same high potential in improving the linear Volterra model performance. However, QS wavelet was more successful in yielding smooth kernels. Moreover, the probability of overfitting while identifying the nonlinear Volterra model may be less than the linear model.     

Association of proportions

Simple correlation leads to misleading results when applied to the proportions of materials in mixtures, because of the constraint that the total of the proportions is less than one. A simple mainly graphical procedure to determine whether the proportions in mixtures are associated after allowing for the constraint is presented. No assumptions about the form of the underlying probability distributions are required. The technique is extended to problems where other constraints apply.     

Analysis of seawater for dissolved cadmium, copper and lead: An intercomparison of voltammetric and atomic absorption methods

An intercomparison study of voltammetric and atomic absorption spectrometric methods for determining cadmium, lead and copper in seawater samples was conducted. The voltammetric approach utilizes differential pulse anodic stripping voltammetry using a rotating, glassy carbon, mercury film electrode under conditions developed to minimize contamination sources and to enhance sensitivity for seawater matrices. The atomic absorption approach involves a concentration step using either an organic solvent extraction of metal dithiocarbamate chelates or a Chelex-100 column with detection by graphite furnace atomic absorption spectrometry. Similar and consistent results were obtained using both methods for the three trace metals studied on a wide range of natural seawater samples. Both methods are comparable in sensitivity for cadmium and copper, however the voltammetric method is better suited for the analysis of lead in seawater because of its enhanced sensitivity and low blank. An advantage of the voltammetric approach is its amenability towards real-time shipboard analysis.     

Stratigraphical correlation of the Late Jurassic Lourinhã Formation in the Consolação Sub‐basin (Lusitanian Basin), Portugal

The c. 700 m thick succession of continental–brackish‐marine deposits forming the Lourinhã Formation, cropping out along the coast of western Portugal between Baleal and Santa Cruz, has been correlated using laterally persistent shelly marker beds. Three shelly units record the episodic establishment of relatively short‐lived, brackish‐marine embayments, transgressing from the southwest, onto a low‐lying coastal plain. The succession displays systematic changes in facies types and stacking patterns reflecting differences in fluvial style, bedload character and palaeontological content. Based on these observations, four new members for the Lourinhã Formation are proposed: the Sáo Bernardino, Porto de Barças, Areia Branca and Ferrel members. New biostratigraphical data indicate that the Lourinhã Formation is Late Kimmeridgian to earliest Early Tithonian in age. This age has also been obtained from the underlying mixed carbonate and clastic deposits of the Abadia Formation at Consolação. As a result, these latter sediments are now re‐assigned to the Alcobaça Formation, a lithostratigraphical term currently in use in other areas of the Lusitanian Basin. Improved regional mapping of the Lourinhã Formation has established a new sub‐basin within the western parts of the Lusitanian Basin. This sub‐basin, now named the Consolação Sub‐basin, is bounded to the east by the Lourinhã–Caldas de Rainha (L–C) fault zone and to the west by the Berlengas Horst. Copyright © 2013 John Wiley & Sons, Ltd.     

Temporal variability in summertime bottom hypoxia in shallow areas of Mobile Bay,Alabama

This paper addresses temporal variability in bottom hypoxia in broad shallow areas of Mobile Bay, Alabama. Time-series data collected in the summer of 2004 from one station (mean depth of 4 m) exhibit bottom dissolved oxygen (DO) variations associated with various time scales of hours to days. Despite a large velocity shear, stratification was strong enough to suppress vertical mixing most of the time. Bottom DO was closely related to the vertical salinity gradient (ΔS). Hypoxia seldom occurred when ΔS (over 2.5 m) was <2 psu and occurred almost all the time when ΔS was >8 psu in the absence of extreme events like hurricanes. Oxygen balance between vertical mixing and total oxygen demand was considered for bottom water from which oxygen demand and diffusive oxygen flux were estimated. The estimated decay rates at 20°C ranging between 0.175–0.322 d⁻¹ and the corresponding oxygen consumption as large as 7.4 g O₂ m⁻² d⁻¹ fall at the upper limit of previously reported ranges. The diffusive oxygen flux and the corresponding vertical diffusivity estimated for well mixed conditions range between 8.6–9.5 g O₂ m⁻² d⁻¹ and 2.6–2.9 m² d⁻¹, respectively. Mobile Bay hypoxia is likely to be associated with a large oxygen demand, supported by both water column and sediment oxygen demands, so that oxygen supply from surface water during destratification events would be quickly exhausted to return to hypoxic conditions within a few hours to days after destratification events are terminated.